A novel open-framework zinc phosphite, Zn3(HPO3) 4·Ni(en)2(H2O)2, templated by a transition-metal complex

Zhi En Lin; Jie Zhang; Shou Tian Zheng; Guo Yu Yang

doi:10.1002/ejic.200300601

A novel open-framework zinc phosphite, Zn₃(HPO₃) ₄·Ni(en)₂(H₂O)₂, templated by a transition-metal complex

Zhi En Lin
, Jie Zhang
, Shou Tian Zheng
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

A new three-dimensional zinc phosphite, Zn₃(HPO ₃)₄·Ni(en)₂(H₂O) ₂, which is the first example of an open-framework metal phosphite templated by a transition-metal complex, was hydrothermally synthesized. The connectivity of the strictly alternating ZnO₄ and HPO₃ units results in a three-dimensional framework with intersecting 8-ring and 12-ring channels, in which the transition-metal complexes reside.

Original language	English
Pages (from-to)	953-955
Number of pages	3
Journal	European Journal of Inorganic Chemistry
Issue number	5
DOIs	https://doi.org/10.1002/ejic.200300601
Publication status	Published - 5 Mar 2004
Externally published	Yes

Keywords

Inorganic solid
Nickel
Open framework
Template synthesis
Zinc

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10.1002/ejic.200300601

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abstract = "A new three-dimensional zinc phosphite, Zn3(HPO 3)4·Ni(en)2(H2O) 2, which is the first example of an open-framework metal phosphite templated by a transition-metal complex, was hydrothermally synthesized. The connectivity of the strictly alternating ZnO4 and HPO3 units results in a three-dimensional framework with intersecting 8-ring and 12-ring channels, in which the transition-metal complexes reside.",

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AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2004/3/5

Y1 - 2004/3/5

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AB - A new three-dimensional zinc phosphite, Zn3(HPO 3)4·Ni(en)2(H2O) 2, which is the first example of an open-framework metal phosphite templated by a transition-metal complex, was hydrothermally synthesized. The connectivity of the strictly alternating ZnO4 and HPO3 units results in a three-dimensional framework with intersecting 8-ring and 12-ring channels, in which the transition-metal complexes reside.

KW - Inorganic solid

KW - Nickel

KW - Open framework

KW - Template synthesis

KW - Zinc

UR - https://www.scopus.com/pages/publications/4544317261

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DO - 10.1002/ejic.200300601

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ER -

A novel open-framework zinc phosphite, Zn₃(HPO₃) ₄·Ni(en)₂(H₂O)₂, templated by a transition-metal complex

Abstract

Keywords

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