Alkaline earth guests in polyoxopalladate Chemistry: From nanocube to nanostar via an open-shell structure

Peng Yang; Yixian Xiang; Zhengguo Lin; Bassem S. Bassil; Jie Cao; Linyuan Fan; Yanxuan Fan; Ming Xing Li; Pablo Jiménez-Lozano; Jorge J. Carbó; Josep M. Poblet; Ulrich Kortz

doi:10.1002/anie.201407090

Alkaline earth guests in polyoxopalladate Chemistry: From nanocube to nanostar via an open-shell structure

Peng Yang
, Yixian Xiang
, Zhengguo Lin
, Bassem S. Bassil
, Jie Cao
, Linyuan Fan
, Yanxuan Fan
, Ming Xing Li
, Pablo Jiménez-Lozano
, Jorge J. Carbó
, Josep M. Poblet
, Ulrich Kortz^*

^*Corresponding author for this work

Constructor University
Ministry of Education in China
Shanghai University
Universidad Rovira i Virgili

Research output: Contribution to journal › Article › peer-review

63 Citations (Scopus)

Abstract

The three novel, discrete palladium(II)-oxo clusters [CaPd12O8(PhAsO₃)₈]6^- (CaPd₁₂), [SrPd₁₂O₆(OH)₃-(PhAsO₃)₆(OAc)₃]4^- (SrPd¹²), and [BaPd₁₅O₁₀(PhAsO₃)₁₀]8^- (BaPd₁₅) encapsulating alkaline earth metal ions were prepared and fully characterized by a multitude of solution and solid-state physicochemical techniques. We have discovered a structure-directing template effect induced by the respective size of the alkaline earth guest ion, which determines the detailed condensation arrangement of the peripheral PdII-oxo shell. The unprecedented SrPd₁₂ with an open-shell type structure is of particular importance and reflects a successful strategy for deliberate design of new structural classes of polyoxo-noble-metalates. Furthermore, the unusual acetate-water ligand exchange phenomenon renders SrPd₁₂ as a promising candidate for noble-metal-based catalysis.

Original language	English
Pages (from-to)	11974-11978
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	53
Issue number	44
DOIs	https://doi.org/10.1002/anie.201407090
Publication status	Published - 12 Sept 2014
Externally published	Yes

Keywords

Cluster compounds
Palladium
Polyoxometalates
Template effect
X-ray diffraction

Access to Document

10.1002/anie.201407090

Cite this

@article{5727bac9d98f49b0b61e4602fb5b95fb,

title = "Alkaline earth guests in polyoxopalladate Chemistry: From nanocube to nanostar via an open-shell structure",

abstract = "The three novel, discrete palladium(II)-oxo clusters [CaPd12O8(PhAsO3)8]6- (CaPd12), [SrPd12O6(OH)3-(PhAsO3)6(OAc)3]4- (SrPd12), and [BaPd15O10(PhAsO3)10]8- (BaPd15) encapsulating alkaline earth metal ions were prepared and fully characterized by a multitude of solution and solid-state physicochemical techniques. We have discovered a structure-directing template effect induced by the respective size of the alkaline earth guest ion, which determines the detailed condensation arrangement of the peripheral PdII-oxo shell. The unprecedented SrPd12 with an open-shell type structure is of particular importance and reflects a successful strategy for deliberate design of new structural classes of polyoxo-noble-metalates. Furthermore, the unusual acetate-water ligand exchange phenomenon renders SrPd12 as a promising candidate for noble-metal-based catalysis.",

keywords = "Cluster compounds, Palladium, Polyoxometalates, Template effect, X-ray diffraction",

author = "Peng Yang and Yixian Xiang and Zhengguo Lin and Bassil, \{Bassem S.\} and Jie Cao and Linyuan Fan and Yanxuan Fan and Li, \{Ming Xing\} and Pablo Jim{\'e}nez-Lozano and Carb{\'o}, \{Jorge J.\} and Poblet, \{Josep M.\} and Ulrich Kortz",

note = "Publisher Copyright: {\textcopyright} 2014 Wiley-VCH Verlag GmbH \&Co. KGaA,Weinheim.",

year = "2014",

month = sep,

day = "12",

doi = "10.1002/anie.201407090",

language = "English",

volume = "53",

pages = "11974--11978",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "44",

}

TY - JOUR

T1 - Alkaline earth guests in polyoxopalladate Chemistry

T2 - From nanocube to nanostar via an open-shell structure

AU - Yang, Peng

AU - Xiang, Yixian

AU - Lin, Zhengguo

AU - Bassil, Bassem S.

AU - Cao, Jie

AU - Fan, Linyuan

AU - Fan, Yanxuan

AU - Li, Ming Xing

AU - Jiménez-Lozano, Pablo

AU - Carbó, Jorge J.

AU - Poblet, Josep M.

AU - Kortz, Ulrich

PY - 2014/9/12

Y1 - 2014/9/12

N2 - The three novel, discrete palladium(II)-oxo clusters [CaPd12O8(PhAsO3)8]6- (CaPd12), [SrPd12O6(OH)3-(PhAsO3)6(OAc)3]4- (SrPd12), and [BaPd15O10(PhAsO3)10]8- (BaPd15) encapsulating alkaline earth metal ions were prepared and fully characterized by a multitude of solution and solid-state physicochemical techniques. We have discovered a structure-directing template effect induced by the respective size of the alkaline earth guest ion, which determines the detailed condensation arrangement of the peripheral PdII-oxo shell. The unprecedented SrPd12 with an open-shell type structure is of particular importance and reflects a successful strategy for deliberate design of new structural classes of polyoxo-noble-metalates. Furthermore, the unusual acetate-water ligand exchange phenomenon renders SrPd12 as a promising candidate for noble-metal-based catalysis.

AB - The three novel, discrete palladium(II)-oxo clusters [CaPd12O8(PhAsO3)8]6- (CaPd12), [SrPd12O6(OH)3-(PhAsO3)6(OAc)3]4- (SrPd12), and [BaPd15O10(PhAsO3)10]8- (BaPd15) encapsulating alkaline earth metal ions were prepared and fully characterized by a multitude of solution and solid-state physicochemical techniques. We have discovered a structure-directing template effect induced by the respective size of the alkaline earth guest ion, which determines the detailed condensation arrangement of the peripheral PdII-oxo shell. The unprecedented SrPd12 with an open-shell type structure is of particular importance and reflects a successful strategy for deliberate design of new structural classes of polyoxo-noble-metalates. Furthermore, the unusual acetate-water ligand exchange phenomenon renders SrPd12 as a promising candidate for noble-metal-based catalysis.

KW - Cluster compounds

KW - Palladium

KW - Polyoxometalates

KW - Template effect

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/84918771893

U2 - 10.1002/anie.201407090

DO - 10.1002/anie.201407090

M3 - Article

AN - SCOPUS:84918771893

SN - 1433-7851

VL - 53

SP - 11974

EP - 11978

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 44

ER -

Alkaline earth guests in polyoxopalladate Chemistry: From nanocube to nanostar via an open-shell structure

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this