An Azide-Bridged Homospin Single-Chain Magnet: [Co(2,2′ -bithiazoline)(N3)2]n

Tian Fu Liu; Dan Fu; Song Gao; Yuan Zhu Zhang; Hao Ling Sun; Gang Su; Yong Jiang Liu

doi:10.1021/ja0380751

An Azide-Bridged Homospin Single-Chain Magnet: [Co(2,2′ -bithiazoline)(N₃)₂]_n

Tian Fu Liu
, Dan Fu
, Song Gao^*
, Yuan Zhu Zhang
, Hao Ling Sun
, Gang Su
, Yong Jiang Liu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

511 Citations (Scopus)

Abstract

A novel end-on azide-bridged homospin 1D chain, Co(bt)(N₃)₂ (1) (bt = 2,2′-bithiazoline), is constructed by sharing edges of Co(II) distorted octahedrons to form a helix, which shows magnetic hysteresis with steps and slow relaxation below 5?6 K, typical of single-chain magnet behavior.

Original language	English
Pages (from-to)	13976-13977
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	125
Issue number	46
DOIs	https://doi.org/10.1021/ja0380751
Publication status	Published - 19 Nov 2003
Externally published	Yes

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title = "An Azide-Bridged Homospin Single-Chain Magnet: [Co(2,2′ -bithiazoline)(N3)2]n",

abstract = "A novel end-on azide-bridged homospin 1D chain, Co(bt)(N3)2 (1) (bt = 2,2′-bithiazoline), is constructed by sharing edges of Co(II) distorted octahedrons to form a helix, which shows magnetic hysteresis with steps and slow relaxation below 5?6 K, typical of single-chain magnet behavior.",

author = "Liu, \{Tian Fu\} and Dan Fu and Song Gao and Zhang, \{Yuan Zhu\} and Sun, \{Hao Ling\} and Gang Su and Liu, \{Yong Jiang\}",

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language = "English",

volume = "125",

pages = "13976--13977",

journal = "Journal of the American Chemical Society",

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T1 - An Azide-Bridged Homospin Single-Chain Magnet

T2 - [Co(2,2′ -bithiazoline)(N3)2]n

AU - Liu, Tian Fu

AU - Fu, Dan

AU - Gao, Song

AU - Zhang, Yuan Zhu

AU - Sun, Hao Ling

AU - Su, Gang

AU - Liu, Yong Jiang

PY - 2003/11/19

Y1 - 2003/11/19

N2 - A novel end-on azide-bridged homospin 1D chain, Co(bt)(N3)2 (1) (bt = 2,2′-bithiazoline), is constructed by sharing edges of Co(II) distorted octahedrons to form a helix, which shows magnetic hysteresis with steps and slow relaxation below 5?6 K, typical of single-chain magnet behavior.

AB - A novel end-on azide-bridged homospin 1D chain, Co(bt)(N3)2 (1) (bt = 2,2′-bithiazoline), is constructed by sharing edges of Co(II) distorted octahedrons to form a helix, which shows magnetic hysteresis with steps and slow relaxation below 5?6 K, typical of single-chain magnet behavior.

UR - https://www.scopus.com/pages/publications/0242498370

U2 - 10.1021/ja0380751

DO - 10.1021/ja0380751

M3 - Article

AN - SCOPUS:0242498370

SN - 0002-7863

VL - 125

SP - 13976

EP - 13977

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 46

ER -

An Azide-Bridged Homospin Single-Chain Magnet: [Co(2,2′ -bithiazoline)(N₃)₂]_n

Abstract

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