A novel polyoxovanadium cluster shell: β-As8V 14O42

Shou Tian Zheng; Jie Zhang; Guo Yu Yang

doi:10.1002/zaac.200400318

A novel polyoxovanadium cluster shell: β-As₈V ₁₄O₄₂

Shou Tian Zheng
, Jie Zhang
, Guo Yu Yang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The hydrothermal reaction of VOSO₄, As₂O₅, piperazine and H₂O produces [H₂N(CH₂) ₄NH₂]₄[β-As₈V ₁₄O₄₂(SO₄)]·2HSO₄ (1), which is the first arsenic-vanadium cluster containing a spherical β-As ₈V₁₄O₄₂ shell. The structure of this compound was characterized by single crystal X-ray diffraction, elemental analysis, TG, and IR spectrum. Crystal data for 1: Orthorhombic, Cmcm, a = 15.369(1) Å, b = 16.404(1) Å, c = 25.772(1) Å, V = 6497.4(9) Å³, Z = 4.

Original language	English
Pages (from-to)	170-173
Number of pages	4
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	631
Issue number	1
DOIs	https://doi.org/10.1002/zaac.200400318
Publication status	Published - 2005
Externally published	Yes

Keywords

Arsenate
Crystal structure
Hydrothermal synthesis
Polyoxometalates
Vanadium

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title = "A novel polyoxovanadium cluster shell: β-As8V 14O42",

abstract = "The hydrothermal reaction of VOSO4, As2O5, piperazine and H2O produces [H2N(CH2) 4NH2]4[β-As8V 14O42(SO4)]·2HSO4 (1), which is the first arsenic-vanadium cluster containing a spherical β-As 8V14O42 shell. The structure of this compound was characterized by single crystal X-ray diffraction, elemental analysis, TG, and IR spectrum. Crystal data for 1: Orthorhombic, Cmcm, a = 15.369(1) {\AA}, b = 16.404(1) {\AA}, c = 25.772(1) {\AA}, V = 6497.4(9) {\AA}3, Z = 4.",

keywords = "Arsenate, Crystal structure, Hydrothermal synthesis, Polyoxometalates, Vanadium",

author = "Zheng, \{Shou Tian\} and Jie Zhang and Yang, \{Guo Yu\}",

year = "2005",

doi = "10.1002/zaac.200400318",

language = "English",

volume = "631",

pages = "170--173",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "1",

}

TY - JOUR

T1 - A novel polyoxovanadium cluster shell

T2 - β-As8V 14O42

AU - Zheng, Shou Tian

AU - Zhang, Jie

AU - Yang, Guo Yu

PY - 2005

Y1 - 2005

N2 - The hydrothermal reaction of VOSO4, As2O5, piperazine and H2O produces [H2N(CH2) 4NH2]4[β-As8V 14O42(SO4)]·2HSO4 (1), which is the first arsenic-vanadium cluster containing a spherical β-As 8V14O42 shell. The structure of this compound was characterized by single crystal X-ray diffraction, elemental analysis, TG, and IR spectrum. Crystal data for 1: Orthorhombic, Cmcm, a = 15.369(1) Å, b = 16.404(1) Å, c = 25.772(1) Å, V = 6497.4(9) Å3, Z = 4.

AB - The hydrothermal reaction of VOSO4, As2O5, piperazine and H2O produces [H2N(CH2) 4NH2]4[β-As8V 14O42(SO4)]·2HSO4 (1), which is the first arsenic-vanadium cluster containing a spherical β-As 8V14O42 shell. The structure of this compound was characterized by single crystal X-ray diffraction, elemental analysis, TG, and IR spectrum. Crystal data for 1: Orthorhombic, Cmcm, a = 15.369(1) Å, b = 16.404(1) Å, c = 25.772(1) Å, V = 6497.4(9) Å3, Z = 4.

KW - Arsenate

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Polyoxometalates

KW - Vanadium

UR - https://www.scopus.com/pages/publications/12344313541

U2 - 10.1002/zaac.200400318

DO - 10.1002/zaac.200400318

M3 - Article

AN - SCOPUS:12344313541

SN - 0044-2313

VL - 631

SP - 170

EP - 173

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 1

ER -

A novel polyoxovanadium cluster shell: β-As₈V ₁₄O₄₂

Abstract

Keywords

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