TY - JOUR
T1 - A series of novel gallium and indium borates constructed from [B 5O8(OH)2]3- clusters and metal complex linkers
AU - Cheng, Lin
AU - Yang, Guo Yu
PY - 2013/2
Y1 - 2013/2
N2 - Four novel gallium and indium borates, [M(en)2][B 5O8(OH)2]·H2O (M=Ga (1), In (2); en=ethylenediamine), [In(dap)2][B5O 8(OH)2]·H2O (3, dap=1,2-diaminopropane), [In(dien)][B5O8(OH)2] (4, dien= diethylenetriamine), have been hydrothermally synthesized and characterized by IR spectra, elemental analyses, powder X-ray diffraction, single crystal X-ray diffraction, and thermogravimetric analyses. Compounds 1, 2 and 3 are isostructural and consist of one-dimensional (1-D) chains built up from [B 5O8(OH)2]3- clusters and Ga-/In-complex linkers. The structure of compound 4 features a 1-D chain containing 8-member rings built by [B5O8(OH) 2]3- clusters and {In2O4} dimeric cluster linkers which have never observed in the structural chemistry of borates to date. The H-bonding interactions between adjacent chains lead to 3-D supramolecular network structure.
AB - Four novel gallium and indium borates, [M(en)2][B 5O8(OH)2]·H2O (M=Ga (1), In (2); en=ethylenediamine), [In(dap)2][B5O 8(OH)2]·H2O (3, dap=1,2-diaminopropane), [In(dien)][B5O8(OH)2] (4, dien= diethylenetriamine), have been hydrothermally synthesized and characterized by IR spectra, elemental analyses, powder X-ray diffraction, single crystal X-ray diffraction, and thermogravimetric analyses. Compounds 1, 2 and 3 are isostructural and consist of one-dimensional (1-D) chains built up from [B 5O8(OH)2]3- clusters and Ga-/In-complex linkers. The structure of compound 4 features a 1-D chain containing 8-member rings built by [B5O8(OH) 2]3- clusters and {In2O4} dimeric cluster linkers which have never observed in the structural chemistry of borates to date. The H-bonding interactions between adjacent chains lead to 3-D supramolecular network structure.
KW - Borate
KW - Cluster
KW - Crystal structure
KW - Gallium
KW - Hydrothermal syntheses
KW - Indium
UR - http://www.scopus.com/inward/record.url?scp=84867429410&partnerID=8YFLogxK
U2 - 10.1016/j.jssc.2012.09.027
DO - 10.1016/j.jssc.2012.09.027
M3 - Article
AN - SCOPUS:84867429410
SN - 0022-4596
VL - 198
SP - 87
EP - 92
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
ER -