Bilayer architecture based on hexanuclear heterometal cluster units

Wei Hui Fang; Guo Yu Yang

doi:10.1039/c4ce00747f

Bilayer architecture based on hexanuclear heterometal cluster units

Wei Hui Fang
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The first bilayer architecture based on the hexanuclear heterometal cluster units [EuCu^II₂Cu^I(μ₃-OH)(μ- OH)L₄(ClO₄)(H₂O)]·ClO ₄·3H₂O (1, L = 4-pyridin-4-yl-benzoate), was hydrothermally made and characterized. One prominent feature is that the nodes are heterometal hexanuclear clusters (Eu^III₂Cu ^II₄) rather than mono-metal ions, in which the heterometal clusters are in a "head-to-head" arrangement. Another feature is the linkages between the monolayers: instead of the generally used organic linkers, the linkers here are [Cu^IL₂] motifs. Moreover, their orientation is opposite: the organic linkers in the literature are approximately vertical to the monolayers, while the [Cu^IL₂] motifs here are parallel to the monolayers. Charge balance is achieved by both non-coordinating and coordinating ClO₄^- anions. This journal is

Original language	English
Pages (from-to)	6790-6796
Number of pages	7
Journal	CrystEngComm
Volume	16
Issue number	29
DOIs	https://doi.org/10.1039/c4ce00747f
Publication status	Published - 7 Aug 2014
Externally published	Yes

Access to Document

10.1039/c4ce00747f

Cite this

@article{70fb12593043417db46f6a11687092ac,

title = "Bilayer architecture based on hexanuclear heterometal cluster units",

abstract = "The first bilayer architecture based on the hexanuclear heterometal cluster units [EuCuII2CuI(μ3-OH)(μ- OH)L4(ClO4)(H2O)]·ClO 4·3H2O (1, L = 4-pyridin-4-yl-benzoate), was hydrothermally made and characterized. One prominent feature is that the nodes are heterometal hexanuclear clusters (EuIII2Cu II4) rather than mono-metal ions, in which the heterometal clusters are in a {"}head-to-head{"} arrangement. Another feature is the linkages between the monolayers: instead of the generally used organic linkers, the linkers here are [CuIL2] motifs. Moreover, their orientation is opposite: the organic linkers in the literature are approximately vertical to the monolayers, while the [CuIL2] motifs here are parallel to the monolayers. Charge balance is achieved by both non-coordinating and coordinating ClO4- anions. This journal is",

author = "Fang, \{Wei Hui\} and Yang, \{Guo Yu\}",

year = "2014",

month = aug,

day = "7",

doi = "10.1039/c4ce00747f",

language = "English",

volume = "16",

pages = "6790--6796",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "29",

}

TY - JOUR

T1 - Bilayer architecture based on hexanuclear heterometal cluster units

AU - Fang, Wei Hui

AU - Yang, Guo Yu

PY - 2014/8/7

Y1 - 2014/8/7

N2 - The first bilayer architecture based on the hexanuclear heterometal cluster units [EuCuII2CuI(μ3-OH)(μ- OH)L4(ClO4)(H2O)]·ClO 4·3H2O (1, L = 4-pyridin-4-yl-benzoate), was hydrothermally made and characterized. One prominent feature is that the nodes are heterometal hexanuclear clusters (EuIII2Cu II4) rather than mono-metal ions, in which the heterometal clusters are in a "head-to-head" arrangement. Another feature is the linkages between the monolayers: instead of the generally used organic linkers, the linkers here are [CuIL2] motifs. Moreover, their orientation is opposite: the organic linkers in the literature are approximately vertical to the monolayers, while the [CuIL2] motifs here are parallel to the monolayers. Charge balance is achieved by both non-coordinating and coordinating ClO4- anions. This journal is

AB - The first bilayer architecture based on the hexanuclear heterometal cluster units [EuCuII2CuI(μ3-OH)(μ- OH)L4(ClO4)(H2O)]·ClO 4·3H2O (1, L = 4-pyridin-4-yl-benzoate), was hydrothermally made and characterized. One prominent feature is that the nodes are heterometal hexanuclear clusters (EuIII2Cu II4) rather than mono-metal ions, in which the heterometal clusters are in a "head-to-head" arrangement. Another feature is the linkages between the monolayers: instead of the generally used organic linkers, the linkers here are [CuIL2] motifs. Moreover, their orientation is opposite: the organic linkers in the literature are approximately vertical to the monolayers, while the [CuIL2] motifs here are parallel to the monolayers. Charge balance is achieved by both non-coordinating and coordinating ClO4- anions. This journal is

UR - https://www.scopus.com/pages/publications/84903746833

U2 - 10.1039/c4ce00747f

DO - 10.1039/c4ce00747f

M3 - Article

AN - SCOPUS:84903746833

SN - 1466-8033

VL - 16

SP - 6790

EP - 6796

JO - CrystEngComm

JF - CrystEngComm

IS - 29

ER -

Bilayer architecture based on hexanuclear heterometal cluster units

Abstract

Access to Document

Other files and links

Fingerprint

Cite this