TY - JOUR
T1 - Chlorine-Induced Hydrogen-Bonding Network of A Novel Dimer Based on Nickel and Tridentate Ligand
T2 - 3-Hydrazine-4-amino-1,2,4-Triazole
AU - Bi, Yangang
AU - Zhao, Wenyuan
AU - Li, Ying
AU - Zhang, Tonglai
N1 - Publisher Copyright:
© 2015 SIOC, CAS, Shanghai & Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
PY - 2015/7
Y1 - 2015/7
N2 - The reaction of NiCl2 and 3-hydrazine-4-amino-1,2,4-triazole (Hatr) in the mixed solvent of EtOH and H2O yielded a dimer compound ([Ni2(Hatr)2(H2O)2(EtOH)2Cl2]Cl2·EtOH) with water and EtOH molecules coordinated to nickle ions. It crystallized in trigonal space group R-3, a=b=29.67(1) Å, c=8.95(7) Å, β=120(1), as determined by single-crystal X-ray diffraction. Then, they were fully characterized by the IR spectroscopy, differential scanning calorimetry (DSC), thermogravimetry (TG), and elemental analysis. The reaction of NiCl2 and 3-hydrazine-4-amino-1,2,4-triazole (Hatr) in the mixed solvent of EtOH and H2O yielded a dimer compound ([Ni2(Hatr)2(H2O)2(EtOH)2Cl2]Cl2· EtOH) with water and EtOH molecules coordinated to nickle ions. It crystallized in trigonal space group R-3, a=b=29.67(1) Å, c=8.95(7) Å, β=120(1), as determined by single-crystal X-ray diffraction. Then, they were fully characterized by the IR spectroscopy, differential scanning calorimetry (DSC), thermogravimetry (TG), and elemental analysis.
AB - The reaction of NiCl2 and 3-hydrazine-4-amino-1,2,4-triazole (Hatr) in the mixed solvent of EtOH and H2O yielded a dimer compound ([Ni2(Hatr)2(H2O)2(EtOH)2Cl2]Cl2·EtOH) with water and EtOH molecules coordinated to nickle ions. It crystallized in trigonal space group R-3, a=b=29.67(1) Å, c=8.95(7) Å, β=120(1), as determined by single-crystal X-ray diffraction. Then, they were fully characterized by the IR spectroscopy, differential scanning calorimetry (DSC), thermogravimetry (TG), and elemental analysis. The reaction of NiCl2 and 3-hydrazine-4-amino-1,2,4-triazole (Hatr) in the mixed solvent of EtOH and H2O yielded a dimer compound ([Ni2(Hatr)2(H2O)2(EtOH)2Cl2]Cl2· EtOH) with water and EtOH molecules coordinated to nickle ions. It crystallized in trigonal space group R-3, a=b=29.67(1) Å, c=8.95(7) Å, β=120(1), as determined by single-crystal X-ray diffraction. Then, they were fully characterized by the IR spectroscopy, differential scanning calorimetry (DSC), thermogravimetry (TG), and elemental analysis.
KW - X-ray diffraction
KW - differential scanning calorimetry
KW - dimer compound
KW - nickel
KW - tridentate ligand
UR - http://www.scopus.com/inward/record.url?scp=84948578924&partnerID=8YFLogxK
U2 - 10.1002/cjoc.201500253
DO - 10.1002/cjoc.201500253
M3 - Article
AN - SCOPUS:84948578924
SN - 1001-604X
VL - 33
SP - 792
EP - 796
JO - Chinese Journal of Chemistry
JF - Chinese Journal of Chemistry
IS - 7
ER -