A novel aluminoborate open-framework [In(dien)2][Al2B7O16H2] with large chiral cavities templated by chiral main group metal complexes

Lin Cheng; Guo Yu Yang

doi:10.1039/c3cc47440b

A novel aluminoborate open-framework [In(dien)₂][Al₂B₇O₁₆H₂] with large chiral cavities templated by chiral main group metal complexes

Lin Cheng, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Abstract

A novel aluminoborate open-framework [In(dien)₂][Al₂B₇O₁₆H₂] (1, dien = diethylenetriamine) with large chiral cavities has been constructed under solvothermal conditions, in which AlO₄ and chainlike B₄O₈ units are alternately linked to form a network with 20-membered ring windows and then further joined by XO₄ (X = 0.5 Al + 0.5 B) units to give a three-dimensional framework.

Original language	English
Pages (from-to)	344-346
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	3
DOIs	https://doi.org/10.1039/c3cc47440b
Publication status	Published - 3 Dec 2014
Externally published	Yes

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title = "A novel aluminoborate open-framework [In(dien)2][Al2B7O16H2] with large chiral cavities templated by chiral main group metal complexes",

abstract = "A novel aluminoborate open-framework [In(dien)2][Al2B7O16H2] (1, dien = diethylenetriamine) with large chiral cavities has been constructed under solvothermal conditions, in which AlO4 and chainlike B4O8 units are alternately linked to form a network with 20-membered ring windows and then further joined by XO4 (X = 0.5 Al + 0.5 B) units to give a three-dimensional framework.",

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N2 - A novel aluminoborate open-framework [In(dien)2][Al2B7O16H2] (1, dien = diethylenetriamine) with large chiral cavities has been constructed under solvothermal conditions, in which AlO4 and chainlike B4O8 units are alternately linked to form a network with 20-membered ring windows and then further joined by XO4 (X = 0.5 Al + 0.5 B) units to give a three-dimensional framework.

AB - A novel aluminoborate open-framework [In(dien)2][Al2B7O16H2] (1, dien = diethylenetriamine) with large chiral cavities has been constructed under solvothermal conditions, in which AlO4 and chainlike B4O8 units are alternately linked to form a network with 20-membered ring windows and then further joined by XO4 (X = 0.5 Al + 0.5 B) units to give a three-dimensional framework.

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A novel aluminoborate open-framework [In(dien)₂][Al₂B₇O₁₆H₂] with large chiral cavities templated by chiral main group metal complexes

Abstract

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