Acetylene Solubility in High-Energy-Density Fuels Enhanced by Amines and Scrambled Cages

E. Xiu-tian-feng; Lei Zhang; Lun Pan; Ji Jun Zou

doi:10.1007/s10553-018-0965-0

Acetylene Solubility in High-Energy-Density Fuels Enhanced by Amines and Scrambled Cages

E. Xiu-tian-feng, Lei Zhang, Lun Pan^*, Ji Jun Zou

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

High-energy-density (HED) fuels are widely used in aerospace engines bit suffer front slow trance and incomplete combustion. A proposed solution to this problem is dissolution of a flammable small-molecule additive, a g., acetylene, in the fuel. The solubility of acetylene in HED fuels JP-10 and QC at 298.15 K and pressure from 0 to 200 kPa was studied. The molar concentration of acetylene in JP-10 and QC fuels or a pressure of 100 kPa reached 0.60 and 0.75%, respectively. Studies of the dissolution of acetylene in the presence of Et₃N and scrambled cages (1, 2, and 5 mass%) showed that such additives could increase significantly the solubility of acetylene in the fuel. The research results are of practical interest for improving the efficiency of HED fuels.

Original language	English
Pages (from-to)	599-605
Number of pages	7
Journal	Chemistry and Technology of Fuels and Oils
Volume	54
Issue number	5
DOIs	https://doi.org/10.1007/s10553-018-0965-0
Publication status	Published - 1 Nov 2018
Externally published	Yes

Keywords

EtN
JP-10
acetylene solubility
quadricyclane
scrambled cages

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10.1007/s10553-018-0965-0

Cite this

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title = "Acetylene Solubility in High-Energy-Density Fuels Enhanced by Amines and Scrambled Cages",

abstract = "High-energy-density (HED) fuels are widely used in aerospace engines bit suffer front slow trance and incomplete combustion. A proposed solution to this problem is dissolution of a flammable small-molecule additive, a g., acetylene, in the fuel. The solubility of acetylene in HED fuels JP-10 and QC at 298.15 K and pressure from 0 to 200 kPa was studied. The molar concentration of acetylene in JP-10 and QC fuels or a pressure of 100 kPa reached 0.60 and 0.75%, respectively. Studies of the dissolution of acetylene in the presence of Et3N and scrambled cages (1, 2, and 5 mass%) showed that such additives could increase significantly the solubility of acetylene in the fuel. The research results are of practical interest for improving the efficiency of HED fuels.",

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AU - Xiu-tian-feng, E.

AU - Zhang, Lei

AU - Pan, Lun

AU - Zou, Ji Jun

PY - 2018/11/1

Y1 - 2018/11/1

N2 - High-energy-density (HED) fuels are widely used in aerospace engines bit suffer front slow trance and incomplete combustion. A proposed solution to this problem is dissolution of a flammable small-molecule additive, a g., acetylene, in the fuel. The solubility of acetylene in HED fuels JP-10 and QC at 298.15 K and pressure from 0 to 200 kPa was studied. The molar concentration of acetylene in JP-10 and QC fuels or a pressure of 100 kPa reached 0.60 and 0.75%, respectively. Studies of the dissolution of acetylene in the presence of Et3N and scrambled cages (1, 2, and 5 mass%) showed that such additives could increase significantly the solubility of acetylene in the fuel. The research results are of practical interest for improving the efficiency of HED fuels.

AB - High-energy-density (HED) fuels are widely used in aerospace engines bit suffer front slow trance and incomplete combustion. A proposed solution to this problem is dissolution of a flammable small-molecule additive, a g., acetylene, in the fuel. The solubility of acetylene in HED fuels JP-10 and QC at 298.15 K and pressure from 0 to 200 kPa was studied. The molar concentration of acetylene in JP-10 and QC fuels or a pressure of 100 kPa reached 0.60 and 0.75%, respectively. Studies of the dissolution of acetylene in the presence of Et3N and scrambled cages (1, 2, and 5 mass%) showed that such additives could increase significantly the solubility of acetylene in the fuel. The research results are of practical interest for improving the efficiency of HED fuels.

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KW - scrambled cages

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Acetylene Solubility in High-Energy-Density Fuels Enhanced by Amines and Scrambled Cages

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Keywords

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