Azo-linked porous organic polymers: Robust and time-efficient synthesis: Via NaBH4-mediated reductive homocoupling on polynitro monomers and adsorption capacity towards aniline in water

Jin Xiu Zhou; Xian Sheng Luo; Xiangxiang Liu; Yan Qiao; Pengfei Wang; David Mecerreyes; Nicolas Bogliotti; Shi Lu Chen; Mu Hua Huang

doi:10.1039/c8ta00341f

Azo-linked porous organic polymers: Robust and time-efficient synthesis: Via NaBH₄-mediated reductive homocoupling on polynitro monomers and adsorption capacity towards aniline in water

Jin Xiu Zhou, Xian Sheng Luo, Xiangxiang Liu^*, Yan Qiao, Pengfei Wang, David Mecerreyes, Nicolas Bogliotti, Shi Lu Chen, Mu Hua Huang

^*Corresponding author for this work

School of Material Science and Engineering

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

Time-efficient synthetic methods of porous organic polymers are searched in order to extend the applications of these materials. In this work, we show a robust and time-efficient synthetic method of azo-linked porous organic polymers named Azo-POPs based on a NaBH₄-mediated reductive coupling polymerization on well-known polynitro monomers. Azo-POPs were found to have a high Brunauer-Emmett-Teller (BET) surface area and potential for aniline adsorption. Interestingly, Azo-POP-1 showed adsorption capacity towards aniline as high as 1059.68 mg g^-1 at 293 K, which surpassed that of adsorbent materials reported in the literature.

Original language	English
Pages (from-to)	5608-5612
Number of pages	5
Journal	Journal of Materials Chemistry A
Volume	6
Issue number	14
DOIs	https://doi.org/10.1039/c8ta00341f
Publication status	Published - 14 Apr 2018

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Zhou, J. X., Luo, X. S., Liu, X., Qiao, Y., Wang, P., Mecerreyes, D., Bogliotti, N., Chen, S. L., & Huang, M. H. (2018). Azo-linked porous organic polymers: Robust and time-efficient synthesis: Via NaBH₄-mediated reductive homocoupling on polynitro monomers and adsorption capacity towards aniline in water. Journal of Materials Chemistry A, 6(14), 5608-5612. https://doi.org/10.1039/c8ta00341f

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title = "Azo-linked porous organic polymers: Robust and time-efficient synthesis: Via NaBH4-mediated reductive homocoupling on polynitro monomers and adsorption capacity towards aniline in water",

abstract = "Time-efficient synthetic methods of porous organic polymers are searched in order to extend the applications of these materials. In this work, we show a robust and time-efficient synthetic method of azo-linked porous organic polymers named Azo-POPs based on a NaBH4-mediated reductive coupling polymerization on well-known polynitro monomers. Azo-POPs were found to have a high Brunauer-Emmett-Teller (BET) surface area and potential for aniline adsorption. Interestingly, Azo-POP-1 showed adsorption capacity towards aniline as high as 1059.68 mg g-1 at 293 K, which surpassed that of adsorbent materials reported in the literature.",

author = "Zhou, \{Jin Xiu\} and Luo, \{Xian Sheng\} and Xiangxiang Liu and Yan Qiao and Pengfei Wang and David Mecerreyes and Nicolas Bogliotti and Chen, \{Shi Lu\} and Huang, \{Mu Hua\}",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

month = apr,

day = "14",

doi = "10.1039/c8ta00341f",

language = "English",

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Zhou, JX, Luo, XS, Liu, X, Qiao, Y, Wang, P, Mecerreyes, D, Bogliotti, N, Chen, SL & Huang, MH 2018, 'Azo-linked porous organic polymers: Robust and time-efficient synthesis: Via NaBH₄-mediated reductive homocoupling on polynitro monomers and adsorption capacity towards aniline in water', Journal of Materials Chemistry A, vol. 6, no. 14, pp. 5608-5612. https://doi.org/10.1039/c8ta00341f

Azo-linked porous organic polymers: Robust and time-efficient synthesis: Via NaBH₄-mediated reductive homocoupling on polynitro monomers and adsorption capacity towards aniline in water. / Zhou, Jin Xiu; Luo, Xian Sheng; Liu, Xiangxiang et al.
In: Journal of Materials Chemistry A, Vol. 6, No. 14, 14.04.2018, p. 5608-5612.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Azo-linked porous organic polymers

T2 - Robust and time-efficient synthesis: Via NaBH4-mediated reductive homocoupling on polynitro monomers and adsorption capacity towards aniline in water

AU - Zhou, Jin Xiu

AU - Luo, Xian Sheng

AU - Liu, Xiangxiang

AU - Qiao, Yan

AU - Wang, Pengfei

AU - Mecerreyes, David

AU - Bogliotti, Nicolas

AU - Chen, Shi Lu

AU - Huang, Mu Hua

PY - 2018/4/14

Y1 - 2018/4/14

N2 - Time-efficient synthetic methods of porous organic polymers are searched in order to extend the applications of these materials. In this work, we show a robust and time-efficient synthetic method of azo-linked porous organic polymers named Azo-POPs based on a NaBH4-mediated reductive coupling polymerization on well-known polynitro monomers. Azo-POPs were found to have a high Brunauer-Emmett-Teller (BET) surface area and potential for aniline adsorption. Interestingly, Azo-POP-1 showed adsorption capacity towards aniline as high as 1059.68 mg g-1 at 293 K, which surpassed that of adsorbent materials reported in the literature.

AB - Time-efficient synthetic methods of porous organic polymers are searched in order to extend the applications of these materials. In this work, we show a robust and time-efficient synthetic method of azo-linked porous organic polymers named Azo-POPs based on a NaBH4-mediated reductive coupling polymerization on well-known polynitro monomers. Azo-POPs were found to have a high Brunauer-Emmett-Teller (BET) surface area and potential for aniline adsorption. Interestingly, Azo-POP-1 showed adsorption capacity towards aniline as high as 1059.68 mg g-1 at 293 K, which surpassed that of adsorbent materials reported in the literature.

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DO - 10.1039/c8ta00341f

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VL - 6

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JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 14

ER -

Azo-linked porous organic polymers: Robust and time-efficient synthesis: Via NaBH₄-mediated reductive homocoupling on polynitro monomers and adsorption capacity towards aniline in water

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