An inclined interpenetrating heteropolynuclear polymer with unusual propagation of metal carboxylate secondary building units by both carboxylate and pyridyl bridging ligands

Pang Kuan Chen; Yun Xia Che; Stuart R. Batten; Ji Min Zheng

doi:10.1016/j.inoche.2006.11.018

An inclined interpenetrating heteropolynuclear polymer with unusual propagation of metal carboxylate secondary building units by both carboxylate and pyridyl bridging ligands

Pang Kuan Chen, Yun Xia Che, Stuart R. Batten, Ji Min Zheng^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The objective of this paper is to describe an unusual coordination polymer, M₄(μ₄-O)(bipy)(m-BDC)₃ (sM₄ = Zn_2.36 Co_1.64, bipy = 4,4′-bipyridine, m-H₂BDC = 1,3-benzenedicarboxylic acid) (1), which has been hydrothermally synthesised and characterized by single-crystal X-ray diffraction, XRPD, IR, TGA, ICP, atomic absorption, and element analysis. 1 crystallizes in the P4₂/mnm space group and contains a M₄O(O₂C)₆ secondary building unit (SBU) with an inclined interpenetrated (4, 4) topology, and is a rare combination of the two most successful approaches to coordination polymer design: generation of metal carboxylate SBUs and the use of pyridyl donor bridges. Moreover, complex 1 exhibits intense fluorescence at about 424 nm (λ_ex = 312 nm) in the solid state.

Original language	English
Pages (from-to)	415-418
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	10
Issue number	4
DOIs	https://doi.org/10.1016/j.inoche.2006.11.018
Publication status	Published - Apr 2007
Externally published	Yes

Keywords

Fluorescent property
Heteropolynuclear
Hydrothermal synthesis
Inclined interpenetration
MO(OC) SBUs

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10.1016/j.inoche.2006.11.018

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title = "An inclined interpenetrating heteropolynuclear polymer with unusual propagation of metal carboxylate secondary building units by both carboxylate and pyridyl bridging ligands",

abstract = "The objective of this paper is to describe an unusual coordination polymer, M4(μ4-O)(bipy)(m-BDC)3 (sM4 = Zn2.36 Co1.64, bipy = 4,4′-bipyridine, m-H2BDC = 1,3-benzenedicarboxylic acid) (1), which has been hydrothermally synthesised and characterized by single-crystal X-ray diffraction, XRPD, IR, TGA, ICP, atomic absorption, and element analysis. 1 crystallizes in the P42/mnm space group and contains a M4O(O2C)6 secondary building unit (SBU) with an inclined interpenetrated (4, 4) topology, and is a rare combination of the two most successful approaches to coordination polymer design: generation of metal carboxylate SBUs and the use of pyridyl donor bridges. Moreover, complex 1 exhibits intense fluorescence at about 424 nm (λex = 312 nm) in the solid state.",

keywords = "Fluorescent property, Heteropolynuclear, Hydrothermal synthesis, Inclined interpenetration, MO(OC) SBUs",

author = "Chen, {Pang Kuan} and Che, {Yun Xia} and Batten, {Stuart R.} and Zheng, {Ji Min}",

year = "2007",

month = apr,

doi = "10.1016/j.inoche.2006.11.018",

language = "English",

volume = "10",

pages = "415--418",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "4",

}

An inclined interpenetrating heteropolynuclear polymer with unusual propagation of metal carboxylate secondary building units by both carboxylate and pyridyl bridging ligands. / Chen, Pang Kuan; Che, Yun Xia; Batten, Stuart R. et al.
In: Inorganic Chemistry Communications, Vol. 10, No. 4, 04.2007, p. 415-418.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - An inclined interpenetrating heteropolynuclear polymer with unusual propagation of metal carboxylate secondary building units by both carboxylate and pyridyl bridging ligands

AU - Chen, Pang Kuan

AU - Che, Yun Xia

AU - Batten, Stuart R.

AU - Zheng, Ji Min

PY - 2007/4

Y1 - 2007/4

N2 - The objective of this paper is to describe an unusual coordination polymer, M4(μ4-O)(bipy)(m-BDC)3 (sM4 = Zn2.36 Co1.64, bipy = 4,4′-bipyridine, m-H2BDC = 1,3-benzenedicarboxylic acid) (1), which has been hydrothermally synthesised and characterized by single-crystal X-ray diffraction, XRPD, IR, TGA, ICP, atomic absorption, and element analysis. 1 crystallizes in the P42/mnm space group and contains a M4O(O2C)6 secondary building unit (SBU) with an inclined interpenetrated (4, 4) topology, and is a rare combination of the two most successful approaches to coordination polymer design: generation of metal carboxylate SBUs and the use of pyridyl donor bridges. Moreover, complex 1 exhibits intense fluorescence at about 424 nm (λex = 312 nm) in the solid state.

AB - The objective of this paper is to describe an unusual coordination polymer, M4(μ4-O)(bipy)(m-BDC)3 (sM4 = Zn2.36 Co1.64, bipy = 4,4′-bipyridine, m-H2BDC = 1,3-benzenedicarboxylic acid) (1), which has been hydrothermally synthesised and characterized by single-crystal X-ray diffraction, XRPD, IR, TGA, ICP, atomic absorption, and element analysis. 1 crystallizes in the P42/mnm space group and contains a M4O(O2C)6 secondary building unit (SBU) with an inclined interpenetrated (4, 4) topology, and is a rare combination of the two most successful approaches to coordination polymer design: generation of metal carboxylate SBUs and the use of pyridyl donor bridges. Moreover, complex 1 exhibits intense fluorescence at about 424 nm (λex = 312 nm) in the solid state.

KW - Fluorescent property

KW - Heteropolynuclear

KW - Hydrothermal synthesis

KW - Inclined interpenetration

KW - MO(OC) SBUs

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U2 - 10.1016/j.inoche.2006.11.018

DO - 10.1016/j.inoche.2006.11.018

M3 - Article

AN - SCOPUS:33847251936

SN - 1387-7003

VL - 10

SP - 415

EP - 418

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 4

ER -

An inclined interpenetrating heteropolynuclear polymer with unusual propagation of metal carboxylate secondary building units by both carboxylate and pyridyl bridging ligands

Abstract

Keywords

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