A novel synthesis of nitroform by the nitrolysis of cucurbituril

Hong Yan Lu; Jia Rong Li; De Li Yang; Qi Zhang; Da Xin Shi

doi:10.1016/j.cclet.2014.12.019

A novel synthesis of nitroform by the nitrolysis of cucurbituril

Hong Yan Lu
, Jia Rong Li
, De Li Yang
, Qi Zhang
, Da Xin Shi^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Cucurbituril has a high symmetry and rigid structure. When cucurbit[6]uril (CB[6]) was nitrolyzed with the mixed solution of acetic anhydride in fuming nitric acid, nitroform (NF) was generated. NF also can be obtained by the nitration of both CB[5,7,8]. This nitration procedure provides a lower risk, inexpensive, new preparation of nitroform, and the reaction condition of this new method is very mild.

Original language	English
Pages (from-to)	365-368
Number of pages	4
Journal	Chinese Chemical Letters
Volume	26
Issue number	3
DOIs	https://doi.org/10.1016/j.cclet.2014.12.019
Publication status	Published - Mar 2015

Keywords

Cucurbituril
Homologues
Nitroform
Nitrolysis

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10.1016/j.cclet.2014.12.019

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title = "A novel synthesis of nitroform by the nitrolysis of cucurbituril",

abstract = "Cucurbituril has a high symmetry and rigid structure. When cucurbit[6]uril (CB[6]) was nitrolyzed with the mixed solution of acetic anhydride in fuming nitric acid, nitroform (NF) was generated. NF also can be obtained by the nitration of both CB[5,7,8]. This nitration procedure provides a lower risk, inexpensive, new preparation of nitroform, and the reaction condition of this new method is very mild.",

keywords = "Cucurbituril, Homologues, Nitroform, Nitrolysis",

author = "Lu, \{Hong Yan\} and Li, \{Jia Rong\} and Yang, \{De Li\} and Qi Zhang and Shi, \{Da Xin\}",

year = "2015",

month = mar,

doi = "10.1016/j.cclet.2014.12.019",

language = "English",

volume = "26",

pages = "365--368",

journal = "Chinese Chemical Letters",

issn = "1001-8417",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - A novel synthesis of nitroform by the nitrolysis of cucurbituril

AU - Lu, Hong Yan

AU - Li, Jia Rong

AU - Yang, De Li

AU - Zhang, Qi

AU - Shi, Da Xin

PY - 2015/3

Y1 - 2015/3

N2 - Cucurbituril has a high symmetry and rigid structure. When cucurbit[6]uril (CB[6]) was nitrolyzed with the mixed solution of acetic anhydride in fuming nitric acid, nitroform (NF) was generated. NF also can be obtained by the nitration of both CB[5,7,8]. This nitration procedure provides a lower risk, inexpensive, new preparation of nitroform, and the reaction condition of this new method is very mild.

AB - Cucurbituril has a high symmetry and rigid structure. When cucurbit[6]uril (CB[6]) was nitrolyzed with the mixed solution of acetic anhydride in fuming nitric acid, nitroform (NF) was generated. NF also can be obtained by the nitration of both CB[5,7,8]. This nitration procedure provides a lower risk, inexpensive, new preparation of nitroform, and the reaction condition of this new method is very mild.

KW - Cucurbituril

KW - Homologues

KW - Nitroform

KW - Nitrolysis

UR - https://www.scopus.com/pages/publications/84940005111

U2 - 10.1016/j.cclet.2014.12.019

DO - 10.1016/j.cclet.2014.12.019

M3 - Article

AN - SCOPUS:84940005111

SN - 1001-8417

VL - 26

SP - 365

EP - 368

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 3

ER -

A novel synthesis of nitroform by the nitrolysis of cucurbituril

Abstract

Keywords

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