Bis[benzidinium(1-)] pentamolybdate

Shu Fang Zhang; Yan Qiong Sun; Guo Yu Yang

doi:10.1107/S010827010401090X

Bis[benzidinium(1-)] pentamolybdate

Shu Fang Zhang
, Yan Qiong Sun
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter
Nanjing University

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The title compound, {(C₁₂H₁₃N₂) ₂[Mo₅O₁₆]}_n, was synthesized under hydrothermal conditions. The structure contains a two-dimensional layer, constructed from [(Mo₄O₁₄)_n]^4n- chains linked through MoO₆ octahedra, which lie across twofold axes. The [(Mo₄O₁₄)_n]^4n- chain consists of [Mo₄O₁₄]^4- clusters connected to one another by sharing their MoO₅ square-pyramidal and MoO₆ octahedral vertices in an anti disposition. The layers are linked by the cation, to which they are connected via N-H⋯O hydrogen bonds.

Original language	English
Pages (from-to)	m299-m301
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	60
Issue number	7
DOIs	https://doi.org/10.1107/S010827010401090X
Publication status	Published - Jul 2004
Externally published	Yes

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@article{b41ab48c7f1547eba4949d7d8e48ef27,

title = "Bis[benzidinium(1-)] pentamolybdate",

abstract = "The title compound, \{(C12H13N2) 2[Mo5O16]\}n, was synthesized under hydrothermal conditions. The structure contains a two-dimensional layer, constructed from [(Mo4O14)n]4n- chains linked through MoO6 octahedra, which lie across twofold axes. The [(Mo4O14)n]4n- chain consists of [Mo4O14]4- clusters connected to one another by sharing their MoO5 square-pyramidal and MoO6 octahedral vertices in an anti disposition. The layers are linked by the cation, to which they are connected via N-H⋯O hydrogen bonds.",

author = "Zhang, \{Shu Fang\} and Sun, \{Yan Qiong\} and Yang, \{Guo Yu\}",

year = "2004",

month = jul,

doi = "10.1107/S010827010401090X",

language = "English",

volume = "60",

pages = "m299--m301",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "7",

}

TY - JOUR

T1 - Bis[benzidinium(1-)] pentamolybdate

AU - Zhang, Shu Fang

AU - Sun, Yan Qiong

AU - Yang, Guo Yu

PY - 2004/7

Y1 - 2004/7

N2 - The title compound, {(C12H13N2) 2[Mo5O16]}n, was synthesized under hydrothermal conditions. The structure contains a two-dimensional layer, constructed from [(Mo4O14)n]4n- chains linked through MoO6 octahedra, which lie across twofold axes. The [(Mo4O14)n]4n- chain consists of [Mo4O14]4- clusters connected to one another by sharing their MoO5 square-pyramidal and MoO6 octahedral vertices in an anti disposition. The layers are linked by the cation, to which they are connected via N-H⋯O hydrogen bonds.

AB - The title compound, {(C12H13N2) 2[Mo5O16]}n, was synthesized under hydrothermal conditions. The structure contains a two-dimensional layer, constructed from [(Mo4O14)n]4n- chains linked through MoO6 octahedra, which lie across twofold axes. The [(Mo4O14)n]4n- chain consists of [Mo4O14]4- clusters connected to one another by sharing their MoO5 square-pyramidal and MoO6 octahedral vertices in an anti disposition. The layers are linked by the cation, to which they are connected via N-H⋯O hydrogen bonds.

UR - https://www.scopus.com/pages/publications/3242790883

U2 - 10.1107/S010827010401090X

DO - 10.1107/S010827010401090X

M3 - Article

AN - SCOPUS:3242790883

SN - 0108-2701

VL - 60

SP - m299-m301

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 7

ER -

Bis[benzidinium(1-)] pentamolybdate

Abstract

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