Cationic scandium aminobenzyl complexes. Synthesis, structure and unprecedented catalysis of copolymerization of 1-hexene and dicyclopentadiene

Xiaofang Li; Masayoshi Nishiura; Kyouichi Mori; Tomohiro Mashiko; Zhaomin Hou

doi:10.1039/b708534f

Cationic scandium aminobenzyl complexes. Synthesis, structure and unprecedented catalysis of copolymerization of 1-hexene and dicyclopentadiene

Xiaofang Li, Masayoshi Nishiura, Kyouichi Mori, Tomohiro Mashiko, Zhaomin Hou^*

^*Corresponding author for this work

RIKEN

Research output: Contribution to journal › Article › peer-review

195 Citations (Scopus)

Abstract

A structurally well-defined THF-free cationic half-sandwich scandium aminobenzyl complex serves as a novel catalyst for the first copolymerization of 1-hexene with dicyclopentadiene to give the random copolymers with a wide range of 1-hexene contents (32-70 mol%) unavailable previously.

Original language	English
Pages (from-to)	4137-4139
Number of pages	3
Journal	Chemical Communications
Issue number	40
DOIs	https://doi.org/10.1039/b708534f
Publication status	Published - 2007
Externally published	Yes

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title = "Cationic scandium aminobenzyl complexes. Synthesis, structure and unprecedented catalysis of copolymerization of 1-hexene and dicyclopentadiene",

abstract = "A structurally well-defined THF-free cationic half-sandwich scandium aminobenzyl complex serves as a novel catalyst for the first copolymerization of 1-hexene with dicyclopentadiene to give the random copolymers with a wide range of 1-hexene contents (32-70 mol\%) unavailable previously.",

author = "Xiaofang Li and Masayoshi Nishiura and Kyouichi Mori and Tomohiro Mashiko and Zhaomin Hou",

year = "2007",

doi = "10.1039/b708534f",

language = "English",

pages = "4137--4139",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "40",

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T1 - Cationic scandium aminobenzyl complexes. Synthesis, structure and unprecedented catalysis of copolymerization of 1-hexene and dicyclopentadiene

AU - Li, Xiaofang

AU - Nishiura, Masayoshi

AU - Mori, Kyouichi

AU - Mashiko, Tomohiro

AU - Hou, Zhaomin

PY - 2007

Y1 - 2007

N2 - A structurally well-defined THF-free cationic half-sandwich scandium aminobenzyl complex serves as a novel catalyst for the first copolymerization of 1-hexene with dicyclopentadiene to give the random copolymers with a wide range of 1-hexene contents (32-70 mol%) unavailable previously.

AB - A structurally well-defined THF-free cationic half-sandwich scandium aminobenzyl complex serves as a novel catalyst for the first copolymerization of 1-hexene with dicyclopentadiene to give the random copolymers with a wide range of 1-hexene contents (32-70 mol%) unavailable previously.

UR - https://www.scopus.com/pages/publications/35248838240

U2 - 10.1039/b708534f

DO - 10.1039/b708534f

M3 - Article

AN - SCOPUS:35248838240

SN - 1359-7345

SP - 4137

EP - 4139

JO - Chemical Communications

JF - Chemical Communications

IS - 40

ER -

Cationic scandium aminobenzyl complexes. Synthesis, structure and unprecedented catalysis of copolymerization of 1-hexene and dicyclopentadiene

Abstract

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