A new 3-D Gd-Cu heterometallic polymer [Gd2Cu3(bpy)2-(ip)6]·6H2O with a non-interpenetrated α-Po net

Xiang Li Jia; Jian Zhou; Jun Wei Zhao; Zhao Hui Li; Shou Tian Zheng; Guo Yu Yang

doi:10.1007/s11434-009-0549-9

A new 3-D Gd-Cu heterometallic polymer [Gd₂Cu₃(bpy)₂-(ip)₆]·6H₂O with a non-interpenetrated α-Po net

Xiang Li Jia, Jian Zhou, Jun Wei Zhao, Zhao Hui Li, Shou Tian Zheng, Guo Yu Yang

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A new 3-D porous Gd-Cu heterometallic polymer [Gd₂Cu₃(bpy)₂(ip)₆]·6H₂O (1) (bpy = 2,2′-bipyridine, H₂ip = isophthalic acid) has been hydrothermally synthesized and structurally characterized. Compound 1 crystallizes in the triclinic space group P1̄ and displays a 3-D non-interpenetrated α-Po network with 1-D channels filled transversely by the hexa-nuclear chain-like (H₂O)₆. The EPR and thermal stability of 1 were investigated.

Original language	English
Pages (from-to)	4272-4276
Number of pages	5
Journal	Chinese Science Bulletin
Volume	54
Issue number	23
DOIs	https://doi.org/10.1007/s11434-009-0549-9
Publication status	Published - Dec 2009
Externally published	Yes

Keywords

Heterometallic polymer
Hydrothermal synthesis
α-Po network

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10.1007/s11434-009-0549-9

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title = "A new 3-D Gd-Cu heterometallic polymer [Gd2Cu3(bpy)2-(ip)6]·6H2O with a non-interpenetrated α-Po net",

abstract = "A new 3-D porous Gd-Cu heterometallic polymer [Gd2Cu3(bpy)2(ip)6]·6H2O (1) (bpy = 2,2′-bipyridine, H2ip = isophthalic acid) has been hydrothermally synthesized and structurally characterized. Compound 1 crystallizes in the triclinic space group P{\=1} and displays a 3-D non-interpenetrated α-Po network with 1-D channels filled transversely by the hexa-nuclear chain-like (H2O)6. The EPR and thermal stability of 1 were investigated.",

keywords = "Heterometallic polymer, Hydrothermal synthesis, α-Po network",

author = "Jia, {Xiang Li} and Jian Zhou and Zhao, {Jun Wei} and Li, {Zhao Hui} and Zheng, {Shou Tian} and Yang, {Guo Yu}",

year = "2009",

month = dec,

doi = "10.1007/s11434-009-0549-9",

language = "English",

volume = "54",

pages = "4272--4276",

journal = "Chinese Science Bulletin",

issn = "1001-6538",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - A new 3-D Gd-Cu heterometallic polymer [Gd2Cu3(bpy)2-(ip)6]·6H2O with a non-interpenetrated α-Po net

AU - Jia, Xiang Li

AU - Zhou, Jian

AU - Zhao, Jun Wei

AU - Li, Zhao Hui

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2009/12

Y1 - 2009/12

N2 - A new 3-D porous Gd-Cu heterometallic polymer [Gd2Cu3(bpy)2(ip)6]·6H2O (1) (bpy = 2,2′-bipyridine, H2ip = isophthalic acid) has been hydrothermally synthesized and structurally characterized. Compound 1 crystallizes in the triclinic space group P1̄ and displays a 3-D non-interpenetrated α-Po network with 1-D channels filled transversely by the hexa-nuclear chain-like (H2O)6. The EPR and thermal stability of 1 were investigated.

AB - A new 3-D porous Gd-Cu heterometallic polymer [Gd2Cu3(bpy)2(ip)6]·6H2O (1) (bpy = 2,2′-bipyridine, H2ip = isophthalic acid) has been hydrothermally synthesized and structurally characterized. Compound 1 crystallizes in the triclinic space group P1̄ and displays a 3-D non-interpenetrated α-Po network with 1-D channels filled transversely by the hexa-nuclear chain-like (H2O)6. The EPR and thermal stability of 1 were investigated.

KW - Heterometallic polymer

KW - Hydrothermal synthesis

KW - α-Po network

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U2 - 10.1007/s11434-009-0549-9

DO - 10.1007/s11434-009-0549-9

M3 - Article

AN - SCOPUS:74749087106

SN - 1001-6538

VL - 54

SP - 4272

EP - 4276

JO - Chinese Science Bulletin

JF - Chinese Science Bulletin

IS - 23

ER -

A new 3-D Gd-Cu heterometallic polymer [Gd₂Cu₃(bpy)₂-(ip)₆]·6H₂O with a non-interpenetrated α-Po net

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Keywords

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