A new 22-Ni-substitued polyoxometalate: Hydrothermal synthesis, structure and electrochemical property

Peng Yun Zhang; Zhong Zhang; Xu Yan Li; Guo Yu Yang

doi:10.1016/j.inoche.2019.107753

A new 22-Ni-substitued polyoxometalate: Hydrothermal synthesis, structure and electrochemical property

Peng Yun Zhang
, Zhong Zhang
, Xu Yan Li
, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

A new inorganic–organic hybrid 22-Ni-substituted phosphotungstate, [Ni(H₂O)₂(en)]₂[Ni(H₂O)(en)₂]₂{[Ni₆(OH)₂(H₂O)(en)₂(B-α-PW₉O₃₄)]₂[W₄O₁₆][Ni₅(H₂O)₃(en)₃(PW₆O₂₆)]₂}·24H₂O (1, en = ethylenediamine) has been made by hydrothermal method and characterized by elemental analysis, single crystal X-ray diffraction, powder X-ray diffraction, IR spectroscopy, thermogravimetric analysis, and UV–Vis diffuse-reflectance spectroscopy, respectively. Compound 1 contains a 22-Ni-substituted polyoxoanion built by central [W₄O₁₆]⁸⁻ core and two different symmetrical clusters, [Ni₆(OH)₂(H₂O)(en)₂(B-α-PW₉O₃₄)]⁺ and [Ni₅(H₂O)₃(en)₃(PW₆O₂₆)]⁻, which is further linked by double-bridging [Ni(H₂O)₂(en)]²⁺ cations to form 1-D chain. Moreover, the counter cations, [Ni(H₂O)(en)₂]²⁺ support to the [B-α-PW₉O₃₄]⁹⁻ fragments.

Original language	English
Article number	107753
Journal	Inorganic Chemistry Communications
Volume	113
DOIs	https://doi.org/10.1016/j.inoche.2019.107753
Publication status	Published - Mar 2020

Keywords

Cluster
High-nuclearity
Hydrothermal synthesis
Ni-substituted
Phosphotungstate

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@article{0566574303ea4388b6d6e9fb33dde61e,

title = "A new 22-Ni-substitued polyoxometalate: Hydrothermal synthesis, structure and electrochemical property",

abstract = "A new inorganic–organic hybrid 22-Ni-substituted phosphotungstate, [Ni(H2O)2(en)]2[Ni(H2O)(en)2]2\{[Ni6(OH)2(H2O)(en)2(B-α-PW9O34)]2[W4O16][Ni5(H2O)3(en)3(PW6O26)]2\}·24H2O (1, en = ethylenediamine) has been made by hydrothermal method and characterized by elemental analysis, single crystal X-ray diffraction, powder X-ray diffraction, IR spectroscopy, thermogravimetric analysis, and UV–Vis diffuse-reflectance spectroscopy, respectively. Compound 1 contains a 22-Ni-substituted polyoxoanion built by central [W4O16]8− core and two different symmetrical clusters, [Ni6(OH)2(H2O)(en)2(B-α-PW9O34)]+ and [Ni5(H2O)3(en)3(PW6O26)]−, which is further linked by double-bridging [Ni(H2O)2(en)]2+ cations to form 1-D chain. Moreover, the counter cations, [Ni(H2O)(en)2]2+ support to the [B-α-PW9O34]9− fragments.",

keywords = "Cluster, High-nuclearity, Hydrothermal synthesis, Ni-substituted, Phosphotungstate",

author = "Zhang, \{Peng Yun\} and Zhong Zhang and Li, \{Xu Yan\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier B.V.",

year = "2020",

month = mar,

doi = "10.1016/j.inoche.2019.107753",

language = "English",

volume = "113",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - A new 22-Ni-substitued polyoxometalate

T2 - Hydrothermal synthesis, structure and electrochemical property

AU - Zhang, Peng Yun

AU - Zhang, Zhong

AU - Li, Xu Yan

AU - Yang, Guo Yu

PY - 2020/3

Y1 - 2020/3

N2 - A new inorganic–organic hybrid 22-Ni-substituted phosphotungstate, [Ni(H2O)2(en)]2[Ni(H2O)(en)2]2{[Ni6(OH)2(H2O)(en)2(B-α-PW9O34)]2[W4O16][Ni5(H2O)3(en)3(PW6O26)]2}·24H2O (1, en = ethylenediamine) has been made by hydrothermal method and characterized by elemental analysis, single crystal X-ray diffraction, powder X-ray diffraction, IR spectroscopy, thermogravimetric analysis, and UV–Vis diffuse-reflectance spectroscopy, respectively. Compound 1 contains a 22-Ni-substituted polyoxoanion built by central [W4O16]8− core and two different symmetrical clusters, [Ni6(OH)2(H2O)(en)2(B-α-PW9O34)]+ and [Ni5(H2O)3(en)3(PW6O26)]−, which is further linked by double-bridging [Ni(H2O)2(en)]2+ cations to form 1-D chain. Moreover, the counter cations, [Ni(H2O)(en)2]2+ support to the [B-α-PW9O34]9− fragments.

AB - A new inorganic–organic hybrid 22-Ni-substituted phosphotungstate, [Ni(H2O)2(en)]2[Ni(H2O)(en)2]2{[Ni6(OH)2(H2O)(en)2(B-α-PW9O34)]2[W4O16][Ni5(H2O)3(en)3(PW6O26)]2}·24H2O (1, en = ethylenediamine) has been made by hydrothermal method and characterized by elemental analysis, single crystal X-ray diffraction, powder X-ray diffraction, IR spectroscopy, thermogravimetric analysis, and UV–Vis diffuse-reflectance spectroscopy, respectively. Compound 1 contains a 22-Ni-substituted polyoxoanion built by central [W4O16]8− core and two different symmetrical clusters, [Ni6(OH)2(H2O)(en)2(B-α-PW9O34)]+ and [Ni5(H2O)3(en)3(PW6O26)]−, which is further linked by double-bridging [Ni(H2O)2(en)]2+ cations to form 1-D chain. Moreover, the counter cations, [Ni(H2O)(en)2]2+ support to the [B-α-PW9O34]9− fragments.

KW - Cluster

KW - High-nuclearity

KW - Hydrothermal synthesis

KW - Ni-substituted

KW - Phosphotungstate

UR - https://www.scopus.com/pages/publications/85077931397

U2 - 10.1016/j.inoche.2019.107753

DO - 10.1016/j.inoche.2019.107753

M3 - Article

AN - SCOPUS:85077931397

SN - 1387-7003

VL - 113

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

M1 - 107753

ER -

A new 22-Ni-substitued polyoxometalate: Hydrothermal synthesis, structure and electrochemical property

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Keywords

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