A Trizirconium(IV)-Substituted Sandwiched Polyoxometalate with Mixed Trilacunary Keggin-/Dawson-Type Polyoxotungstate Units

Zhong Zhang; Jun Wei Zhao; Guo Yu Yang

doi:10.1002/ejic.201700410

A Trizirconium(IV)-Substituted Sandwiched Polyoxometalate with Mixed Trilacunary Keggin-/Dawson-Type Polyoxotungstate Units

Zhong Zhang
, Jun Wei Zhao^*
, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

A trizirconium(IV)-substituted sandwich-type polyoxotungstate, K_7.5H_6.5[Zr₃(µ₂-OH)₂(µ₂-O)(A-α-GeW₉O₃₄)(1,4,9-α-P₂W₁₅O₅₆)]·16.5H₂O (1), was hydrothermally synthesized and characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis, powder X-ray diffraction, energy-dispersive X-ray spectroscopy, and single-crystal X-ray diffraction. The structural unit of 1 consists of trilacunary Dawson-type phosphotungstate and trilacunary Keggin-type germanotungstate units that are linked by a trizirconium(IV) cluster.

Original language	English
Pages (from-to)	3244-3247
Number of pages	4
Journal	European Journal of Inorganic Chemistry
Volume	2017
Issue number	26
DOIs	https://doi.org/10.1002/ejic.201700410
Publication status	Published - 2017

Keywords

Cluster compounds
Polyoxometalates
Sandwich complexes
Tungsten
Zirconium

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10.1002/ejic.201700410

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title = "A Trizirconium(IV)-Substituted Sandwiched Polyoxometalate with Mixed Trilacunary Keggin-/Dawson-Type Polyoxotungstate Units",

abstract = "A trizirconium(IV)-substituted sandwich-type polyoxotungstate, K7.5H6.5[Zr3(µ2-OH)2(µ2-O)(A-α-GeW9O34)(1,4,9-α-P2W15O56)]·16.5H2O (1), was hydrothermally synthesized and characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis, powder X-ray diffraction, energy-dispersive X-ray spectroscopy, and single-crystal X-ray diffraction. The structural unit of 1 consists of trilacunary Dawson-type phosphotungstate and trilacunary Keggin-type germanotungstate units that are linked by a trizirconium(IV) cluster.",

keywords = "Cluster compounds, Polyoxometalates, Sandwich complexes, Tungsten, Zirconium",

author = "Zhong Zhang and Zhao, \{Jun Wei\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2017 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2017",

doi = "10.1002/ejic.201700410",

language = "English",

volume = "2017",

pages = "3244--3247",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "26",

}

TY - JOUR

T1 - A Trizirconium(IV)-Substituted Sandwiched Polyoxometalate with Mixed Trilacunary Keggin-/Dawson-Type Polyoxotungstate Units

AU - Zhang, Zhong

AU - Zhao, Jun Wei

AU - Yang, Guo Yu

PY - 2017

Y1 - 2017

N2 - A trizirconium(IV)-substituted sandwich-type polyoxotungstate, K7.5H6.5[Zr3(µ2-OH)2(µ2-O)(A-α-GeW9O34)(1,4,9-α-P2W15O56)]·16.5H2O (1), was hydrothermally synthesized and characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis, powder X-ray diffraction, energy-dispersive X-ray spectroscopy, and single-crystal X-ray diffraction. The structural unit of 1 consists of trilacunary Dawson-type phosphotungstate and trilacunary Keggin-type germanotungstate units that are linked by a trizirconium(IV) cluster.

AB - A trizirconium(IV)-substituted sandwich-type polyoxotungstate, K7.5H6.5[Zr3(µ2-OH)2(µ2-O)(A-α-GeW9O34)(1,4,9-α-P2W15O56)]·16.5H2O (1), was hydrothermally synthesized and characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis, powder X-ray diffraction, energy-dispersive X-ray spectroscopy, and single-crystal X-ray diffraction. The structural unit of 1 consists of trilacunary Dawson-type phosphotungstate and trilacunary Keggin-type germanotungstate units that are linked by a trizirconium(IV) cluster.

KW - Cluster compounds

KW - Polyoxometalates

KW - Sandwich complexes

KW - Tungsten

KW - Zirconium

UR - https://www.scopus.com/pages/publications/85024114454

U2 - 10.1002/ejic.201700410

DO - 10.1002/ejic.201700410

M3 - Article

AN - SCOPUS:85024114454

SN - 1434-1948

VL - 2017

SP - 3244

EP - 3247

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 26

ER -

A Trizirconium(IV)-Substituted Sandwiched Polyoxometalate with Mixed Trilacunary Keggin-/Dawson-Type Polyoxotungstate Units

Abstract

Keywords

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