Chirality from substitution: Enantiomer separation via a modified metal-organic framework

Jingshu Zhao; Haiwei Li; Yuzhen Han; Rui Li; Xuesong Ding; Xiao Feng; Bo Wang

doi:10.1039/c5ta00998g

Chirality from substitution: Enantiomer separation via a modified metal-organic framework

Jingshu Zhao
, Haiwei Li
, Yuzhen Han
, Rui Li
, Xuesong Ding
, Xiao Feng^*
, Bo Wang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology
China National Offshore Oil Corp
National Center for Nanoscience and Technology

Research output: Contribution to journal › Article › peer-review

88 Citations (Scopus)

Abstract

A microporous MOF structure, d-his-ZIF-8, with a chiral environment was synthesized via a simple ligand in situ substitution (LIS) of 2-methyl imidazolate (mIm) with d-histidine. These chiral MOF composites show exceptional selective separation capability for racemic alanine and glutamic acid, with an ee value of 78.52% and 79.44%, respectively.

Original language	English
Pages (from-to)	12145-12148
Number of pages	4
Journal	Journal of Materials Chemistry A
Volume	3
Issue number	23
DOIs	https://doi.org/10.1039/c5ta00998g
Publication status	Published - 21 Jun 2015

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10.1039/c5ta00998g

Cite this

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title = "Chirality from substitution: Enantiomer separation via a modified metal-organic framework",

abstract = "A microporous MOF structure, d-his-ZIF-8, with a chiral environment was synthesized via a simple ligand in situ substitution (LIS) of 2-methyl imidazolate (mIm) with d-histidine. These chiral MOF composites show exceptional selective separation capability for racemic alanine and glutamic acid, with an ee value of 78.52\% and 79.44\%, respectively.",

author = "Jingshu Zhao and Haiwei Li and Yuzhen Han and Rui Li and Xuesong Ding and Xiao Feng and Bo Wang",

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T2 - Enantiomer separation via a modified metal-organic framework

AU - Zhao, Jingshu

AU - Li, Haiwei

AU - Han, Yuzhen

AU - Li, Rui

AU - Ding, Xuesong

AU - Feng, Xiao

AU - Wang, Bo

PY - 2015/6/21

Y1 - 2015/6/21

N2 - A microporous MOF structure, d-his-ZIF-8, with a chiral environment was synthesized via a simple ligand in situ substitution (LIS) of 2-methyl imidazolate (mIm) with d-histidine. These chiral MOF composites show exceptional selective separation capability for racemic alanine and glutamic acid, with an ee value of 78.52% and 79.44%, respectively.

AB - A microporous MOF structure, d-his-ZIF-8, with a chiral environment was synthesized via a simple ligand in situ substitution (LIS) of 2-methyl imidazolate (mIm) with d-histidine. These chiral MOF composites show exceptional selective separation capability for racemic alanine and glutamic acid, with an ee value of 78.52% and 79.44%, respectively.

UR - https://www.scopus.com/pages/publications/84931270479

U2 - 10.1039/c5ta00998g

DO - 10.1039/c5ta00998g

M3 - Article

AN - SCOPUS:84931270479

SN - 2050-7488

VL - 3

SP - 12145

EP - 12148

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 23

ER -

Chirality from substitution: Enantiomer separation via a modified metal-organic framework

Abstract

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