Binary mixture isothermal vapour-liquid equilibrium: Trifluoromethane (R23) + octafluoropropane (R218) at the temperature from 223.150 K to 263.150 K

Yunxiao Wang; Xian Wang; Yanxing Zhao; Maoqiong Gong; Xiaoyu Yao; Xueqiang Dong

doi:10.1016/j.jct.2021.106567

Binary mixture isothermal vapour-liquid equilibrium: Trifluoromethane (R23) + octafluoropropane (R218) at the temperature from 223.150 K to 263.150 K

Yunxiao Wang, Xian Wang, Yanxing Zhao^*, Maoqiong Gong, Xiaoyu Yao, Xueqiang Dong

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The mixed-refrigerant Joule-Thomson refrigerator (MJTR) is simple in structure, safe and reliable, and is suitable for temperatures from 80 to 230 K. Trifluoromethane (R23) and octafluoropropane (R218) are satisfactory as non-flammable refrigerants in MJTR. In this paper, the gas-phase single-cycle method was used to conduct a vapor–liquid equilibrium (VLE) experiment on the R23 + R218 binary system in the temperature range from 223.150 K to 263.150 K. The VLE experimental data were correlated using the Peng-Robinson (PR) equation of state and the Huron-Vidal (HV) mixing rule combined with non-random two-liquid (NRTL) activity coefficient model. The maximum average absolute relative deviation of pressure (AARDp) and the maximum average absolute deviation of vapor phase composition (AADy) are 0.67% and 0.005, respectively.

Original language	English
Article number	106567
Journal	Journal of Chemical Thermodynamics
Volume	162
DOIs	https://doi.org/10.1016/j.jct.2021.106567
Publication status	Published - Nov 2021
Externally published	Yes

Keywords

Non-azeotropic
Non-flammable refrigerants
Octafluoropropane (R218)
Trifluoromethane (R23)
Vapor liquid equilibrium (VLE)

Access to Document

10.1016/j.jct.2021.106567

Cite this

@article{1d50a9951ed3470983306ec22dcbaf0f,

title = "Binary mixture isothermal vapour-liquid equilibrium: Trifluoromethane (R23) + octafluoropropane (R218) at the temperature from 223.150 K to 263.150 K",

abstract = "The mixed-refrigerant Joule-Thomson refrigerator (MJTR) is simple in structure, safe and reliable, and is suitable for temperatures from 80 to 230 K. Trifluoromethane (R23) and octafluoropropane (R218) are satisfactory as non-flammable refrigerants in MJTR. In this paper, the gas-phase single-cycle method was used to conduct a vapor–liquid equilibrium (VLE) experiment on the R23 + R218 binary system in the temperature range from 223.150 K to 263.150 K. The VLE experimental data were correlated using the Peng-Robinson (PR) equation of state and the Huron-Vidal (HV) mixing rule combined with non-random two-liquid (NRTL) activity coefficient model. The maximum average absolute relative deviation of pressure (AARDp) and the maximum average absolute deviation of vapor phase composition (AADy) are 0.67\% and 0.005, respectively.",

keywords = "Non-azeotropic, Non-flammable refrigerants, Octafluoropropane (R218), Trifluoromethane (R23), Vapor liquid equilibrium (VLE)",

author = "Yunxiao Wang and Xian Wang and Yanxing Zhao and Maoqiong Gong and Xiaoyu Yao and Xueqiang Dong",

note = "Publisher Copyright: {\textcopyright} 2021 Elsevier Ltd",

year = "2021",

month = nov,

doi = "10.1016/j.jct.2021.106567",

language = "English",

volume = "162",

journal = "Journal of Chemical Thermodynamics",

issn = "0021-9614",

publisher = "Academic Press",

}

TY - JOUR

T1 - Binary mixture isothermal vapour-liquid equilibrium

T2 - Trifluoromethane (R23) + octafluoropropane (R218) at the temperature from 223.150 K to 263.150 K

AU - Wang, Yunxiao

AU - Wang, Xian

AU - Zhao, Yanxing

AU - Gong, Maoqiong

AU - Yao, Xiaoyu

AU - Dong, Xueqiang

PY - 2021/11

Y1 - 2021/11

N2 - The mixed-refrigerant Joule-Thomson refrigerator (MJTR) is simple in structure, safe and reliable, and is suitable for temperatures from 80 to 230 K. Trifluoromethane (R23) and octafluoropropane (R218) are satisfactory as non-flammable refrigerants in MJTR. In this paper, the gas-phase single-cycle method was used to conduct a vapor–liquid equilibrium (VLE) experiment on the R23 + R218 binary system in the temperature range from 223.150 K to 263.150 K. The VLE experimental data were correlated using the Peng-Robinson (PR) equation of state and the Huron-Vidal (HV) mixing rule combined with non-random two-liquid (NRTL) activity coefficient model. The maximum average absolute relative deviation of pressure (AARDp) and the maximum average absolute deviation of vapor phase composition (AADy) are 0.67% and 0.005, respectively.

AB - The mixed-refrigerant Joule-Thomson refrigerator (MJTR) is simple in structure, safe and reliable, and is suitable for temperatures from 80 to 230 K. Trifluoromethane (R23) and octafluoropropane (R218) are satisfactory as non-flammable refrigerants in MJTR. In this paper, the gas-phase single-cycle method was used to conduct a vapor–liquid equilibrium (VLE) experiment on the R23 + R218 binary system in the temperature range from 223.150 K to 263.150 K. The VLE experimental data were correlated using the Peng-Robinson (PR) equation of state and the Huron-Vidal (HV) mixing rule combined with non-random two-liquid (NRTL) activity coefficient model. The maximum average absolute relative deviation of pressure (AARDp) and the maximum average absolute deviation of vapor phase composition (AADy) are 0.67% and 0.005, respectively.

KW - Non-azeotropic

KW - Non-flammable refrigerants

KW - Octafluoropropane (R218)

KW - Trifluoromethane (R23)

KW - Vapor liquid equilibrium (VLE)

UR - https://www.scopus.com/pages/publications/85110369664

U2 - 10.1016/j.jct.2021.106567

DO - 10.1016/j.jct.2021.106567

M3 - Article

AN - SCOPUS:85110369664

SN - 0021-9614

VL - 162

JO - Journal of Chemical Thermodynamics

JF - Journal of Chemical Thermodynamics

M1 - 106567

ER -

Binary mixture isothermal vapour-liquid equilibrium: Trifluoromethane (R23) + octafluoropropane (R218) at the temperature from 223.150 K to 263.150 K

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this