A novel poly(polyoxometalate) built by {Cu9}/{Cu5} clusters and {PW9}/{PW10}/{PW11} lacunary fragments

Wei Hui Fang; Wei Dong Wang; Guo Yu Yang

doi:10.1039/c5dt01999k

A novel poly(polyoxometalate) built by {Cu₉}/{Cu₅} clusters and {PW₉}/{PW₁₀}/{PW₁₁} lacunary fragments

Wei Hui Fang
, Wei Dong Wang
, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

The hydrothermal reactions of [A-α-PW₉O₃₄]^9- with CuCl₂·2H₂O in the presence of ethanediamine (en) and acetate afforded a novel poly(polyoxotungstate) containing different lacunary fragments: monolacunary {α-PW₁₁O₃₉}, dilacunary {α-PW₁₀O₃₇}, trilacunary {B-α-PW₉O₃₄}, etc. In addition, a cockhorse-like nona-copper {Cu₉} slab is incorporated. Magnetic investigation indicates overall antiferromagnetic interactions in this compound.

Original language	English
Pages (from-to)	12546-12549
Number of pages	4
Journal	Dalton Transactions
Volume	44
Issue number	28
DOIs	https://doi.org/10.1039/c5dt01999k
Publication status	Published - 28 Jul 2015

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title = "A novel poly(polyoxometalate) built by \{Cu9\}/\{Cu5\} clusters and \{PW9\}/\{PW10\}/\{PW11\} lacunary fragments",

abstract = "The hydrothermal reactions of [A-α-PW9O34]9- with CuCl2·2H2O in the presence of ethanediamine (en) and acetate afforded a novel poly(polyoxotungstate) containing different lacunary fragments: monolacunary \{α-PW11O39\}, dilacunary \{α-PW10O37\}, trilacunary \{B-α-PW9O34\}, etc. In addition, a cockhorse-like nona-copper \{Cu9\} slab is incorporated. Magnetic investigation indicates overall antiferromagnetic interactions in this compound.",

author = "Fang, \{Wei Hui\} and Wang, \{Wei Dong\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2015",

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day = "28",

doi = "10.1039/c5dt01999k",

language = "English",

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T1 - A novel poly(polyoxometalate) built by {Cu9}/{Cu5} clusters and {PW9}/{PW10}/{PW11} lacunary fragments

AU - Fang, Wei Hui

AU - Wang, Wei Dong

AU - Yang, Guo Yu

PY - 2015/7/28

Y1 - 2015/7/28

N2 - The hydrothermal reactions of [A-α-PW9O34]9- with CuCl2·2H2O in the presence of ethanediamine (en) and acetate afforded a novel poly(polyoxotungstate) containing different lacunary fragments: monolacunary {α-PW11O39}, dilacunary {α-PW10O37}, trilacunary {B-α-PW9O34}, etc. In addition, a cockhorse-like nona-copper {Cu9} slab is incorporated. Magnetic investigation indicates overall antiferromagnetic interactions in this compound.

AB - The hydrothermal reactions of [A-α-PW9O34]9- with CuCl2·2H2O in the presence of ethanediamine (en) and acetate afforded a novel poly(polyoxotungstate) containing different lacunary fragments: monolacunary {α-PW11O39}, dilacunary {α-PW10O37}, trilacunary {B-α-PW9O34}, etc. In addition, a cockhorse-like nona-copper {Cu9} slab is incorporated. Magnetic investigation indicates overall antiferromagnetic interactions in this compound.

UR - https://www.scopus.com/pages/publications/84936869143

U2 - 10.1039/c5dt01999k

DO - 10.1039/c5dt01999k

M3 - Article

AN - SCOPUS:84936869143

SN - 1477-9226

VL - 44

SP - 12546

EP - 12549

JO - Dalton Transactions

JF - Dalton Transactions

IS - 28

ER -

A novel poly(polyoxometalate) built by {Cu₉}/{Cu₅} clusters and {PW₉}/{PW₁₀}/{PW₁₁} lacunary fragments

Abstract

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