A novel N, O-carboxymethyl amphoteric chitosan/poly(ethersulfone) composite MF membrane and its charged characteristics

Zhiping Zhao, Zhi Wang*, Nan Ye, Shichang Wang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

60 Citations (Scopus)

Abstract

An amphoteric chitosan derivative, containing carboxymethyl (-COOH) groups and amine (-NH2) groups, had been prepared. FT-IR spectra confirmed the presence of γsymCOO (1408 cm-1) and γasCOO (1584 cm-1) on the structural units of the chitosan derivative, and 13C NMR spectra revealed that carboxy methylation reactions took place not only on the -OH but also on the -NH2. N, O-carboxymethyl chitosan (CM-CS)/ poly(ethersulfone) (PES) composite microfiltration (MF) membranes were prepared by immersing PES MF membranes into CM-CS solutions and cross-linking with glutaraldehyde. Streaming potential measurements indicate that the CM-CS/PES composite MF membranes possess a weaker positively charged characteristic at low pHs but a stronger negative charged characteristic at high pHs than the chitosan composite membrane (CS/PES). It was further observed that the CM-CS/PES composite membranes have higher adsorption capacities of bovine serum albumin (BSA) than the CS/PES composite membranes and PES membrane at lower pH 3.0-4.7, and lower adsorption capacities at higher pH 6.0-8.0. Therefore, the CM-CS/PES composite membranes may be suitable for resistant to protein fouling at high pHs or protein adsorption separations at low pHs applications.

Original languageEnglish
Pages (from-to)35-39
Number of pages5
JournalDesalination
Volume144
Issue number1-3
DOIs
Publication statusPublished - 10 Sept 2002
Externally publishedYes

Keywords

  • Carboxymethyl chitosan
  • Composite membranes
  • Fouling
  • Poly(ethersulfone)
  • Protein adsorption
  • Zeta potential

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