A new inorganic-organic hybrid with zinc phosphate layers pillared by the 4,4′-bipyridine units

Zhi En Lin; Jie Zhang; Shou Tian Zheng; Guo Yu Yang

doi:10.1002/zaac.200400379

A new inorganic-organic hybrid with zinc phosphate layers pillared by the 4,4′-bipyridine units

Zhi En Lin, Jie Zhang, Shou Tian Zheng, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

A new inorganic-organic hybrid zinc phosphate with the formula Zn ₂(4,4′-bipy)(HPO₄)₂ (4,4′-bipy = 4,4′-bipyridine) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, FTIR, ICP analysis, elemental analysis, SEM, powder X-ray diffraction, thermogravimetric analysis and its fluorescent spectrum. The compound crystallizes in the monoclinic system, space group P2₁/c (No. 14), a = 10.4479(7), b = 8.1694(5), c = 8.9643(5) Å, β = 97.907(2), V = 757.86(8) Å³, Z = 2. The structure consists of ZnO₃N and HPO₄ tetrahedra by corner-sharing to generate neutral 4.8²-net sheets, which are pillared through 4,4′-bipy ligands to form a 3-D hybrid framework.

Original language	English
Pages (from-to)	155-159
Number of pages	5
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	631
Issue number	1
DOIs	https://doi.org/10.1002/zaac.200400379
Publication status	Published - 2005
Externally published	Yes

Keywords

Crystal elucidation
Hybrid
Hydrothermal synthesis
Phosphate
Zinc

Access to Document

10.1002/zaac.200400379

Cite this

@article{0f1a478390874e44ab63dc7f7db6a705,

title = "A new inorganic-organic hybrid with zinc phosphate layers pillared by the 4,4′-bipyridine units",

abstract = "A new inorganic-organic hybrid zinc phosphate with the formula Zn 2(4,4′-bipy)(HPO4)2 (4,4′-bipy = 4,4′-bipyridine) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, FTIR, ICP analysis, elemental analysis, SEM, powder X-ray diffraction, thermogravimetric analysis and its fluorescent spectrum. The compound crystallizes in the monoclinic system, space group P21/c (No. 14), a = 10.4479(7), b = 8.1694(5), c = 8.9643(5) {\AA}, β = 97.907(2), V = 757.86(8) {\AA}3, Z = 2. The structure consists of ZnO3N and HPO4 tetrahedra by corner-sharing to generate neutral 4.82-net sheets, which are pillared through 4,4′-bipy ligands to form a 3-D hybrid framework.",

keywords = "Crystal elucidation, Hybrid, Hydrothermal synthesis, Phosphate, Zinc",

author = "Lin, \{Zhi En\} and Jie Zhang and Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

year = "2005",

doi = "10.1002/zaac.200400379",

language = "English",

volume = "631",

pages = "155--159",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "1",

}

TY - JOUR

T1 - A new inorganic-organic hybrid with zinc phosphate layers pillared by the 4,4′-bipyridine units

AU - Lin, Zhi En

AU - Zhang, Jie

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2005

Y1 - 2005

N2 - A new inorganic-organic hybrid zinc phosphate with the formula Zn 2(4,4′-bipy)(HPO4)2 (4,4′-bipy = 4,4′-bipyridine) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, FTIR, ICP analysis, elemental analysis, SEM, powder X-ray diffraction, thermogravimetric analysis and its fluorescent spectrum. The compound crystallizes in the monoclinic system, space group P21/c (No. 14), a = 10.4479(7), b = 8.1694(5), c = 8.9643(5) Å, β = 97.907(2), V = 757.86(8) Å3, Z = 2. The structure consists of ZnO3N and HPO4 tetrahedra by corner-sharing to generate neutral 4.82-net sheets, which are pillared through 4,4′-bipy ligands to form a 3-D hybrid framework.

AB - A new inorganic-organic hybrid zinc phosphate with the formula Zn 2(4,4′-bipy)(HPO4)2 (4,4′-bipy = 4,4′-bipyridine) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, FTIR, ICP analysis, elemental analysis, SEM, powder X-ray diffraction, thermogravimetric analysis and its fluorescent spectrum. The compound crystallizes in the monoclinic system, space group P21/c (No. 14), a = 10.4479(7), b = 8.1694(5), c = 8.9643(5) Å, β = 97.907(2), V = 757.86(8) Å3, Z = 2. The structure consists of ZnO3N and HPO4 tetrahedra by corner-sharing to generate neutral 4.82-net sheets, which are pillared through 4,4′-bipy ligands to form a 3-D hybrid framework.

KW - Crystal elucidation

KW - Hybrid

KW - Hydrothermal synthesis

KW - Phosphate

KW - Zinc

UR - https://www.scopus.com/pages/publications/12344262098

U2 - 10.1002/zaac.200400379

DO - 10.1002/zaac.200400379

M3 - Article

AN - SCOPUS:12344262098

SN - 0044-2313

VL - 631

SP - 155

EP - 159

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 1

ER -

A new inorganic-organic hybrid with zinc phosphate layers pillared by the 4,4′-bipyridine units

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this