A new method of synthesis for the compound H2[Hbim]2 [(Bim)2Mo8O26]·H2O

Zhong Qiang Zhang; Ru Dan Huang; Yan Qing Xu; Zhi Wei Jiao; Chang Wen Hu

A new method of synthesis for the compound H₂[Hbim]₂ [(Bim)₂Mo₈O₂₆]·H₂O

Zhong Qiang Zhang^*
, Ru Dan Huang
, Yan Qing Xu
, Zhi Wei Jiao
, Chang Wen Hu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology
Hengshui University

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

A new compound, H₂[Hbim]₂ [(bim)₂Mo₈O₂₆]·H₂O (bim=benzimidazole), was synthesized by benzimidazole, MoO₃, et al. and characterized by IR spectrum and single-crystal X-ray diffraction. The compound crystallizes as a monoclinic system, having space group: P2(1)/n, unit cell with a=1.3882(14)nm, b=1.3927(14) nm, c=1.5940(16) nm, α=90°, β=107.334(12)°, γ=90°, V=2.942(5) nm³, Z=2, R₁=0.0525. The compound has the _[Mo8O26]4- cluster as the structural motif and covalently linked with benzimidazole molecules by Mo-N bond. The protonated benzimidazole cations and H⁺ cations play a role of charge-balance.

Original language	English
Pages (from-to)	1109-1112
Number of pages	4
Journal	Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology
Volume	28
Issue number	12
Publication status	Published - Dec 2008

Keywords

Benzimidazole
Compound
Polyoxometalate

Cite this

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title = "A new method of synthesis for the compound H2[Hbim]2 [(Bim)2Mo8O26]·H2O",

abstract = "A new compound, H2[Hbim]2 [(bim)2Mo8O26]·H2O (bim=benzimidazole), was synthesized by benzimidazole, MoO3, et al. and characterized by IR spectrum and single-crystal X-ray diffraction. The compound crystallizes as a monoclinic system, having space group: P2(1)/n, unit cell with a=1.3882(14)nm, b=1.3927(14) nm, c=1.5940(16) nm, α=90°, β=107.334(12)°, γ=90°, V=2.942(5) nm3, Z=2, R1=0.0525. The compound has the [Mo8O26]4- cluster as the structural motif and covalently linked with benzimidazole molecules by Mo-N bond. The protonated benzimidazole cations and H+ cations play a role of charge-balance.",

keywords = "Benzimidazole, Compound, Polyoxometalate",

author = "Zhang, \{Zhong Qiang\} and Huang, \{Ru Dan\} and Xu, \{Yan Qing\} and Jiao, \{Zhi Wei\} and Hu, \{Chang Wen\}",

year = "2008",

month = dec,

language = "English",

volume = "28",

pages = "1109--1112",

journal = "Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology",

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TY - JOUR

T1 - A new method of synthesis for the compound H2[Hbim]2 [(Bim)2Mo8O26]·H2O

AU - Zhang, Zhong Qiang

AU - Huang, Ru Dan

AU - Xu, Yan Qing

AU - Jiao, Zhi Wei

AU - Hu, Chang Wen

PY - 2008/12

Y1 - 2008/12

N2 - A new compound, H2[Hbim]2 [(bim)2Mo8O26]·H2O (bim=benzimidazole), was synthesized by benzimidazole, MoO3, et al. and characterized by IR spectrum and single-crystal X-ray diffraction. The compound crystallizes as a monoclinic system, having space group: P2(1)/n, unit cell with a=1.3882(14)nm, b=1.3927(14) nm, c=1.5940(16) nm, α=90°, β=107.334(12)°, γ=90°, V=2.942(5) nm3, Z=2, R1=0.0525. The compound has the [Mo8O26]4- cluster as the structural motif and covalently linked with benzimidazole molecules by Mo-N bond. The protonated benzimidazole cations and H+ cations play a role of charge-balance.

AB - A new compound, H2[Hbim]2 [(bim)2Mo8O26]·H2O (bim=benzimidazole), was synthesized by benzimidazole, MoO3, et al. and characterized by IR spectrum and single-crystal X-ray diffraction. The compound crystallizes as a monoclinic system, having space group: P2(1)/n, unit cell with a=1.3882(14)nm, b=1.3927(14) nm, c=1.5940(16) nm, α=90°, β=107.334(12)°, γ=90°, V=2.942(5) nm3, Z=2, R1=0.0525. The compound has the [Mo8O26]4- cluster as the structural motif and covalently linked with benzimidazole molecules by Mo-N bond. The protonated benzimidazole cations and H+ cations play a role of charge-balance.

KW - Benzimidazole

KW - Compound

KW - Polyoxometalate

UR - https://www.scopus.com/pages/publications/58249138846

M3 - Article

AN - SCOPUS:58249138846

SN - 1001-0645

VL - 28

SP - 1109

EP - 1112

JO - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

JF - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

IS - 12

ER -

A new method of synthesis for the compound H₂[Hbim]₂ [(Bim)₂Mo₈O₂₆]·H₂O

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Keywords

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