A new layered aluminoborate [Zn(dien)2][{Al(OH)}{B 5O9F}] templated by transition metal complexes

Jian Zhou; Shou Tian Zheng; Mingyi Zhang; Guang Zhen Liu; Guo Yu Yang

doi:10.1039/b909693k

A new layered aluminoborate [Zn(dien)₂][{Al(OH)}{B ₅O₉F}] templated by transition metal complexes

Jian Zhou
, Shou Tian Zheng
, Mingyi Zhang
, Guang Zhen Liu
, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

58 Citations (Scopus)

Abstract

A new layered aluminoborate [Zn(dien)₂][{Al(OH)}{B ₅O₉F}] (1, en = diethylenetriamine) with an acentric structure has been yielded under solvothermal conditions. In 1, the AlO ₃(OH) tetrahedra and B₅O₉F clusters interconnect to form a layer of [{Al(OH)}{B₅O₉F}] ^2- with 7-MR helical channels. 1 exhibits weak SHG properties and luminescence emission at 450 nm.

Original language	English
Pages (from-to)	2597-2600
Number of pages	4
Journal	CrystEngComm
Volume	11
Issue number	12
DOIs	https://doi.org/10.1039/b909693k
Publication status	Published - 2009

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title = "A new layered aluminoborate [Zn(dien)2][\{Al(OH)\}\{B 5O9F\}] templated by transition metal complexes",

abstract = "A new layered aluminoborate [Zn(dien)2][\{Al(OH)\}\{B 5O9F\}] (1, en = diethylenetriamine) with an acentric structure has been yielded under solvothermal conditions. In 1, the AlO 3(OH) tetrahedra and B5O9F clusters interconnect to form a layer of [\{Al(OH)\}\{B5O9F\}] 2- with 7-MR helical channels. 1 exhibits weak SHG properties and luminescence emission at 450 nm.",

author = "Jian Zhou and Zheng, \{Shou Tian\} and Mingyi Zhang and Liu, \{Guang Zhen\} and Yang, \{Guo Yu\}",

year = "2009",

doi = "10.1039/b909693k",

language = "English",

volume = "11",

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journal = "CrystEngComm",

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publisher = "Royal Society of Chemistry",

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T1 - A new layered aluminoborate [Zn(dien)2][{Al(OH)}{B 5O9F}] templated by transition metal complexes

AU - Zhou, Jian

AU - Zheng, Shou Tian

AU - Zhang, Mingyi

AU - Liu, Guang Zhen

AU - Yang, Guo Yu

PY - 2009

Y1 - 2009

N2 - A new layered aluminoborate [Zn(dien)2][{Al(OH)}{B 5O9F}] (1, en = diethylenetriamine) with an acentric structure has been yielded under solvothermal conditions. In 1, the AlO 3(OH) tetrahedra and B5O9F clusters interconnect to form a layer of [{Al(OH)}{B5O9F}] 2- with 7-MR helical channels. 1 exhibits weak SHG properties and luminescence emission at 450 nm.

AB - A new layered aluminoborate [Zn(dien)2][{Al(OH)}{B 5O9F}] (1, en = diethylenetriamine) with an acentric structure has been yielded under solvothermal conditions. In 1, the AlO 3(OH) tetrahedra and B5O9F clusters interconnect to form a layer of [{Al(OH)}{B5O9F}] 2- with 7-MR helical channels. 1 exhibits weak SHG properties and luminescence emission at 450 nm.

UR - https://www.scopus.com/pages/publications/72449145391

U2 - 10.1039/b909693k

DO - 10.1039/b909693k

M3 - Article

AN - SCOPUS:72449145391

SN - 1466-8033

VL - 11

SP - 2597

EP - 2600

JO - CrystEngComm

JF - CrystEngComm

IS - 12

ER -

A new layered aluminoborate [Zn(dien)₂][{Al(OH)}{B ₅O₉F}] templated by transition metal complexes

Abstract

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