Bipyridine conformations control the solid-state supramolecular chemistry of zinc(II) phthalocyanine with bipyridines

Qingdao Zeng; Dongxia Wu; Chen Wang; Jun Lu; Baocheng Ma; Chunying Shu; Hongwei Ma; Yan Li; Chunli Bai

doi:10.1039/b502587g

Bipyridine conformations control the solid-state supramolecular chemistry of zinc(II) phthalocyanine with bipyridines

Qingdao Zeng^*, Dongxia Wu, Chen Wang, Jun Lu, Baocheng Ma, Chunying Shu, Hongwei Ma, Yan Li, Chunli Bai

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

Two H-shaped supramolecular complexes (C₃₂H₁₆N ₈Zn)₂Â·(C₁₂H₁₂N ₂)Â·0.96H₂O (1), (C₃₂H ₁₆N₈Zn)₂Â·(C₁₂H ₁₀N₂)Â·(DMF)₂ (2), and one T-shaped supramolecular complex C₃₂H₁₆N ₈ZnÂ·C₁₃H₁₄N₂ (3) have been prepared from zinc(II) phthalocyanine with 1,2-bis(4-pyridyl)ethane (bipy-eta), 1,2-di(4-pyridyl)ethylene (dipy-ete) or 1,3-di(4-pyridyl)propane (dipy-pra), respectively, and characterized by single-crystal X-ray diffraction, electronic absorption spectra and fluorescence spectra; the conformation of the bipyridines plays an important role in the assembly processes.

Original language	English
Article number	38
Pages (from-to)	243-248
Number of pages	6
Journal	CrystEngComm
Volume	7
DOIs	https://doi.org/10.1039/b502587g
Publication status	Published - 24 Mar 2005
Externally published	Yes

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title = "Bipyridine conformations control the solid-state supramolecular chemistry of zinc(II) phthalocyanine with bipyridines",

abstract = "Two H-shaped supramolecular complexes (C32H16N 8Zn)2{\^A}·(C12H12N 2){\^A}·0.96H2O (1), (C32H 16N8Zn)2{\^A}·(C12H 10N2){\^A}·(DMF)2 (2), and one T-shaped supramolecular complex C32H16N 8Zn{\^A}·C13H14N2 (3) have been prepared from zinc(II) phthalocyanine with 1,2-bis(4-pyridyl)ethane (bipy-eta), 1,2-di(4-pyridyl)ethylene (dipy-ete) or 1,3-di(4-pyridyl)propane (dipy-pra), respectively, and characterized by single-crystal X-ray diffraction, electronic absorption spectra and fluorescence spectra; the conformation of the bipyridines plays an important role in the assembly processes.",

author = "Qingdao Zeng and Dongxia Wu and Chen Wang and Jun Lu and Baocheng Ma and Chunying Shu and Hongwei Ma and Yan Li and Chunli Bai",

year = "2005",

month = mar,

day = "24",

doi = "10.1039/b502587g",

language = "English",

volume = "7",

pages = "243--248",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Bipyridine conformations control the solid-state supramolecular chemistry of zinc(II) phthalocyanine with bipyridines

AU - Zeng, Qingdao

AU - Wu, Dongxia

AU - Wang, Chen

AU - Lu, Jun

AU - Ma, Baocheng

AU - Shu, Chunying

AU - Ma, Hongwei

AU - Li, Yan

AU - Bai, Chunli

PY - 2005/3/24

Y1 - 2005/3/24

N2 - Two H-shaped supramolecular complexes (C32H16N 8Zn)2Â·(C12H12N 2)Â·0.96H2O (1), (C32H 16N8Zn)2Â·(C12H 10N2)Â·(DMF)2 (2), and one T-shaped supramolecular complex C32H16N 8ZnÂ·C13H14N2 (3) have been prepared from zinc(II) phthalocyanine with 1,2-bis(4-pyridyl)ethane (bipy-eta), 1,2-di(4-pyridyl)ethylene (dipy-ete) or 1,3-di(4-pyridyl)propane (dipy-pra), respectively, and characterized by single-crystal X-ray diffraction, electronic absorption spectra and fluorescence spectra; the conformation of the bipyridines plays an important role in the assembly processes.

AB - Two H-shaped supramolecular complexes (C32H16N 8Zn)2Â·(C12H12N 2)Â·0.96H2O (1), (C32H 16N8Zn)2Â·(C12H 10N2)Â·(DMF)2 (2), and one T-shaped supramolecular complex C32H16N 8ZnÂ·C13H14N2 (3) have been prepared from zinc(II) phthalocyanine with 1,2-bis(4-pyridyl)ethane (bipy-eta), 1,2-di(4-pyridyl)ethylene (dipy-ete) or 1,3-di(4-pyridyl)propane (dipy-pra), respectively, and characterized by single-crystal X-ray diffraction, electronic absorption spectra and fluorescence spectra; the conformation of the bipyridines plays an important role in the assembly processes.

UR - http://www.scopus.com/inward/record.url?scp=19344365402&partnerID=8YFLogxK

U2 - 10.1039/b502587g

DO - 10.1039/b502587g

M3 - Article

AN - SCOPUS:19344365402

SN - 1466-8033

VL - 7

SP - 243

EP - 248

JO - CrystEngComm

JF - CrystEngComm

M1 - 38

ER -

Bipyridine conformations control the solid-state supramolecular chemistry of zinc(II) phthalocyanine with bipyridines

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