Charge-transfer complex crystal based on extended-π-conjugated acceptor and sulfur-bridged annulene: Charge-transfer interaction and remarkable high ambipolar transport characteristics

Yunke Qin; Jing Zhang; Xiaoyan Zheng; Hua Geng; Guangyao Zhao; Wei Xu; Wenping Hu; Zhigang Shuai; Daoben Zhu

doi:10.1002/adma.201400056

Charge-transfer complex crystal based on extended-π-conjugated acceptor and sulfur-bridged annulene: Charge-transfer interaction and remarkable high ambipolar transport characteristics

Yunke Qin
, Jing Zhang
, Xiaoyan Zheng
, Hua Geng
, Guangyao Zhao
, Wei Xu^*
, Wenping Hu
, Zhigang Shuai
, Daoben Zhu

^*Corresponding author for this work

CAS - Institute of Chemistry
University of Chinese Academy of Sciences
Tsinghua University

Research output: Contribution to journal › Article › peer-review

154 Citations (Scopus)

Abstract

A single crystal of a novel mixed-stack donor-acceptor complex formed by a tetracyanoquinodimethane derivative with an extended π-conjugated system and a sulfur-bridged annulene displays the highest ambipolar transport behavior among donor-acceptor complexes reported with electron and hole mobilities reaching up to 0.24 and 0.77 cm² V^-1 s^-1, respectively.

Original language	English
Pages (from-to)	4093-4099
Number of pages	7
Journal	Advanced Materials
Volume	26
Issue number	24
DOIs	https://doi.org/10.1002/adma.201400056
Publication status	Published - 25 Jun 2014
Externally published	Yes

Keywords

ambipolar transport
charge-transfer complexes
co-crystals
field-effect transistor

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10.1002/adma.201400056

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title = "Charge-transfer complex crystal based on extended-π-conjugated acceptor and sulfur-bridged annulene: Charge-transfer interaction and remarkable high ambipolar transport characteristics",

abstract = "A single crystal of a novel mixed-stack donor-acceptor complex formed by a tetracyanoquinodimethane derivative with an extended π-conjugated system and a sulfur-bridged annulene displays the highest ambipolar transport behavior among donor-acceptor complexes reported with electron and hole mobilities reaching up to 0.24 and 0.77 cm2 V-1 s-1, respectively.",

keywords = "ambipolar transport, charge-transfer complexes, co-crystals, field-effect transistor",

author = "Yunke Qin and Jing Zhang and Xiaoyan Zheng and Hua Geng and Guangyao Zhao and Wei Xu and Wenping Hu and Zhigang Shuai and Daoben Zhu",

year = "2014",

month = jun,

day = "25",

doi = "10.1002/adma.201400056",

language = "English",

volume = "26",

pages = "4093--4099",

journal = "Advanced Materials",

issn = "0935-9648",

publisher = "Wiley-Blackwell",

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}

Charge-transfer complex crystal based on extended-π-conjugated acceptor and sulfur-bridged annulene: Charge-transfer interaction and remarkable high ambipolar transport characteristics. / Qin, Yunke; Zhang, Jing; Zheng, Xiaoyan et al.
In: Advanced Materials, Vol. 26, No. 24, 25.06.2014, p. 4093-4099.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Charge-transfer complex crystal based on extended-π-conjugated acceptor and sulfur-bridged annulene

T2 - Charge-transfer interaction and remarkable high ambipolar transport characteristics

AU - Qin, Yunke

AU - Zhang, Jing

AU - Zheng, Xiaoyan

AU - Geng, Hua

AU - Zhao, Guangyao

AU - Xu, Wei

AU - Hu, Wenping

AU - Shuai, Zhigang

AU - Zhu, Daoben

PY - 2014/6/25

Y1 - 2014/6/25

N2 - A single crystal of a novel mixed-stack donor-acceptor complex formed by a tetracyanoquinodimethane derivative with an extended π-conjugated system and a sulfur-bridged annulene displays the highest ambipolar transport behavior among donor-acceptor complexes reported with electron and hole mobilities reaching up to 0.24 and 0.77 cm2 V-1 s-1, respectively.

AB - A single crystal of a novel mixed-stack donor-acceptor complex formed by a tetracyanoquinodimethane derivative with an extended π-conjugated system and a sulfur-bridged annulene displays the highest ambipolar transport behavior among donor-acceptor complexes reported with electron and hole mobilities reaching up to 0.24 and 0.77 cm2 V-1 s-1, respectively.

KW - ambipolar transport

KW - charge-transfer complexes

KW - co-crystals

KW - field-effect transistor

UR - https://www.scopus.com/pages/publications/84903159096

U2 - 10.1002/adma.201400056

DO - 10.1002/adma.201400056

M3 - Article

AN - SCOPUS:84903159096

SN - 0935-9648

VL - 26

SP - 4093

EP - 4099

JO - Advanced Materials

JF - Advanced Materials

IS - 24

ER -

Charge-transfer complex crystal based on extended-π-conjugated acceptor and sulfur-bridged annulene: Charge-transfer interaction and remarkable high ambipolar transport characteristics

Abstract

Keywords

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