Assembly of two supramolecular structures by metal complexes with a urea-based pyridyl ligand

Biao Wu; Xiaojuan Huang; Jianjun Liang; Yanyan Liu; Xiao Juan Yang; Huai Ming Hu

doi:10.1016/j.inoche.2007.01.026

Assembly of two supramolecular structures by metal complexes with a urea-based pyridyl ligand

Biao Wu^*
, Xiaojuan Huang
, Jianjun Liang
, Yanyan Liu
, Xiao Juan Yang
, Huai Ming Hu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

The supramolecular structures of two metal complexes, [CuL₄Cl₂] (1) and [ZnL₂Cl₂] (2), where L = N-(2,6-dimethylphenyl)-N′-(3-pyridy1)urea, are reported. Complex 1 features infinite tapes formed by intermolecular N-H⋯Cl hydrogen bonds with an R₂¹(6) motif, as well as a π-π stacking interaction. The solid-state structure of 2 shows a 2D network held together by two types of N-H⋯O R₂¹(6) motifs, and there is no significant interaction between the NH groups and the metal-bound Cl^- ions.

Original language	English
Pages (from-to)	563-566
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	10
Issue number	5
DOIs	https://doi.org/10.1016/j.inoche.2007.01.026
Publication status	Published - May 2007
Externally published	Yes

Keywords

Copper(II)
Hydrogen bonding
Pyridyl urea
Zinc(II)
π-π Stacking

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10.1016/j.inoche.2007.01.026

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@article{18a2153b52c949bab93c88be3f920dbe,

title = "Assembly of two supramolecular structures by metal complexes with a urea-based pyridyl ligand",

abstract = "The supramolecular structures of two metal complexes, [CuL4Cl2] (1) and [ZnL2Cl2] (2), where L = N-(2,6-dimethylphenyl)-N′-(3-pyridy1)urea, are reported. Complex 1 features infinite tapes formed by intermolecular N-H⋯Cl hydrogen bonds with an R21(6) motif, as well as a π-π stacking interaction. The solid-state structure of 2 shows a 2D network held together by two types of N-H⋯O R21(6) motifs, and there is no significant interaction between the NH groups and the metal-bound Cl- ions.",

keywords = "Copper(II), Hydrogen bonding, Pyridyl urea, Zinc(II), π-π Stacking",

author = "Biao Wu and Xiaojuan Huang and Jianjun Liang and Yanyan Liu and Yang, \{Xiao Juan\} and Hu, \{Huai Ming\}",

year = "2007",

month = may,

doi = "10.1016/j.inoche.2007.01.026",

language = "English",

volume = "10",

pages = "563--566",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "5",

}

TY - JOUR

T1 - Assembly of two supramolecular structures by metal complexes with a urea-based pyridyl ligand

AU - Wu, Biao

AU - Huang, Xiaojuan

AU - Liang, Jianjun

AU - Liu, Yanyan

AU - Yang, Xiao Juan

AU - Hu, Huai Ming

PY - 2007/5

Y1 - 2007/5

N2 - The supramolecular structures of two metal complexes, [CuL4Cl2] (1) and [ZnL2Cl2] (2), where L = N-(2,6-dimethylphenyl)-N′-(3-pyridy1)urea, are reported. Complex 1 features infinite tapes formed by intermolecular N-H⋯Cl hydrogen bonds with an R21(6) motif, as well as a π-π stacking interaction. The solid-state structure of 2 shows a 2D network held together by two types of N-H⋯O R21(6) motifs, and there is no significant interaction between the NH groups and the metal-bound Cl- ions.

AB - The supramolecular structures of two metal complexes, [CuL4Cl2] (1) and [ZnL2Cl2] (2), where L = N-(2,6-dimethylphenyl)-N′-(3-pyridy1)urea, are reported. Complex 1 features infinite tapes formed by intermolecular N-H⋯Cl hydrogen bonds with an R21(6) motif, as well as a π-π stacking interaction. The solid-state structure of 2 shows a 2D network held together by two types of N-H⋯O R21(6) motifs, and there is no significant interaction between the NH groups and the metal-bound Cl- ions.

KW - Copper(II)

KW - Hydrogen bonding

KW - Pyridyl urea

KW - Zinc(II)

KW - π-π Stacking

UR - https://www.scopus.com/pages/publications/34047269426

U2 - 10.1016/j.inoche.2007.01.026

DO - 10.1016/j.inoche.2007.01.026

M3 - Article

AN - SCOPUS:34047269426

SN - 1387-7003

VL - 10

SP - 563

EP - 566

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 5

ER -

Assembly of two supramolecular structures by metal complexes with a urea-based pyridyl ligand

Abstract

Keywords

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