A two-step field-induced magnetic transition in spin-canted systems observed only for the CoII coordination polymer

Hong Peng Jia; Wei Li; Zhan Feng Ju; Jie Zhang

doi:10.1039/b714678g

A two-step field-induced magnetic transition in spin-canted systems observed only for the Co^II coordination polymer

Hong Peng Jia, Wei Li, Zhan Feng Ju, Jie Zhang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

75 Citations (Scopus)

Abstract

Two isostructural 1D compounds {[M₃(hpdc)₂(H ₂O)₆]·2H₂O}_n (M = Mn, Co; H₃hpdc = 2-hydroxypyrimidine-4,6-dicarboxylic acid) were synthesized by the in situ hydrothermal reactions of 2-chloropyrimidine-4,6-dicarboxylic acid with MCl₂ (M = Mn, Co) and NaOH; the Mn^II compound shows spin-canted antiferromagnetism, whereas the Co^II compound exhibits the coexistence of spin-canting and a two-step field-induced magnetic phase transition.

Original language	English
Pages (from-to)	371-373
Number of pages	3
Journal	Chemical Communications
Issue number	3
DOIs	https://doi.org/10.1039/b714678g
Publication status	Published - 2008
Externally published	Yes

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title = "A two-step field-induced magnetic transition in spin-canted systems observed only for the CoII coordination polymer",

abstract = "Two isostructural 1D compounds {[M3(hpdc)2(H 2O)6]·2H2O}n (M = Mn, Co; H3hpdc = 2-hydroxypyrimidine-4,6-dicarboxylic acid) were synthesized by the in situ hydrothermal reactions of 2-chloropyrimidine-4,6-dicarboxylic acid with MCl2 (M = Mn, Co) and NaOH; the MnII compound shows spin-canted antiferromagnetism, whereas the CoII compound exhibits the coexistence of spin-canting and a two-step field-induced magnetic phase transition.",

author = "Jia, {Hong Peng} and Wei Li and Ju, {Zhan Feng} and Jie Zhang",

year = "2008",

doi = "10.1039/b714678g",

language = "English",

pages = "371--373",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "3",

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T1 - A two-step field-induced magnetic transition in spin-canted systems observed only for the CoII coordination polymer

AU - Jia, Hong Peng

AU - Li, Wei

AU - Ju, Zhan Feng

AU - Zhang, Jie

PY - 2008

Y1 - 2008

N2 - Two isostructural 1D compounds {[M3(hpdc)2(H 2O)6]·2H2O}n (M = Mn, Co; H3hpdc = 2-hydroxypyrimidine-4,6-dicarboxylic acid) were synthesized by the in situ hydrothermal reactions of 2-chloropyrimidine-4,6-dicarboxylic acid with MCl2 (M = Mn, Co) and NaOH; the MnII compound shows spin-canted antiferromagnetism, whereas the CoII compound exhibits the coexistence of spin-canting and a two-step field-induced magnetic phase transition.

AB - Two isostructural 1D compounds {[M3(hpdc)2(H 2O)6]·2H2O}n (M = Mn, Co; H3hpdc = 2-hydroxypyrimidine-4,6-dicarboxylic acid) were synthesized by the in situ hydrothermal reactions of 2-chloropyrimidine-4,6-dicarboxylic acid with MCl2 (M = Mn, Co) and NaOH; the MnII compound shows spin-canted antiferromagnetism, whereas the CoII compound exhibits the coexistence of spin-canting and a two-step field-induced magnetic phase transition.

UR - http://www.scopus.com/inward/record.url?scp=37748998801&partnerID=8YFLogxK

U2 - 10.1039/b714678g

DO - 10.1039/b714678g

M3 - Article

AN - SCOPUS:37748998801

SN - 1359-7345

SP - 371

EP - 373

JO - Chemical Communications

JF - Chemical Communications

IS - 3

ER -

A two-step field-induced magnetic transition in spin-canted systems observed only for the Co^II coordination polymer

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