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Activity coefficients at infinite dilution of alkanes, alkenes, and alkyl benzenes in 1-propyl-2,3-dimethylimidazolium tetrafluoroborate using gas-liquid chromatography

  • Ming Hui Wang
  • , Jun Sheng Wu*
  • , Li Sheng Wang
  • , Mi Yi Li
  • *Corresponding author for this work
  • Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

Activity coefficients at infinite dilution, γi ∞, have been determined for 17 organic solutes, alkanes, alkenes, and alkyl benzenes, in the ionic liquid 1-propyl-2,3- dimethylimidazolium tetrafluoroborate ([PDMIM][BF4]) by the gas-liquid chromatographic method with the ionic liquid as the stationary phase. The measurements were carried out in the temperature range of 303.15 K to 363.15 K. The partial molar excess enthalpies at infinite dilution, H iE,∞ were also determined for the solutes from the temperature dependence of the γi∞ values.

Original languageEnglish
Pages (from-to)1488-1491
Number of pages4
JournalJournal of Chemical and Engineering Data
Volume52
Issue number4
DOIs
Publication statusPublished - Jul 2007
Externally publishedYes

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