A new method to prepare exfoliated UV-cured polymer/LDH nanocomposites via nanoplatelet-like LDHs modified with N-Lauroyl-glutamate

Bing Zhi Guo; Yun Zhao; Qiang Tao Huang; Qing Ze Jiao

doi:10.1016/j.compscitech.2013.02.022

A new method to prepare exfoliated UV-cured polymer/LDH nanocomposites via nanoplatelet-like LDHs modified with N-Lauroyl-glutamate

Bing Zhi Guo, Yun Zhao, Qiang Tao Huang, Qing Ze Jiao^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

A novel approach to prepare the exfoliated polymer/layered double hydroxide (LDH) nanocomposites is reported. The key features of this method are synthesis of nanoplatelet-like organic LDH modified with N-Lauroyl-glutamate (LDH-LG) and blending LDH-LG with polyester acrylate followed by UV curing. The LDH-LG was prepared by adjusting the proportion of the oil phase in the O/W type microemulsion. From X-ray diffraction analysis and high resolution transmission electron microscope observation, the nanoscale organic LDH particles were homogeneously dispersed in the polymer matrix. The addition of LDH-LG into polyester acrylate improved the wear resistance of the nanocomposite film significantly. The coefficients of static friction, dynamic friction and gloss of nanocomposite with 2. wt% of LDH-LG decreased to 0.114°, 0.062° and 87.5° compared with 0.856°, 0.758° and 94.0° of the pure polymer, respectively. The thermal properties of the polymer/LDH nanocomposites were also discussed.

Original language	English
Pages (from-to)	37-41
Number of pages	5
Journal	Composites Science and Technology
Volume	81
DOIs	https://doi.org/10.1016/j.compscitech.2013.02.022
Publication status	Published - 4 Jun 2013

Keywords

A. Nanocomposites
A. Polymers
B. Thermal properties
Layered double hydroxides

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10.1016/j.compscitech.2013.02.022

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title = "A new method to prepare exfoliated UV-cured polymer/LDH nanocomposites via nanoplatelet-like LDHs modified with N-Lauroyl-glutamate",

abstract = "A novel approach to prepare the exfoliated polymer/layered double hydroxide (LDH) nanocomposites is reported. The key features of this method are synthesis of nanoplatelet-like organic LDH modified with N-Lauroyl-glutamate (LDH-LG) and blending LDH-LG with polyester acrylate followed by UV curing. The LDH-LG was prepared by adjusting the proportion of the oil phase in the O/W type microemulsion. From X-ray diffraction analysis and high resolution transmission electron microscope observation, the nanoscale organic LDH particles were homogeneously dispersed in the polymer matrix. The addition of LDH-LG into polyester acrylate improved the wear resistance of the nanocomposite film significantly. The coefficients of static friction, dynamic friction and gloss of nanocomposite with 2. wt\% of LDH-LG decreased to 0.114°, 0.062° and 87.5° compared with 0.856°, 0.758° and 94.0° of the pure polymer, respectively. The thermal properties of the polymer/LDH nanocomposites were also discussed.",

keywords = "A. Nanocomposites, A. Polymers, B. Thermal properties, Layered double hydroxides",

author = "Guo, \{Bing Zhi\} and Yun Zhao and Huang, \{Qiang Tao\} and Jiao, \{Qing Ze\}",

year = "2013",

month = jun,

day = "4",

doi = "10.1016/j.compscitech.2013.02.022",

language = "English",

volume = "81",

pages = "37--41",

journal = "Composites Science and Technology",

issn = "0266-3538",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - A new method to prepare exfoliated UV-cured polymer/LDH nanocomposites via nanoplatelet-like LDHs modified with N-Lauroyl-glutamate

AU - Guo, Bing Zhi

AU - Zhao, Yun

AU - Huang, Qiang Tao

AU - Jiao, Qing Ze

PY - 2013/6/4

Y1 - 2013/6/4

N2 - A novel approach to prepare the exfoliated polymer/layered double hydroxide (LDH) nanocomposites is reported. The key features of this method are synthesis of nanoplatelet-like organic LDH modified with N-Lauroyl-glutamate (LDH-LG) and blending LDH-LG with polyester acrylate followed by UV curing. The LDH-LG was prepared by adjusting the proportion of the oil phase in the O/W type microemulsion. From X-ray diffraction analysis and high resolution transmission electron microscope observation, the nanoscale organic LDH particles were homogeneously dispersed in the polymer matrix. The addition of LDH-LG into polyester acrylate improved the wear resistance of the nanocomposite film significantly. The coefficients of static friction, dynamic friction and gloss of nanocomposite with 2. wt% of LDH-LG decreased to 0.114°, 0.062° and 87.5° compared with 0.856°, 0.758° and 94.0° of the pure polymer, respectively. The thermal properties of the polymer/LDH nanocomposites were also discussed.

AB - A novel approach to prepare the exfoliated polymer/layered double hydroxide (LDH) nanocomposites is reported. The key features of this method are synthesis of nanoplatelet-like organic LDH modified with N-Lauroyl-glutamate (LDH-LG) and blending LDH-LG with polyester acrylate followed by UV curing. The LDH-LG was prepared by adjusting the proportion of the oil phase in the O/W type microemulsion. From X-ray diffraction analysis and high resolution transmission electron microscope observation, the nanoscale organic LDH particles were homogeneously dispersed in the polymer matrix. The addition of LDH-LG into polyester acrylate improved the wear resistance of the nanocomposite film significantly. The coefficients of static friction, dynamic friction and gloss of nanocomposite with 2. wt% of LDH-LG decreased to 0.114°, 0.062° and 87.5° compared with 0.856°, 0.758° and 94.0° of the pure polymer, respectively. The thermal properties of the polymer/LDH nanocomposites were also discussed.

KW - A. Nanocomposites

KW - A. Polymers

KW - B. Thermal properties

KW - Layered double hydroxides

UR - https://www.scopus.com/pages/publications/84876731433

U2 - 10.1016/j.compscitech.2013.02.022

DO - 10.1016/j.compscitech.2013.02.022

M3 - Article

AN - SCOPUS:84876731433

SN - 0266-3538

VL - 81

SP - 37

EP - 41

JO - Composites Science and Technology

JF - Composites Science and Technology

ER -

A new method to prepare exfoliated UV-cured polymer/LDH nanocomposites via nanoplatelet-like LDHs modified with N-Lauroyl-glutamate

Abstract

Keywords

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