Applying the B/N Lewis Pair Approach to Access Fusion-Expanded Binaphthyl-Based Chiral Analogues

Guoqing Tian; Jin Fa Chen; Kai Zhang; Yafei Shi; Chenglong Li; Xiaodong Yin; Kanglei Liu; Pangkuan Chen

doi:10.1021/acs.inorgchem.2c02875

Applying the B/N Lewis Pair Approach to Access Fusion-Expanded Binaphthyl-Based Chiral Analogues

Guoqing Tian
, Jin Fa Chen
, Kai Zhang
, Yafei Shi
, Chenglong Li
, Xiaodong Yin
, Kanglei Liu^*
, Pangkuan Chen^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

We herein describe the synthesis of two axially chiral systems (HBN and BBN) by the incorporation of B centers into binaphthyl derivatives (HPy and BPy). Heteroatom-doped chiral polycyclic aromatic hydrocarbons were thus formed by fusion of the azaboroles to binaphthyls with the formation of B-N dative bonds. The resulting B-N Lewis pairs that serve as attractive fluorophores enabled modulation of the chiroptical properties both in solution and in the solid state.

Original language	English
Pages (from-to)	15315-15319
Number of pages	5
Journal	Inorganic Chemistry
Volume	61
Issue number	39
DOIs	https://doi.org/10.1021/acs.inorgchem.2c02875
Publication status	Published - 3 Oct 2022

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10.1021/acs.inorgchem.2c02875

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title = "Applying the B/N Lewis Pair Approach to Access Fusion-Expanded Binaphthyl-Based Chiral Analogues",

abstract = "We herein describe the synthesis of two axially chiral systems (HBN and BBN) by the incorporation of B centers into binaphthyl derivatives (HPy and BPy). Heteroatom-doped chiral polycyclic aromatic hydrocarbons were thus formed by fusion of the azaboroles to binaphthyls with the formation of B-N dative bonds. The resulting B-N Lewis pairs that serve as attractive fluorophores enabled modulation of the chiroptical properties both in solution and in the solid state.",

author = "Guoqing Tian and Chen, \{Jin Fa\} and Kai Zhang and Yafei Shi and Chenglong Li and Xiaodong Yin and Kanglei Liu and Pangkuan Chen",

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year = "2022",

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doi = "10.1021/acs.inorgchem.2c02875",

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T1 - Applying the B/N Lewis Pair Approach to Access Fusion-Expanded Binaphthyl-Based Chiral Analogues

AU - Tian, Guoqing

AU - Chen, Jin Fa

AU - Zhang, Kai

AU - Shi, Yafei

AU - Li, Chenglong

AU - Yin, Xiaodong

AU - Liu, Kanglei

AU - Chen, Pangkuan

PY - 2022/10/3

Y1 - 2022/10/3

N2 - We herein describe the synthesis of two axially chiral systems (HBN and BBN) by the incorporation of B centers into binaphthyl derivatives (HPy and BPy). Heteroatom-doped chiral polycyclic aromatic hydrocarbons were thus formed by fusion of the azaboroles to binaphthyls with the formation of B-N dative bonds. The resulting B-N Lewis pairs that serve as attractive fluorophores enabled modulation of the chiroptical properties both in solution and in the solid state.

AB - We herein describe the synthesis of two axially chiral systems (HBN and BBN) by the incorporation of B centers into binaphthyl derivatives (HPy and BPy). Heteroatom-doped chiral polycyclic aromatic hydrocarbons were thus formed by fusion of the azaboroles to binaphthyls with the formation of B-N dative bonds. The resulting B-N Lewis pairs that serve as attractive fluorophores enabled modulation of the chiroptical properties both in solution and in the solid state.

UR - https://www.scopus.com/pages/publications/85138955138

U2 - 10.1021/acs.inorgchem.2c02875

DO - 10.1021/acs.inorgchem.2c02875

M3 - Article

C2 - 36135458

AN - SCOPUS:85138955138

SN - 0020-1669

VL - 61

SP - 15315

EP - 15319

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 39

ER -

Applying the B/N Lewis Pair Approach to Access Fusion-Expanded Binaphthyl-Based Chiral Analogues

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