Catena-Poly[[diaquacadmium(II)]-μ-5-carboxyimidazole-4-carboxyl-ato- κ4N1,O5:O4,N3]

Yan Qiong Sun; Jie Zhang; Guo Yu Yang

doi:10.1107/S0108270104024692

Catena-Poly[[diaquacadmium(II)]-μ-5-carboxyimidazole-4-carboxyl-ato- κ⁴N¹,O⁵:O⁴,N³]

Yan Qiong Sun
, Jie Zhang
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A new cadmium coordination polymer, [Cd(C₅H₂N ₂O₄)-(H₂O)₂]_n, possesses a one-dimensional zigzag chain structure built from Cd^II centers bridged sequentially by pairs of O and N atoms of the 5-carboxyimidazole-4- carboxylate ligand. The Cd^II center is in a distorted octahedral geometry, being coordinated by two O atoms from two coordinated water molecules [Cd-O = 2.322 (7) and 2.364 (7) Å], and by two N atoms [Cd-N = 2.222 (6) and 2.232 (6) Å] and two carboxyl O atoms [Cd-O = 2.383 (6) and 2.414 (6) Å] from two 5-carboxyimidazole-4-carboxylate ligands.

Original language	English
Pages (from-to)	m590-m591
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	60
Issue number	11
DOIs	https://doi.org/10.1107/S0108270104024692
Publication status	Published - Nov 2004
Externally published	Yes

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title = "Catena-Poly[[diaquacadmium(II)]-μ-5-carboxyimidazole-4-carboxyl-ato- κ4N1,O5:O4,N3]",

abstract = "A new cadmium coordination polymer, [Cd(C5H2N 2O4)-(H2O)2]n, possesses a one-dimensional zigzag chain structure built from CdII centers bridged sequentially by pairs of O and N atoms of the 5-carboxyimidazole-4- carboxylate ligand. The CdII center is in a distorted octahedral geometry, being coordinated by two O atoms from two coordinated water molecules [Cd-O = 2.322 (7) and 2.364 (7) {\AA}], and by two N atoms [Cd-N = 2.222 (6) and 2.232 (6) {\AA}] and two carboxyl O atoms [Cd-O = 2.383 (6) and 2.414 (6) {\AA}] from two 5-carboxyimidazole-4-carboxylate ligands.",

author = "Sun, \{Yan Qiong\} and Jie Zhang and Yang, \{Guo Yu\}",

year = "2004",

month = nov,

doi = "10.1107/S0108270104024692",

language = "English",

volume = "60",

pages = "m590--m591",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "11",

}

TY - JOUR

T1 - Catena-Poly[[diaquacadmium(II)]-μ-5-carboxyimidazole-4-carboxyl-ato- κ4N1,O5:O4,N3]

AU - Sun, Yan Qiong

AU - Zhang, Jie

AU - Yang, Guo Yu

PY - 2004/11

Y1 - 2004/11

N2 - A new cadmium coordination polymer, [Cd(C5H2N 2O4)-(H2O)2]n, possesses a one-dimensional zigzag chain structure built from CdII centers bridged sequentially by pairs of O and N atoms of the 5-carboxyimidazole-4- carboxylate ligand. The CdII center is in a distorted octahedral geometry, being coordinated by two O atoms from two coordinated water molecules [Cd-O = 2.322 (7) and 2.364 (7) Å], and by two N atoms [Cd-N = 2.222 (6) and 2.232 (6) Å] and two carboxyl O atoms [Cd-O = 2.383 (6) and 2.414 (6) Å] from two 5-carboxyimidazole-4-carboxylate ligands.

AB - A new cadmium coordination polymer, [Cd(C5H2N 2O4)-(H2O)2]n, possesses a one-dimensional zigzag chain structure built from CdII centers bridged sequentially by pairs of O and N atoms of the 5-carboxyimidazole-4- carboxylate ligand. The CdII center is in a distorted octahedral geometry, being coordinated by two O atoms from two coordinated water molecules [Cd-O = 2.322 (7) and 2.364 (7) Å], and by two N atoms [Cd-N = 2.222 (6) and 2.232 (6) Å] and two carboxyl O atoms [Cd-O = 2.383 (6) and 2.414 (6) Å] from two 5-carboxyimidazole-4-carboxylate ligands.

UR - https://www.scopus.com/pages/publications/9744235879

U2 - 10.1107/S0108270104024692

DO - 10.1107/S0108270104024692

M3 - Article

AN - SCOPUS:9744235879

SN - 0108-2701

VL - 60

SP - m590-m591

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 11

ER -

Catena-Poly[[diaquacadmium(II)]-μ-5-carboxyimidazole-4-carboxyl-ato- κ⁴N¹,O⁵:O⁴,N³]

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