B3O4(OH) · 0.5(C4H10N2): First organic-inorganic hybrid borate with a neutral layered framework

Guang Zhen Liu; Shou Tian Zheng; Guo Yu Yang

doi:10.1016/j.inoche.2006.09.021

B₃O₄(OH) · 0.5(C₄H₁₀N₂): First organic-inorganic hybrid borate with a neutral layered framework

Guang Zhen Liu
, Shou Tian Zheng
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Abstract

A novel hybrid borate B₃O₄(OH) · 0.5(C₄H₁₀N₂) 1 was synthesized under milder hydrothermal conditions. The product was characterized by a combination of elemental analysis, FT-IR, thermogravimetric analysis and powder X-ray diffraction, as well as single-crystal X-ray diffraction studies. The structure consists of two types of inorganic borate helices cohered by piperazine rings, giving rise to a neutral hybrid sheet. The adjacent layers are stacked in a parallel fashion and further stabilized by hydrogen bonding interactions.

Original language	English
Pages (from-to)	84-87
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	10
Issue number	1
DOIs	https://doi.org/10.1016/j.inoche.2006.09.021
Publication status	Published - Jan 2007
Externally published	Yes

Keywords

Borates
Crystal structure
Hydrothermal synthesis
Inorganic-organic hybrid

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10.1016/j.inoche.2006.09.021

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title = "B3O4(OH) · 0.5(C4H10N2): First organic-inorganic hybrid borate with a neutral layered framework",

abstract = "A novel hybrid borate B3O4(OH) · 0.5(C4H10N2) 1 was synthesized under milder hydrothermal conditions. The product was characterized by a combination of elemental analysis, FT-IR, thermogravimetric analysis and powder X-ray diffraction, as well as single-crystal X-ray diffraction studies. The structure consists of two types of inorganic borate helices cohered by piperazine rings, giving rise to a neutral hybrid sheet. The adjacent layers are stacked in a parallel fashion and further stabilized by hydrogen bonding interactions.",

keywords = "Borates, Crystal structure, Hydrothermal synthesis, Inorganic-organic hybrid",

author = "Liu, \{Guang Zhen\} and Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

year = "2007",

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doi = "10.1016/j.inoche.2006.09.021",

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pages = "84--87",

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T2 - First organic-inorganic hybrid borate with a neutral layered framework

AU - Liu, Guang Zhen

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2007/1

Y1 - 2007/1

N2 - A novel hybrid borate B3O4(OH) · 0.5(C4H10N2) 1 was synthesized under milder hydrothermal conditions. The product was characterized by a combination of elemental analysis, FT-IR, thermogravimetric analysis and powder X-ray diffraction, as well as single-crystal X-ray diffraction studies. The structure consists of two types of inorganic borate helices cohered by piperazine rings, giving rise to a neutral hybrid sheet. The adjacent layers are stacked in a parallel fashion and further stabilized by hydrogen bonding interactions.

AB - A novel hybrid borate B3O4(OH) · 0.5(C4H10N2) 1 was synthesized under milder hydrothermal conditions. The product was characterized by a combination of elemental analysis, FT-IR, thermogravimetric analysis and powder X-ray diffraction, as well as single-crystal X-ray diffraction studies. The structure consists of two types of inorganic borate helices cohered by piperazine rings, giving rise to a neutral hybrid sheet. The adjacent layers are stacked in a parallel fashion and further stabilized by hydrogen bonding interactions.

KW - Borates

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Inorganic-organic hybrid

UR - https://www.scopus.com/pages/publications/33845185993

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DO - 10.1016/j.inoche.2006.09.021

M3 - Article

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SN - 1387-7003

VL - 10

SP - 84

EP - 87

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 1

ER -

B₃O₄(OH) · 0.5(C₄H₁₀N₂): First organic-inorganic hybrid borate with a neutral layered framework

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Keywords

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