Carbon-carbon bond cleavage by strongly electrophilic boranes

Bao Hua Xu; Gerald Kehr; Roland Fröhlich; Gerhard Erker

doi:10.1002/chem.201002047

Carbon-carbon bond cleavage by strongly electrophilic boranes

Bao Hua Xu, Gerald Kehr, Roland Fröhlich, Gerhard Erker^*

^*Corresponding author for this work

University of Münster

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Make and break: Strongly electrophilic boranes RB(C₆F ₅)₂ (R=Me, CH₂CH₂Ph) react with an aminodihydropentalene substrate by C=C bond cleavage with concomitant borylene insertion to yield the ring-enlarged zwitterionic borate/iminium product.

Original language	English
Pages (from-to)	12538-12540
Number of pages	3
Journal	Chemistry - A European Journal
Volume	16
Issue number	42
DOIs	https://doi.org/10.1002/chem.201002047
Publication status	Published - 8 Nov 2010
Externally published	Yes

Keywords

C-C activation
boranes
carboboration
ring expansion

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10.1002/chem.201002047

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title = "Carbon-carbon bond cleavage by strongly electrophilic boranes",

abstract = "Make and break: Strongly electrophilic boranes RB(C6F 5)2 (R=Me, CH2CH2Ph) react with an aminodihydropentalene substrate by C=C bond cleavage with concomitant borylene insertion to yield the ring-enlarged zwitterionic borate/iminium product.",

keywords = "C-C activation, boranes, carboboration, ring expansion",

author = "Xu, {Bao Hua} and Gerald Kehr and Roland Fr{\"o}hlich and Gerhard Erker",

year = "2010",

month = nov,

day = "8",

doi = "10.1002/chem.201002047",

language = "English",

volume = "16",

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journal = "Chemistry - A European Journal",

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T1 - Carbon-carbon bond cleavage by strongly electrophilic boranes

AU - Xu, Bao Hua

AU - Kehr, Gerald

AU - Fröhlich, Roland

AU - Erker, Gerhard

PY - 2010/11/8

Y1 - 2010/11/8

N2 - Make and break: Strongly electrophilic boranes RB(C6F 5)2 (R=Me, CH2CH2Ph) react with an aminodihydropentalene substrate by C=C bond cleavage with concomitant borylene insertion to yield the ring-enlarged zwitterionic borate/iminium product.

AB - Make and break: Strongly electrophilic boranes RB(C6F 5)2 (R=Me, CH2CH2Ph) react with an aminodihydropentalene substrate by C=C bond cleavage with concomitant borylene insertion to yield the ring-enlarged zwitterionic borate/iminium product.

KW - C-C activation

KW - boranes

KW - carboboration

KW - ring expansion

UR - http://www.scopus.com/inward/record.url?scp=78249274226&partnerID=8YFLogxK

U2 - 10.1002/chem.201002047

DO - 10.1002/chem.201002047

M3 - Article

AN - SCOPUS:78249274226

SN - 0947-6539

VL - 16

SP - 12538

EP - 12540

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 42

ER -

Carbon-carbon bond cleavage by strongly electrophilic boranes

Abstract

Keywords

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