Chemoselective Luche-type reduction of α,β-unsaturated ketones by aluminium hydride catalysis

Ben Yan; Xiaoli Ma; Ziyuan Pang; Zhi Yang

doi:10.1039/d3dt03987k

Chemoselective Luche-type reduction of α,β-unsaturated ketones by aluminium hydride catalysis

Ben Yan, Xiaoli Ma^*, Ziyuan Pang, Zhi Yang^*

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A novel, simple, eco-friendly, non-toxic aluminium catalyst was synthesised for the chemoselective reduction of α,β-unsaturated ketones. A wide range of ketones were achieved with excellent yields, mild conditions, and low catalyst loading. Furthermore, this unprecedented method allowed for the stereoselective reduction of natural ketones.

Original language	English
Pages (from-to)	4127-4131
Number of pages	5
Journal	Dalton Transactions
Volume	53
Issue number	9
DOIs	https://doi.org/10.1039/d3dt03987k
Publication status	Published - 25 Jan 2024
Externally published	Yes

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title = "Chemoselective Luche-type reduction of α,β-unsaturated ketones by aluminium hydride catalysis",

abstract = "A novel, simple, eco-friendly, non-toxic aluminium catalyst was synthesised for the chemoselective reduction of α,β-unsaturated ketones. A wide range of ketones were achieved with excellent yields, mild conditions, and low catalyst loading. Furthermore, this unprecedented method allowed for the stereoselective reduction of natural ketones.",

author = "Ben Yan and Xiaoli Ma and Ziyuan Pang and Zhi Yang",

note = "Publisher Copyright: {\textcopyright} 2024 The Royal Society of Chemistry.",

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month = jan,

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doi = "10.1039/d3dt03987k",

language = "English",

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T1 - Chemoselective Luche-type reduction of α,β-unsaturated ketones by aluminium hydride catalysis

AU - Yan, Ben

AU - Ma, Xiaoli

AU - Pang, Ziyuan

AU - Yang, Zhi

PY - 2024/1/25

Y1 - 2024/1/25

N2 - A novel, simple, eco-friendly, non-toxic aluminium catalyst was synthesised for the chemoselective reduction of α,β-unsaturated ketones. A wide range of ketones were achieved with excellent yields, mild conditions, and low catalyst loading. Furthermore, this unprecedented method allowed for the stereoselective reduction of natural ketones.

AB - A novel, simple, eco-friendly, non-toxic aluminium catalyst was synthesised for the chemoselective reduction of α,β-unsaturated ketones. A wide range of ketones were achieved with excellent yields, mild conditions, and low catalyst loading. Furthermore, this unprecedented method allowed for the stereoselective reduction of natural ketones.

UR - https://www.scopus.com/pages/publications/85184019363

U2 - 10.1039/d3dt03987k

DO - 10.1039/d3dt03987k

M3 - Article

C2 - 38315772

AN - SCOPUS:85184019363

SN - 1477-9226

VL - 53

SP - 4127

EP - 4131

JO - Dalton Transactions

JF - Dalton Transactions

IS - 9

ER -

Chemoselective Luche-type reduction of α,β-unsaturated ketones by aluminium hydride catalysis

Abstract

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