A Two-Dimensional Spin-Crossover Coordination Polymer Exhibiting Interlayer Multiple C-Hδ+···Hδ--B Dihydrogen Bonds

Jin Peng Xue; Wen Jie Wu; Quan Song Li; Zi Shuo Yao; Jun Tao

doi:10.1021/acs.inorgchem.9b02927

A Two-Dimensional Spin-Crossover Coordination Polymer Exhibiting Interlayer Multiple C-H^δ+···H^δ--B Dihydrogen Bonds

Jin Peng Xue, Wen Jie Wu, Quan Song Li, Zi Shuo Yao^*, Jun Tao

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The reaction of 1,1,2,2-tetrakis(4-(pyridin-4-yl)phenyl)ethene (tppe) with [Fe(NCBH₃)₂] produced a two-dimensional coordination polymer [Fe(NCBH₃)₂(tppe)]_n (1), which was pillared in an ABAB manner through interlayer multiple [C-H^δ+···H^δ--B] dihydrogen bonds (DHBs) to form a stable porous three-dimensional (3D) supramolecular structure that showed guest-molecule-dependent spin-crossover behaviors.

Original language	English
Pages (from-to)	15705-15709
Number of pages	5
Journal	Inorganic Chemistry
Volume	58
Issue number	23
DOIs	https://doi.org/10.1021/acs.inorgchem.9b02927
Publication status	Published - 2 Dec 2019

Access to Document

10.1021/acs.inorgchem.9b02927

Cite this

@article{4e5fbd2ca71e400c96b2d22f63b3415a,

title = "A Two-Dimensional Spin-Crossover Coordination Polymer Exhibiting Interlayer Multiple C-Hδ+···Hδ--B Dihydrogen Bonds",

abstract = "The reaction of 1,1,2,2-tetrakis(4-(pyridin-4-yl)phenyl)ethene (tppe) with [Fe(NCBH3)2] produced a two-dimensional coordination polymer [Fe(NCBH3)2(tppe)]n (1), which was pillared in an ABAB manner through interlayer multiple [C-Hδ+···Hδ--B] dihydrogen bonds (DHBs) to form a stable porous three-dimensional (3D) supramolecular structure that showed guest-molecule-dependent spin-crossover behaviors.",

author = "Xue, \{Jin Peng\} and Wu, \{Wen Jie\} and Li, \{Quan Song\} and Yao, \{Zi Shuo\} and Jun Tao",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = dec,

day = "2",

doi = "10.1021/acs.inorgchem.9b02927",

language = "English",

volume = "58",

pages = "15705--15709",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "23",

}

TY - JOUR

T1 - A Two-Dimensional Spin-Crossover Coordination Polymer Exhibiting Interlayer Multiple C-Hδ+···Hδ--B Dihydrogen Bonds

AU - Xue, Jin Peng

AU - Wu, Wen Jie

AU - Li, Quan Song

AU - Yao, Zi Shuo

AU - Tao, Jun

PY - 2019/12/2

Y1 - 2019/12/2

N2 - The reaction of 1,1,2,2-tetrakis(4-(pyridin-4-yl)phenyl)ethene (tppe) with [Fe(NCBH3)2] produced a two-dimensional coordination polymer [Fe(NCBH3)2(tppe)]n (1), which was pillared in an ABAB manner through interlayer multiple [C-Hδ+···Hδ--B] dihydrogen bonds (DHBs) to form a stable porous three-dimensional (3D) supramolecular structure that showed guest-molecule-dependent spin-crossover behaviors.

AB - The reaction of 1,1,2,2-tetrakis(4-(pyridin-4-yl)phenyl)ethene (tppe) with [Fe(NCBH3)2] produced a two-dimensional coordination polymer [Fe(NCBH3)2(tppe)]n (1), which was pillared in an ABAB manner through interlayer multiple [C-Hδ+···Hδ--B] dihydrogen bonds (DHBs) to form a stable porous three-dimensional (3D) supramolecular structure that showed guest-molecule-dependent spin-crossover behaviors.

UR - https://www.scopus.com/pages/publications/85075184674

U2 - 10.1021/acs.inorgchem.9b02927

DO - 10.1021/acs.inorgchem.9b02927

M3 - Article

C2 - 31710218

AN - SCOPUS:85075184674

SN - 0020-1669

VL - 58

SP - 15705

EP - 15709

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 23

ER -

A Two-Dimensional Spin-Crossover Coordination Polymer Exhibiting Interlayer Multiple C-H^δ+···H^δ--B Dihydrogen Bonds

Abstract

Access to Document

Other files and links

Fingerprint

Cite this