A polymorph of cis-dichloridobis(1,10-phenanthroline-k2 N,N′)cobalt(II)

Ling Ling Li; Dong Xia Liu; Tian Fu Liu

doi:10.1107/S1600536807028073

A polymorph of cis-dichloridobis(1,10-phenanthroline-k² N,N′)cobalt(II)

Ling Ling Li
, Dong Xia Liu
, Tian Fu Liu^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A new polymorph of the title cobalt(II) complex, [CoCl2(C12H8N2)2], is reported here. A previous study reported a monoclinic form of this complex [Zhong, Zeng & Luo (2006), Acta Cryst. E62, m3330-m3332]. In the present orthorhombic structure, the Co^II ion is located in a distorted octa-hedral geometry and coordinated by four N atoms from two 1,10-phenanthroline ligands and two Cl^- anions. The mol-ecules are linked into a two-dimensional framework via weak C - H⋯Cl hydrogen bonding.

Original language	English
Pages (from-to)	m1880
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	7
DOIs	https://doi.org/10.1107/S1600536807028073
Publication status	Published - 6 Jun 2007

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title = "A polymorph of cis-dichloridobis(1,10-phenanthroline-k2 N,N′)cobalt(II)",

abstract = "A new polymorph of the title cobalt(II) complex, [CoCl2(C12H8N2)2], is reported here. A previous study reported a monoclinic form of this complex [Zhong, Zeng \& Luo (2006), Acta Cryst. E62, m3330-m3332]. In the present orthorhombic structure, the CoII ion is located in a distorted octa-hedral geometry and coordinated by four N atoms from two 1,10-phenanthroline ligands and two Cl- anions. The mol-ecules are linked into a two-dimensional framework via weak C - H⋯Cl hydrogen bonding.",

author = "Li, \{Ling Ling\} and Liu, \{Dong Xia\} and Liu, \{Tian Fu\}",

year = "2007",

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language = "English",

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T1 - A polymorph of cis-dichloridobis(1,10-phenanthroline-k2 N,N′)cobalt(II)

AU - Li, Ling Ling

AU - Liu, Dong Xia

AU - Liu, Tian Fu

PY - 2007/6/6

Y1 - 2007/6/6

N2 - A new polymorph of the title cobalt(II) complex, [CoCl2(C12H8N2)2], is reported here. A previous study reported a monoclinic form of this complex [Zhong, Zeng & Luo (2006), Acta Cryst. E62, m3330-m3332]. In the present orthorhombic structure, the CoII ion is located in a distorted octa-hedral geometry and coordinated by four N atoms from two 1,10-phenanthroline ligands and two Cl- anions. The mol-ecules are linked into a two-dimensional framework via weak C - H⋯Cl hydrogen bonding.

AB - A new polymorph of the title cobalt(II) complex, [CoCl2(C12H8N2)2], is reported here. A previous study reported a monoclinic form of this complex [Zhong, Zeng & Luo (2006), Acta Cryst. E62, m3330-m3332]. In the present orthorhombic structure, the CoII ion is located in a distorted octa-hedral geometry and coordinated by four N atoms from two 1,10-phenanthroline ligands and two Cl- anions. The mol-ecules are linked into a two-dimensional framework via weak C - H⋯Cl hydrogen bonding.

UR - https://www.scopus.com/pages/publications/34547201182

U2 - 10.1107/S1600536807028073

DO - 10.1107/S1600536807028073

M3 - Article

AN - SCOPUS:34547201182

SN - 1600-5368

VL - 63

SP - m1880

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7

ER -

A polymorph of cis-dichloridobis(1,10-phenanthroline-k² N,N′)cobalt(II)

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