A New 2-D network containing {As4V16O 42(H2O)} cluster units

Jian Zhou; Shou Tian Zheng; Wei Hui Fang; Guo Yu Yang

doi:10.1002/ejic.200900596

A New 2-D network containing {As₄V₁₆O ₄₂(H₂O)} cluster units

Jian Zhou
, Shou Tian Zheng
, Wei Hui Fang
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

A new polyoxometalate [Cd(dien)]₂[Cd(dien)(H₂O)] ₂[As₄V₁₆O₄₂(H₂O)] ·2H₂O (1, dien = diethylenetriamine) has been hydrothermally synthesized and structurally characterized. 1 is the first example of 2-D network based on the linkages of the rare (As₄V₁₆O ₄₂(H₂O)) cluster units and two types of cadmium(II) complex fragments. The magnetic susceptibility shows the antiferromagnetic interaction between V^IV cations in 1.

Original language	English
Pages (from-to)	5075-5078
Number of pages	4
Journal	European Journal of Inorganic Chemistry
Issue number	34
DOIs	https://doi.org/10.1002/ejic.200900596
Publication status	Published - 2009
Externally published	Yes

Keywords

Arsenic
Cluster compounds
Hydrothermal synthesis
Polyoxometalates
Vanadium

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10.1002/ejic.200900596

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@article{016c7131f8c7495dad9ee73a76bdb057,

title = "A New 2-D network containing \{As4V16O 42(H2O)\} cluster units",

abstract = "A new polyoxometalate [Cd(dien)]2[Cd(dien)(H2O)] 2[As4V16O42(H2O)] ·2H2O (1, dien = diethylenetriamine) has been hydrothermally synthesized and structurally characterized. 1 is the first example of 2-D network based on the linkages of the rare (As4V16O 42(H2O)) cluster units and two types of cadmium(II) complex fragments. The magnetic susceptibility shows the antiferromagnetic interaction between VIV cations in 1.",

keywords = "Arsenic, Cluster compounds, Hydrothermal synthesis, Polyoxometalates, Vanadium",

author = "Jian Zhou and Zheng, \{Shou Tian\} and Fang, \{Wei Hui\} and Yang, \{Guo Yu\}",

year = "2009",

doi = "10.1002/ejic.200900596",

language = "English",

pages = "5075--5078",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

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T1 - A New 2-D network containing {As4V16O 42(H2O)} cluster units

AU - Zhou, Jian

AU - Zheng, Shou Tian

AU - Fang, Wei Hui

AU - Yang, Guo Yu

PY - 2009

Y1 - 2009

N2 - A new polyoxometalate [Cd(dien)]2[Cd(dien)(H2O)] 2[As4V16O42(H2O)] ·2H2O (1, dien = diethylenetriamine) has been hydrothermally synthesized and structurally characterized. 1 is the first example of 2-D network based on the linkages of the rare (As4V16O 42(H2O)) cluster units and two types of cadmium(II) complex fragments. The magnetic susceptibility shows the antiferromagnetic interaction between VIV cations in 1.

AB - A new polyoxometalate [Cd(dien)]2[Cd(dien)(H2O)] 2[As4V16O42(H2O)] ·2H2O (1, dien = diethylenetriamine) has been hydrothermally synthesized and structurally characterized. 1 is the first example of 2-D network based on the linkages of the rare (As4V16O 42(H2O)) cluster units and two types of cadmium(II) complex fragments. The magnetic susceptibility shows the antiferromagnetic interaction between VIV cations in 1.

KW - Arsenic

KW - Cluster compounds

KW - Hydrothermal synthesis

KW - Polyoxometalates

KW - Vanadium

UR - https://www.scopus.com/pages/publications/72949094017

U2 - 10.1002/ejic.200900596

DO - 10.1002/ejic.200900596

M3 - Article

AN - SCOPUS:72949094017

SN - 1434-1948

SP - 5075

EP - 5078

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 34

ER -

A New 2-D network containing {As₄V₁₆O ₄₂(H₂O)} cluster units

Abstract

Keywords

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