An advanced low-cost cathode composed of graphene-coated Na2.4Fe1.8(SO4)3 nanograins in a 3D graphene network for ultra-stable sodium storage

Yongjin Fang; Qi Liu; Xiangming Feng; Weihua Chen; Xinping Ai; Liguang Wang; Liang Wang; Zhiyuan Ma; Yang Ren; Hanxi Yang; Yuliang Cao

doi:10.1016/j.jechem.2020.06.020

An advanced low-cost cathode composed of graphene-coated Na_2.4Fe_1.8(SO₄)₃ nanograins in a 3D graphene network for ultra-stable sodium storage

Yongjin Fang
, Qi Liu
, Xiangming Feng
, Weihua Chen
, Xinping Ai
, Liguang Wang
, Liang Wang
, Zhiyuan Ma
, Yang Ren
, Hanxi Yang
, Yuliang Cao^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

Iron-based electrodes have attracted great attention for sodium storage because of the distinct cost effectiveness. However, exploring suitable iron-based electrodes with high power density and long duration remains a big challenge. Herein, a spray-drying strategy is adopted to construct graphene-coated Na_2.4Fe_1.8(SO₄)₃ nanograins in a 3D graphene microsphere network. The unique structural and compositional advantages endow these electrodes to exhibit outstanding electrochemical properties with remarkable rate performance and long cycle life. Mechanism analyses further explain the outstanding electrochemical properties from the structural aspect.

Original language	English
Pages (from-to)	564-570
Number of pages	7
Journal	Journal of Energy Chemistry
Volume	54
DOIs	https://doi.org/10.1016/j.jechem.2020.06.020
Publication status	Published - Mar 2021
Externally published	Yes

Keywords

Cathode
NaFe(SO)
Polyanions
Sodium-ion batteries
Spray-drying

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10.1016/j.jechem.2020.06.020

Cite this

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title = "An advanced low-cost cathode composed of graphene-coated Na2.4Fe1.8(SO4)3 nanograins in a 3D graphene network for ultra-stable sodium storage",

abstract = "Iron-based electrodes have attracted great attention for sodium storage because of the distinct cost effectiveness. However, exploring suitable iron-based electrodes with high power density and long duration remains a big challenge. Herein, a spray-drying strategy is adopted to construct graphene-coated Na2.4Fe1.8(SO4)3 nanograins in a 3D graphene microsphere network. The unique structural and compositional advantages endow these electrodes to exhibit outstanding electrochemical properties with remarkable rate performance and long cycle life. Mechanism analyses further explain the outstanding electrochemical properties from the structural aspect.",

keywords = "Cathode, NaFe(SO), Polyanions, Sodium-ion batteries, Spray-drying",

author = "Yongjin Fang and Qi Liu and Xiangming Feng and Weihua Chen and Xinping Ai and Liguang Wang and Liang Wang and Zhiyuan Ma and Yang Ren and Hanxi Yang and Yuliang Cao",

note = "Publisher Copyright: {\textcopyright} 2020 Science Press",

year = "2021",

month = mar,

doi = "10.1016/j.jechem.2020.06.020",

language = "English",

volume = "54",

pages = "564--570",

journal = "Journal of Energy Chemistry",

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publisher = "Elsevier B.V.",

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TY - JOUR

T1 - An advanced low-cost cathode composed of graphene-coated Na2.4Fe1.8(SO4)3 nanograins in a 3D graphene network for ultra-stable sodium storage

AU - Fang, Yongjin

AU - Liu, Qi

AU - Feng, Xiangming

AU - Chen, Weihua

AU - Ai, Xinping

AU - Wang, Liguang

AU - Wang, Liang

AU - Ma, Zhiyuan

AU - Ren, Yang

AU - Yang, Hanxi

AU - Cao, Yuliang

PY - 2021/3

Y1 - 2021/3

N2 - Iron-based electrodes have attracted great attention for sodium storage because of the distinct cost effectiveness. However, exploring suitable iron-based electrodes with high power density and long duration remains a big challenge. Herein, a spray-drying strategy is adopted to construct graphene-coated Na2.4Fe1.8(SO4)3 nanograins in a 3D graphene microsphere network. The unique structural and compositional advantages endow these electrodes to exhibit outstanding electrochemical properties with remarkable rate performance and long cycle life. Mechanism analyses further explain the outstanding electrochemical properties from the structural aspect.

AB - Iron-based electrodes have attracted great attention for sodium storage because of the distinct cost effectiveness. However, exploring suitable iron-based electrodes with high power density and long duration remains a big challenge. Herein, a spray-drying strategy is adopted to construct graphene-coated Na2.4Fe1.8(SO4)3 nanograins in a 3D graphene microsphere network. The unique structural and compositional advantages endow these electrodes to exhibit outstanding electrochemical properties with remarkable rate performance and long cycle life. Mechanism analyses further explain the outstanding electrochemical properties from the structural aspect.

KW - Cathode

KW - NaFe(SO)

KW - Polyanions

KW - Sodium-ion batteries

KW - Spray-drying

UR - https://www.scopus.com/pages/publications/85087706028

U2 - 10.1016/j.jechem.2020.06.020

DO - 10.1016/j.jechem.2020.06.020

M3 - Article

AN - SCOPUS:85087706028

SN - 2095-4956

VL - 54

SP - 564

EP - 570

JO - Journal of Energy Chemistry

JF - Journal of Energy Chemistry

ER -

An advanced low-cost cathode composed of graphene-coated Na_2.4Fe_1.8(SO₄)₃ nanograins in a 3D graphene network for ultra-stable sodium storage

Abstract

Keywords

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