A new acentric metal borate Mg[B6O9(OH) 2]·4H2O: Synthesis, structure and optical property

Han Qing Wu; Qi Wei; Huan He; Bai Feng Yang; Qiang Zhang; Guo Yu Yang

doi:10.1016/j.inoche.2014.05.004

A new acentric metal borate Mg[B₆O₉(OH) ₂]·4H₂O: Synthesis, structure and optical property

Han Qing Wu
, Qi Wei
, Huan He
, Bai Feng Yang
, Qiang Zhang^*
, Guo Yu Yang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

An acentric metal borate, Mg[B₆O₉(OH) ₂]·4H₂O, has been successfully made under mild hydrothermal conditions. Its structure contains a novel 2-D layer constructed from the B₆O₁₁(OH)₂ cluster units, which are further linked by the MgO₆ polyhedra to form a 3-D framework. It has a UV cutoff edge below 200 nm and exhibits SHG efficiency approximately 1.1 times that of KDP.

Original language	English
Pages (from-to)	69-72
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	46
DOIs	https://doi.org/10.1016/j.inoche.2014.05.004
Publication status	Published - Aug 2014
Externally published	Yes

Keywords

Acentric
Borate
Cluster
Magnesium
Nonlinear optics

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10.1016/j.inoche.2014.05.004

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title = "A new acentric metal borate Mg[B6O9(OH) 2]·4H2O: Synthesis, structure and optical property",

abstract = "An acentric metal borate, Mg[B6O9(OH) 2]·4H2O, has been successfully made under mild hydrothermal conditions. Its structure contains a novel 2-D layer constructed from the B6O11(OH)2 cluster units, which are further linked by the MgO6 polyhedra to form a 3-D framework. It has a UV cutoff edge below 200 nm and exhibits SHG efficiency approximately 1.1 times that of KDP.",

keywords = "Acentric, Borate, Cluster, Magnesium, Nonlinear optics",

author = "Wu, \{Han Qing\} and Qi Wei and Huan He and Yang, \{Bai Feng\} and Qiang Zhang and Yang, \{Guo Yu\}",

year = "2014",

month = aug,

doi = "10.1016/j.inoche.2014.05.004",

language = "English",

volume = "46",

pages = "69--72",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

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T1 - A new acentric metal borate Mg[B6O9(OH) 2]·4H2O

T2 - Synthesis, structure and optical property

AU - Wu, Han Qing

AU - Wei, Qi

AU - He, Huan

AU - Yang, Bai Feng

AU - Zhang, Qiang

AU - Yang, Guo Yu

PY - 2014/8

Y1 - 2014/8

N2 - An acentric metal borate, Mg[B6O9(OH) 2]·4H2O, has been successfully made under mild hydrothermal conditions. Its structure contains a novel 2-D layer constructed from the B6O11(OH)2 cluster units, which are further linked by the MgO6 polyhedra to form a 3-D framework. It has a UV cutoff edge below 200 nm and exhibits SHG efficiency approximately 1.1 times that of KDP.

AB - An acentric metal borate, Mg[B6O9(OH) 2]·4H2O, has been successfully made under mild hydrothermal conditions. Its structure contains a novel 2-D layer constructed from the B6O11(OH)2 cluster units, which are further linked by the MgO6 polyhedra to form a 3-D framework. It has a UV cutoff edge below 200 nm and exhibits SHG efficiency approximately 1.1 times that of KDP.

KW - Acentric

KW - Borate

KW - Cluster

KW - Magnesium

KW - Nonlinear optics

UR - https://www.scopus.com/pages/publications/84901396365

U2 - 10.1016/j.inoche.2014.05.004

DO - 10.1016/j.inoche.2014.05.004

M3 - Article

AN - SCOPUS:84901396365

SN - 1387-7003

VL - 46

SP - 69

EP - 72

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

A new acentric metal borate Mg[B₆O₉(OH) ₂]·4H₂O: Synthesis, structure and optical property

Abstract

Keywords

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