An aluminoborate directed by [Zn(H2O)4]2 + complex: Synthesis, structure and properties

Rui Pan; Bai Bai Yang; Guo Ming Wang; Guo Yu Yang

doi:10.1016/j.inoche.2016.12.009

An aluminoborate directed by [Zn(H₂O)₄]^2 + complex: Synthesis, structure and properties

Rui Pan
, Bai Bai Yang
, Guo Ming Wang^*
, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology
Qingdao University

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A novel 3D aluminoborate with [Zn(H₂O)₄]²⁺ cationic complexes as structure-directing agents (SDAs), namely, [Zn(H₂O)₄][Al(B₅O₁₀)]·0.5(H₂O) (1), has been solvothermally prepared and characterized by IR spectroscopy, UV–vis reflection spectroscopy, thermogravimetric (TG) analyses, powder and single crystal X-ray diffraction, respectively. The alternative linkage of AlO₄ tetrahedra and B₅O₁₀ units produces an open-framework aluminoborate with helical 6- and 8-membered ring (MR) channels, as well as large odd 11-MR channels. The [Zn(H₂O)₄]²⁺ templates, generated in situ from solvothermal conditions, are orderly located in the center of the 11-MR channels. The second-harmonic generation (SHG) measurement indicates that 1 exhibits about 0.5 times that of KDP standard (K₂HPO₄).

Original language	English
Pages (from-to)	26-29
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	76
DOIs	https://doi.org/10.1016/j.inoche.2016.12.009
Publication status	Published - 1 Feb 2017

Keywords

Aluminoborate
Crystal structure
Nonlinear optical
Solvothermal synthesis

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10.1016/j.inoche.2016.12.009

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@article{6e25fe04b6b641cfb17589c517dffffe,

title = "An aluminoborate directed by [Zn(H2O)4]2 + complex: Synthesis, structure and properties",

abstract = "A novel 3D aluminoborate with [Zn(H2O)4]2+ cationic complexes as structure-directing agents (SDAs), namely, [Zn(H2O)4][Al(B5O10)]·0.5(H2O) (1), has been solvothermally prepared and characterized by IR spectroscopy, UV–vis reflection spectroscopy, thermogravimetric (TG) analyses, powder and single crystal X-ray diffraction, respectively. The alternative linkage of AlO4 tetrahedra and B5O10 units produces an open-framework aluminoborate with helical 6- and 8-membered ring (MR) channels, as well as large odd 11-MR channels. The [Zn(H2O)4]2+ templates, generated in situ from solvothermal conditions, are orderly located in the center of the 11-MR channels. The second-harmonic generation (SHG) measurement indicates that 1 exhibits about 0.5 times that of KDP standard (K2HPO4).",

keywords = "Aluminoborate, Crystal structure, Nonlinear optical, Solvothermal synthesis",

author = "Rui Pan and Yang, \{Bai Bai\} and Wang, \{Guo Ming\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2017",

month = feb,

day = "1",

doi = "10.1016/j.inoche.2016.12.009",

language = "English",

volume = "76",

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journal = "Inorganic Chemistry Communications",

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T1 - An aluminoborate directed by [Zn(H2O)4]2 + complex

T2 - Synthesis, structure and properties

AU - Pan, Rui

AU - Yang, Bai Bai

AU - Wang, Guo Ming

AU - Yang, Guo Yu

PY - 2017/2/1

Y1 - 2017/2/1

N2 - A novel 3D aluminoborate with [Zn(H2O)4]2+ cationic complexes as structure-directing agents (SDAs), namely, [Zn(H2O)4][Al(B5O10)]·0.5(H2O) (1), has been solvothermally prepared and characterized by IR spectroscopy, UV–vis reflection spectroscopy, thermogravimetric (TG) analyses, powder and single crystal X-ray diffraction, respectively. The alternative linkage of AlO4 tetrahedra and B5O10 units produces an open-framework aluminoborate with helical 6- and 8-membered ring (MR) channels, as well as large odd 11-MR channels. The [Zn(H2O)4]2+ templates, generated in situ from solvothermal conditions, are orderly located in the center of the 11-MR channels. The second-harmonic generation (SHG) measurement indicates that 1 exhibits about 0.5 times that of KDP standard (K2HPO4).

AB - A novel 3D aluminoborate with [Zn(H2O)4]2+ cationic complexes as structure-directing agents (SDAs), namely, [Zn(H2O)4][Al(B5O10)]·0.5(H2O) (1), has been solvothermally prepared and characterized by IR spectroscopy, UV–vis reflection spectroscopy, thermogravimetric (TG) analyses, powder and single crystal X-ray diffraction, respectively. The alternative linkage of AlO4 tetrahedra and B5O10 units produces an open-framework aluminoborate with helical 6- and 8-membered ring (MR) channels, as well as large odd 11-MR channels. The [Zn(H2O)4]2+ templates, generated in situ from solvothermal conditions, are orderly located in the center of the 11-MR channels. The second-harmonic generation (SHG) measurement indicates that 1 exhibits about 0.5 times that of KDP standard (K2HPO4).

KW - Aluminoborate

KW - Crystal structure

KW - Nonlinear optical

KW - Solvothermal synthesis

UR - https://www.scopus.com/pages/publications/85008413056

U2 - 10.1016/j.inoche.2016.12.009

DO - 10.1016/j.inoche.2016.12.009

M3 - Article

AN - SCOPUS:85008413056

SN - 1387-7003

VL - 76

SP - 26

EP - 29

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

An aluminoborate directed by [Zn(H₂O)₄]^2 + complex: Synthesis, structure and properties

Abstract

Keywords

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