A Zr-added Dawson-type poly(polyoxometalate)

Hai Lou Li; Chen Lian; Guo Yu Yang

doi:10.1039/d2dt03820j

A Zr-added Dawson-type poly(polyoxometalate)

Hai Lou Li, Chen Lian, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

A novel Zr-added trimer, [H₂N(CH₃)₂]₁₀H₁₄[(Zr₂P₂W₁₆O₆₁)₃]·7H₂O (1), has been made under hydrothermal conditions, and contains the highest number of Zr centers in known Dawson-type poly(POM)s. A remarkable feature of this study is the first discovery of a new type of divacant [α-5,10-P₂W₁₆O₆₀]¹⁴⁻ fragment, which assembles with Zr⁴⁺ ions to form a cyclic trimer. Furthermore, 1 as a heterogeneous catalyst exhibits high activity for the selective oxidative degradation of a sulfur mustard simulant CEES.

Original language	English
Pages (from-to)	857-861
Number of pages	5
Journal	Dalton Transactions
Volume	52
Issue number	4
DOIs	https://doi.org/10.1039/d2dt03820j
Publication status	Published - 22 Dec 2022

Access to Document

10.1039/d2dt03820j

Cite this

@article{b5a8070f8ea44ce2ba395a04d908e83e,

title = "A Zr-added Dawson-type poly(polyoxometalate)",

abstract = "A novel Zr-added trimer, [H2N(CH3)2]10H14[(Zr2P2W16O61)3]·7H2O (1), has been made under hydrothermal conditions, and contains the highest number of Zr centers in known Dawson-type poly(POM)s. A remarkable feature of this study is the first discovery of a new type of divacant [α-5,10-P2W16O60]14− fragment, which assembles with Zr4+ ions to form a cyclic trimer. Furthermore, 1 as a heterogeneous catalyst exhibits high activity for the selective oxidative degradation of a sulfur mustard simulant CEES.",

author = "Li, {Hai Lou} and Chen Lian and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2022",

month = dec,

day = "22",

doi = "10.1039/d2dt03820j",

language = "English",

volume = "52",

pages = "857--861",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "4",

}

TY - JOUR

T1 - A Zr-added Dawson-type poly(polyoxometalate)

AU - Li, Hai Lou

AU - Lian, Chen

AU - Yang, Guo Yu

PY - 2022/12/22

Y1 - 2022/12/22

N2 - A novel Zr-added trimer, [H2N(CH3)2]10H14[(Zr2P2W16O61)3]·7H2O (1), has been made under hydrothermal conditions, and contains the highest number of Zr centers in known Dawson-type poly(POM)s. A remarkable feature of this study is the first discovery of a new type of divacant [α-5,10-P2W16O60]14− fragment, which assembles with Zr4+ ions to form a cyclic trimer. Furthermore, 1 as a heterogeneous catalyst exhibits high activity for the selective oxidative degradation of a sulfur mustard simulant CEES.

AB - A novel Zr-added trimer, [H2N(CH3)2]10H14[(Zr2P2W16O61)3]·7H2O (1), has been made under hydrothermal conditions, and contains the highest number of Zr centers in known Dawson-type poly(POM)s. A remarkable feature of this study is the first discovery of a new type of divacant [α-5,10-P2W16O60]14− fragment, which assembles with Zr4+ ions to form a cyclic trimer. Furthermore, 1 as a heterogeneous catalyst exhibits high activity for the selective oxidative degradation of a sulfur mustard simulant CEES.

UR - http://www.scopus.com/inward/record.url?scp=85146162565&partnerID=8YFLogxK

U2 - 10.1039/d2dt03820j

DO - 10.1039/d2dt03820j

M3 - Article

C2 - 36602105

AN - SCOPUS:85146162565

SN - 1477-9226

VL - 52

SP - 857

EP - 861

JO - Dalton Transactions

JF - Dalton Transactions

IS - 4

ER -

A Zr-added Dawson-type poly(polyoxometalate)

Abstract

Access to Document

Other files and links

Fingerprint

Cite this