Alkaline earth guests in polyoxopalladate Chemistry: From nanocube to nanostar via an open-shell structure

Peng Yang; Yixian Xiang; Zhengguo Lin; Bassem S. Bassil; Jie Cao; Linyuan Fan; Yanxuan Fan; Ming Xing Li; Pablo Jiménez-Lozano; Jorge J. Carbó; Josep M. Poblet; Ulrich Kortz

doi:10.1002/anie.201407090

Alkaline earth guests in polyoxopalladate Chemistry: From nanocube to nanostar via an open-shell structure

Peng Yang, Yixian Xiang, Zhengguo Lin, Bassem S. Bassil, Jie Cao, Linyuan Fan, Yanxuan Fan, Ming Xing Li, Pablo Jiménez-Lozano, Jorge J. Carbó, Josep M. Poblet, Ulrich Kortz^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

60 Citations (Scopus)

Abstract

The three novel, discrete palladium(II)-oxo clusters [CaPd12O8(PhAsO₃)₈]6^- (CaPd₁₂), [SrPd₁₂O₆(OH)₃-(PhAsO₃)₆(OAc)₃]4^- (SrPd¹²), and [BaPd₁₅O₁₀(PhAsO₃)₁₀]8^- (BaPd₁₅) encapsulating alkaline earth metal ions were prepared and fully characterized by a multitude of solution and solid-state physicochemical techniques. We have discovered a structure-directing template effect induced by the respective size of the alkaline earth guest ion, which determines the detailed condensation arrangement of the peripheral PdII-oxo shell. The unprecedented SrPd₁₂ with an open-shell type structure is of particular importance and reflects a successful strategy for deliberate design of new structural classes of polyoxo-noble-metalates. Furthermore, the unusual acetate-water ligand exchange phenomenon renders SrPd₁₂ as a promising candidate for noble-metal-based catalysis.

Original language	English
Pages (from-to)	11974-11978
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	53
Issue number	44
DOIs	https://doi.org/10.1002/anie.201407090
Publication status	Published - 12 Sept 2014
Externally published	Yes

Keywords

Cluster compounds
Palladium
Polyoxometalates
Template effect
X-ray diffraction

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10.1002/anie.201407090

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title = "Alkaline earth guests in polyoxopalladate Chemistry: From nanocube to nanostar via an open-shell structure",

abstract = "The three novel, discrete palladium(II)-oxo clusters [CaPd12O8(PhAsO3)8]6- (CaPd12), [SrPd12O6(OH)3-(PhAsO3)6(OAc)3]4- (SrPd12), and [BaPd15O10(PhAsO3)10]8- (BaPd15) encapsulating alkaline earth metal ions were prepared and fully characterized by a multitude of solution and solid-state physicochemical techniques. We have discovered a structure-directing template effect induced by the respective size of the alkaline earth guest ion, which determines the detailed condensation arrangement of the peripheral PdII-oxo shell. The unprecedented SrPd12 with an open-shell type structure is of particular importance and reflects a successful strategy for deliberate design of new structural classes of polyoxo-noble-metalates. Furthermore, the unusual acetate-water ligand exchange phenomenon renders SrPd12 as a promising candidate for noble-metal-based catalysis.",

keywords = "Cluster compounds, Palladium, Polyoxometalates, Template effect, X-ray diffraction",

author = "Peng Yang and Yixian Xiang and Zhengguo Lin and Bassil, {Bassem S.} and Jie Cao and Linyuan Fan and Yanxuan Fan and Li, {Ming Xing} and Pablo Jim{\'e}nez-Lozano and Carb{\'o}, {Jorge J.} and Poblet, {Josep M.} and Ulrich Kortz",

note = "Publisher Copyright: {\textcopyright} 2014 Wiley-VCH Verlag GmbH &Co. KGaA,Weinheim.",

year = "2014",

month = sep,

day = "12",

doi = "10.1002/anie.201407090",

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AU - Yang, Peng

AU - Xiang, Yixian

AU - Lin, Zhengguo

AU - Bassil, Bassem S.

AU - Cao, Jie

AU - Fan, Linyuan

AU - Fan, Yanxuan

AU - Li, Ming Xing

AU - Jiménez-Lozano, Pablo

AU - Carbó, Jorge J.

AU - Poblet, Josep M.

AU - Kortz, Ulrich

PY - 2014/9/12

Y1 - 2014/9/12

N2 - The three novel, discrete palladium(II)-oxo clusters [CaPd12O8(PhAsO3)8]6- (CaPd12), [SrPd12O6(OH)3-(PhAsO3)6(OAc)3]4- (SrPd12), and [BaPd15O10(PhAsO3)10]8- (BaPd15) encapsulating alkaline earth metal ions were prepared and fully characterized by a multitude of solution and solid-state physicochemical techniques. We have discovered a structure-directing template effect induced by the respective size of the alkaline earth guest ion, which determines the detailed condensation arrangement of the peripheral PdII-oxo shell. The unprecedented SrPd12 with an open-shell type structure is of particular importance and reflects a successful strategy for deliberate design of new structural classes of polyoxo-noble-metalates. Furthermore, the unusual acetate-water ligand exchange phenomenon renders SrPd12 as a promising candidate for noble-metal-based catalysis.

AB - The three novel, discrete palladium(II)-oxo clusters [CaPd12O8(PhAsO3)8]6- (CaPd12), [SrPd12O6(OH)3-(PhAsO3)6(OAc)3]4- (SrPd12), and [BaPd15O10(PhAsO3)10]8- (BaPd15) encapsulating alkaline earth metal ions were prepared and fully characterized by a multitude of solution and solid-state physicochemical techniques. We have discovered a structure-directing template effect induced by the respective size of the alkaline earth guest ion, which determines the detailed condensation arrangement of the peripheral PdII-oxo shell. The unprecedented SrPd12 with an open-shell type structure is of particular importance and reflects a successful strategy for deliberate design of new structural classes of polyoxo-noble-metalates. Furthermore, the unusual acetate-water ligand exchange phenomenon renders SrPd12 as a promising candidate for noble-metal-based catalysis.

KW - Cluster compounds

KW - Palladium

KW - Polyoxometalates

KW - Template effect

KW - X-ray diffraction

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DO - 10.1002/anie.201407090

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ER -

Alkaline earth guests in polyoxopalladate Chemistry: From nanocube to nanostar via an open-shell structure

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Keywords

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