Adsorption of Cr(VI) in waste water by functional superparamagnetic PGMA polymer microspheres with amino groups

Peng Fei Li; Liang Rong Yang; Wen Song Li; Yin Bin Huang; Juan Wang; Peng Kong; Lin Xu; Hui Zhou Liu

Adsorption of Cr(VI) in waste water by functional superparamagnetic PGMA polymer microspheres with amino groups

Peng Fei Li
, Liang Rong Yang
, Wen Song Li
, Yin Bin Huang
, Juan Wang
, Peng Kong
, Lin Xu
, Hui Zhou Liu^*

^*Corresponding author for this work

CAS - Institute of Process Engineering
University of Chinese Academy of Sciences

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Micron-sized monodisperse superparamagnetic polyglycidyl methacrylate (PGMA) particles with functional amino groups were prepared and characterized by SEM, FT-IR and XRD, respectively. The effect of pH value on the adsorption was studied. Their adsorption properties and mechanism for Cr(VI) from wastewater were investigated. In a model system, the adsorption process followed the Langmuir adsorption isotherm, and the maximum sorption capacity of was calculated to be 263.16 mg/g at 308 K and pH 4.5. The adsorption of Cr(VI) capacity reached equilibrium within 15 min and followed pseudo second order kinetics. The adsorption was a spontaneous and endothermic process with ΔH⁰=9.63 kJ/mol.

Original language	English
Pages (from-to)	554-560
Number of pages	7
Journal	Guocheng Gongcheng Xuebao/The Chinese Journal of Process Engineering
Volume	11
Issue number	4
Publication status	Published - Aug 2011
Externally published	Yes

Keywords

Adsorption
Amino group
Cr(VI)
Monodispersion
PGMA
Superparamagnetism

Cite this

@article{2b6b560149cc40e89ef886e4fedd691d,

title = "Adsorption of Cr(VI) in waste water by functional superparamagnetic PGMA polymer microspheres with amino groups",

abstract = "Micron-sized monodisperse superparamagnetic polyglycidyl methacrylate (PGMA) particles with functional amino groups were prepared and characterized by SEM, FT-IR and XRD, respectively. The effect of pH value on the adsorption was studied. Their adsorption properties and mechanism for Cr(VI) from wastewater were investigated. In a model system, the adsorption process followed the Langmuir adsorption isotherm, and the maximum sorption capacity of was calculated to be 263.16 mg/g at 308 K and pH 4.5. The adsorption of Cr(VI) capacity reached equilibrium within 15 min and followed pseudo second order kinetics. The adsorption was a spontaneous and endothermic process with ΔH0=9.63 kJ/mol.",

keywords = "Adsorption, Amino group, Cr(VI), Monodispersion, PGMA, Superparamagnetism",

author = "Li, \{Peng Fei\} and Yang, \{Liang Rong\} and Li, \{Wen Song\} and Huang, \{Yin Bin\} and Juan Wang and Peng Kong and Lin Xu and Liu, \{Hui Zhou\}",

year = "2011",

month = aug,

language = "English",

volume = "11",

pages = "554--560",

journal = "Guocheng Gongcheng Xuebao/The Chinese Journal of Process Engineering",

issn = "1009-606X",

publisher = "Science Press",

number = "4",

}

TY - JOUR

T1 - Adsorption of Cr(VI) in waste water by functional superparamagnetic PGMA polymer microspheres with amino groups

AU - Li, Peng Fei

AU - Yang, Liang Rong

AU - Li, Wen Song

AU - Huang, Yin Bin

AU - Wang, Juan

AU - Kong, Peng

AU - Xu, Lin

AU - Liu, Hui Zhou

PY - 2011/8

Y1 - 2011/8

N2 - Micron-sized monodisperse superparamagnetic polyglycidyl methacrylate (PGMA) particles with functional amino groups were prepared and characterized by SEM, FT-IR and XRD, respectively. The effect of pH value on the adsorption was studied. Their adsorption properties and mechanism for Cr(VI) from wastewater were investigated. In a model system, the adsorption process followed the Langmuir adsorption isotherm, and the maximum sorption capacity of was calculated to be 263.16 mg/g at 308 K and pH 4.5. The adsorption of Cr(VI) capacity reached equilibrium within 15 min and followed pseudo second order kinetics. The adsorption was a spontaneous and endothermic process with ΔH0=9.63 kJ/mol.

AB - Micron-sized monodisperse superparamagnetic polyglycidyl methacrylate (PGMA) particles with functional amino groups were prepared and characterized by SEM, FT-IR and XRD, respectively. The effect of pH value on the adsorption was studied. Their adsorption properties and mechanism for Cr(VI) from wastewater were investigated. In a model system, the adsorption process followed the Langmuir adsorption isotherm, and the maximum sorption capacity of was calculated to be 263.16 mg/g at 308 K and pH 4.5. The adsorption of Cr(VI) capacity reached equilibrium within 15 min and followed pseudo second order kinetics. The adsorption was a spontaneous and endothermic process with ΔH0=9.63 kJ/mol.

KW - Adsorption

KW - Amino group

KW - Cr(VI)

KW - Monodispersion

KW - PGMA

KW - Superparamagnetism

UR - https://www.scopus.com/pages/publications/80052900606

M3 - Article

AN - SCOPUS:80052900606

SN - 1009-606X

VL - 11

SP - 554

EP - 560

JO - Guocheng Gongcheng Xuebao/The Chinese Journal of Process Engineering

JF - Guocheng Gongcheng Xuebao/The Chinese Journal of Process Engineering

IS - 4

ER -

Adsorption of Cr(VI) in waste water by functional superparamagnetic PGMA polymer microspheres with amino groups

Abstract

Keywords

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