A New Tubular Borate Built By [B14O24(OH)6]12− Cluster Units

Xiao Shuang Sun; Dan Qin; Xu Yan Li; Guo Yu Yang

doi:10.1007/s40242-021-1183-6

A New Tubular Borate Built By [B₁₄O₂₄(OH)₆]¹²⁻ Cluster Units

Xiao Shuang Sun
, Dan Qin
, Xu Yan Li
, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

A new mixed alkali and alkaline-earth metal borate Na₄Ca₂[B₁₄O₂₂(OH)₆]·2H₂O(1) has been made under a mild solvothermal condition and characterized by single-crystal X-ray diffraction, infrared(IR) spectroscopy, UV-Vis diffuse reflectance spectroscopy, powder X-ray diffraction and thermogravimetric analysis, respectively. Compound 1 features a 1D tube based on [B₁₄O₂₄(OH)₆]¹²⁻({B₁₄}-1) oxo-boron clusters. Such a tube built by {B₁₄}-1 units has been discovered for the first time in borate system. These tubes are arranged orderly to generate 2D layers and a further 3D supramolecular network through hydrogen bond interactions. UV-Vis diffuse reflectance spectrum reveals that compound 1 is a wide band-gap semiconductor and has potential application in UV region.

Original language	English
Pages (from-to)	123-127
Number of pages	5
Journal	Chemical Research in Chinese Universities
Volume	38
Issue number	1
DOIs	https://doi.org/10.1007/s40242-021-1183-6
Publication status	Published - Feb 2022

Keywords

Alkali and alkaline-earth metal
Borate
Cluster
Solvothermal synthesis
Tube

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10.1007/s40242-021-1183-6

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title = "A New Tubular Borate Built By [B14O24(OH)6]12− Cluster Units",

abstract = "A new mixed alkali and alkaline-earth metal borate Na4Ca2[B14O22(OH)6]·2H2O(1) has been made under a mild solvothermal condition and characterized by single-crystal X-ray diffraction, infrared(IR) spectroscopy, UV-Vis diffuse reflectance spectroscopy, powder X-ray diffraction and thermogravimetric analysis, respectively. Compound 1 features a 1D tube based on [B14O24(OH)6]12−(\{B14\}-1) oxo-boron clusters. Such a tube built by \{B14\}-1 units has been discovered for the first time in borate system. These tubes are arranged orderly to generate 2D layers and a further 3D supramolecular network through hydrogen bond interactions. UV-Vis diffuse reflectance spectrum reveals that compound 1 is a wide band-gap semiconductor and has potential application in UV region.",

keywords = "Alkali and alkaline-earth metal, Borate, Cluster, Solvothermal synthesis, Tube",

author = "Sun, \{Xiao Shuang\} and Dan Qin and Li, \{Xu Yan\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2021, Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH.",

year = "2022",

month = feb,

doi = "10.1007/s40242-021-1183-6",

language = "English",

volume = "38",

pages = "123--127",

journal = "Chemical Research in Chinese Universities",

issn = "1005-9040",

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TY - JOUR

T1 - A New Tubular Borate Built By [B14O24(OH)6]12− Cluster Units

AU - Sun, Xiao Shuang

AU - Qin, Dan

AU - Li, Xu Yan

AU - Yang, Guo Yu

PY - 2022/2

Y1 - 2022/2

N2 - A new mixed alkali and alkaline-earth metal borate Na4Ca2[B14O22(OH)6]·2H2O(1) has been made under a mild solvothermal condition and characterized by single-crystal X-ray diffraction, infrared(IR) spectroscopy, UV-Vis diffuse reflectance spectroscopy, powder X-ray diffraction and thermogravimetric analysis, respectively. Compound 1 features a 1D tube based on [B14O24(OH)6]12−({B14}-1) oxo-boron clusters. Such a tube built by {B14}-1 units has been discovered for the first time in borate system. These tubes are arranged orderly to generate 2D layers and a further 3D supramolecular network through hydrogen bond interactions. UV-Vis diffuse reflectance spectrum reveals that compound 1 is a wide band-gap semiconductor and has potential application in UV region.

AB - A new mixed alkali and alkaline-earth metal borate Na4Ca2[B14O22(OH)6]·2H2O(1) has been made under a mild solvothermal condition and characterized by single-crystal X-ray diffraction, infrared(IR) spectroscopy, UV-Vis diffuse reflectance spectroscopy, powder X-ray diffraction and thermogravimetric analysis, respectively. Compound 1 features a 1D tube based on [B14O24(OH)6]12−({B14}-1) oxo-boron clusters. Such a tube built by {B14}-1 units has been discovered for the first time in borate system. These tubes are arranged orderly to generate 2D layers and a further 3D supramolecular network through hydrogen bond interactions. UV-Vis diffuse reflectance spectrum reveals that compound 1 is a wide band-gap semiconductor and has potential application in UV region.

KW - Alkali and alkaline-earth metal

KW - Borate

KW - Cluster

KW - Solvothermal synthesis

KW - Tube

UR - https://www.scopus.com/pages/publications/85108014323

U2 - 10.1007/s40242-021-1183-6

DO - 10.1007/s40242-021-1183-6

M3 - Article

AN - SCOPUS:85108014323

SN - 1005-9040

VL - 38

SP - 123

EP - 127

JO - Chemical Research in Chinese Universities

JF - Chemical Research in Chinese Universities

IS - 1

ER -

A New Tubular Borate Built By [B₁₄O₂₄(OH)₆]¹²⁻ Cluster Units

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Keywords

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