A series of lanthanide-based cluster organic frameworks made of heptanuclear trigonal-prismatic cluster units

Wei Hui Fang; Lin Cheng; Ling Huang; Guo Yu Yang

doi:10.1021/ic301963v

A series of lanthanide-based cluster organic frameworks made of heptanuclear trigonal-prismatic cluster units

Wei Hui Fang
, Lin Cheng
, Ling Huang
, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

79 Citations (Scopus)

Abstract

A series of lanthanide-based cluster organic frameworks, [Ln ₇(μ₃-OH)₈L₉(H₂O) ₆]·4ClO₄·3HL·nH₂O [HL = 4-pyridin-4-ylbenzoic acid; Ln = Y (1), La (2), Gd (3), Yb (6), n = 6; Ln = Dy (4), Er (5), n = 4], were hydrothermally made and characterized. It is the first example of heptanuclear trigonal-prismatic lanthanide clusters via a hydrothermal reaction. The magnetic properties of 3 and 4 show typical antiferromagnetic interactions.

Original language	English
Pages (from-to)	6-8
Number of pages	3
Journal	Inorganic Chemistry
Volume	52
Issue number	1
DOIs	https://doi.org/10.1021/ic301963v
Publication status	Published - 7 Jan 2013

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title = "A series of lanthanide-based cluster organic frameworks made of heptanuclear trigonal-prismatic cluster units",

abstract = "A series of lanthanide-based cluster organic frameworks, [Ln 7(μ3-OH)8L9(H2O) 6]·4ClO4·3HL·nH2O [HL = 4-pyridin-4-ylbenzoic acid; Ln = Y (1), La (2), Gd (3), Yb (6), n = 6; Ln = Dy (4), Er (5), n = 4], were hydrothermally made and characterized. It is the first example of heptanuclear trigonal-prismatic lanthanide clusters via a hydrothermal reaction. The magnetic properties of 3 and 4 show typical antiferromagnetic interactions.",

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T1 - A series of lanthanide-based cluster organic frameworks made of heptanuclear trigonal-prismatic cluster units

AU - Fang, Wei Hui

AU - Cheng, Lin

AU - Huang, Ling

AU - Yang, Guo Yu

PY - 2013/1/7

Y1 - 2013/1/7

N2 - A series of lanthanide-based cluster organic frameworks, [Ln 7(μ3-OH)8L9(H2O) 6]·4ClO4·3HL·nH2O [HL = 4-pyridin-4-ylbenzoic acid; Ln = Y (1), La (2), Gd (3), Yb (6), n = 6; Ln = Dy (4), Er (5), n = 4], were hydrothermally made and characterized. It is the first example of heptanuclear trigonal-prismatic lanthanide clusters via a hydrothermal reaction. The magnetic properties of 3 and 4 show typical antiferromagnetic interactions.

AB - A series of lanthanide-based cluster organic frameworks, [Ln 7(μ3-OH)8L9(H2O) 6]·4ClO4·3HL·nH2O [HL = 4-pyridin-4-ylbenzoic acid; Ln = Y (1), La (2), Gd (3), Yb (6), n = 6; Ln = Dy (4), Er (5), n = 4], were hydrothermally made and characterized. It is the first example of heptanuclear trigonal-prismatic lanthanide clusters via a hydrothermal reaction. The magnetic properties of 3 and 4 show typical antiferromagnetic interactions.

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EP - 8

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 1

ER -

A series of lanthanide-based cluster organic frameworks made of heptanuclear trigonal-prismatic cluster units

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