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Chirality sensing of choline derivatives by a triple anion helicate cage through induced circular dichroism

  • Wei Zuo
  • , Zhe Huang
  • , Yanxia Zhao
  • , Wenhua Xu
  • , Zhihua Liu
  • , Xiao Juan Yang
  • , Chuandong Jia*
  • , Biao Wu
  • *Corresponding author for this work
  • Northwest University China

Research output: Contribution to journalArticlepeer-review

Abstract

Chirality sensing of choline derivatives is achieved by a self-assembled, racemic triple anion helicate cage which exhibits induced circular dichroism (ICD) upon encapsulation of a chiral guest. The host-guest interactions were illustrated by NMR, crystal structure, CD and DFT calculations. The absolute configurations and ee values were determined by ICD.

Original languageEnglish
Pages (from-to)7378-7381
Number of pages4
JournalChemical Communications
Volume54
Issue number53
DOIs
Publication statusPublished - 2018
Externally publishedYes

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