Activity coefficients at infinite dilution of alkanes, alkenes, and alkyl benzenes in 1-hexyl-3-methylimidazolium trifluoromethanesulfonate using gas-liquid chromatography

Xiao Jun Yang; Jun Sheng Wu; Ming Lan Ge; Li Sheng Wang; Mi Yi Li

doi:10.1021/je800043a

Activity coefficients at infinite dilution of alkanes, alkenes, and alkyl benzenes in 1-hexyl-3-methylimidazolium trifluoromethanesulfonate using gas-liquid chromatography

Xiao Jun Yang
, Jun Sheng Wu^*
, Ming Lan Ge
, Li Sheng Wang
, Mi Yi Li

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Abstract

Activity coefficients at infinite dilution γ_i ^∞ have been determined for 17 organic solutes, alkanes, alkenes, and alkyl benzenes, in the ionic liquid l-hexyl-3-methylimidazolium trifluoromethanesulfonate ([HMIM][CF₃SO₃]) by the gas-liquid chromatographic (GLC) method with the ionic liquid as the stationary phase. The measurements were carried out in the temperature range of (303.15 to 363.15) K. The partial molar excess enthalpies at infinite dilution H _i^E,∞ were also determined for the solutes from the temperature dependence of the γ_i ^∞ values.

Original language	English
Pages (from-to)	1220-1222
Number of pages	3
Journal	Journal of Chemical and Engineering Data
Volume	53
Issue number	5
DOIs	https://doi.org/10.1021/je800043a
Publication status	Published - May 2008
Externally published	Yes

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10.1021/je800043a

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@article{4ee082b6caca44f981614d2ea0776f3a,

title = "Activity coefficients at infinite dilution of alkanes, alkenes, and alkyl benzenes in 1-hexyl-3-methylimidazolium trifluoromethanesulfonate using gas-liquid chromatography",

abstract = "Activity coefficients at infinite dilution γi ∞ have been determined for 17 organic solutes, alkanes, alkenes, and alkyl benzenes, in the ionic liquid l-hexyl-3-methylimidazolium trifluoromethanesulfonate ([HMIM][CF3SO3]) by the gas-liquid chromatographic (GLC) method with the ionic liquid as the stationary phase. The measurements were carried out in the temperature range of (303.15 to 363.15) K. The partial molar excess enthalpies at infinite dilution H iE,∞ were also determined for the solutes from the temperature dependence of the γi ∞ values.",

author = "Yang, \{Xiao Jun\} and Wu, \{Jun Sheng\} and Ge, \{Ming Lan\} and Wang, \{Li Sheng\} and Li, \{Mi Yi\}",

year = "2008",

month = may,

doi = "10.1021/je800043a",

language = "English",

volume = "53",

pages = "1220--1222",

journal = "Journal of Chemical and Engineering Data",

issn = "0021-9568",

publisher = "American Chemical Society",

number = "5",

}

Activity coefficients at infinite dilution of alkanes, alkenes, and alkyl benzenes in 1-hexyl-3-methylimidazolium trifluoromethanesulfonate using gas-liquid chromatography. / Yang, Xiao Jun; Wu, Jun Sheng; Ge, Ming Lan et al.
In: Journal of Chemical and Engineering Data, Vol. 53, No. 5, 05.2008, p. 1220-1222.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Activity coefficients at infinite dilution of alkanes, alkenes, and alkyl benzenes in 1-hexyl-3-methylimidazolium trifluoromethanesulfonate using gas-liquid chromatography

AU - Yang, Xiao Jun

AU - Wu, Jun Sheng

AU - Ge, Ming Lan

AU - Wang, Li Sheng

AU - Li, Mi Yi

PY - 2008/5

Y1 - 2008/5

N2 - Activity coefficients at infinite dilution γi ∞ have been determined for 17 organic solutes, alkanes, alkenes, and alkyl benzenes, in the ionic liquid l-hexyl-3-methylimidazolium trifluoromethanesulfonate ([HMIM][CF3SO3]) by the gas-liquid chromatographic (GLC) method with the ionic liquid as the stationary phase. The measurements were carried out in the temperature range of (303.15 to 363.15) K. The partial molar excess enthalpies at infinite dilution H iE,∞ were also determined for the solutes from the temperature dependence of the γi ∞ values.

AB - Activity coefficients at infinite dilution γi ∞ have been determined for 17 organic solutes, alkanes, alkenes, and alkyl benzenes, in the ionic liquid l-hexyl-3-methylimidazolium trifluoromethanesulfonate ([HMIM][CF3SO3]) by the gas-liquid chromatographic (GLC) method with the ionic liquid as the stationary phase. The measurements were carried out in the temperature range of (303.15 to 363.15) K. The partial molar excess enthalpies at infinite dilution H iE,∞ were also determined for the solutes from the temperature dependence of the γi ∞ values.

UR - https://www.scopus.com/pages/publications/44949264568

U2 - 10.1021/je800043a

DO - 10.1021/je800043a

M3 - Article

AN - SCOPUS:44949264568

SN - 0021-9568

VL - 53

SP - 1220

EP - 1222

JO - Journal of Chemical and Engineering Data

JF - Journal of Chemical and Engineering Data

IS - 5

ER -

Activity coefficients at infinite dilution of alkanes, alkenes, and alkyl benzenes in 1-hexyl-3-methylimidazolium trifluoromethanesulfonate using gas-liquid chromatography

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