TY - JOUR
T1 - A multi-fused heat-resistant energetic compound constructed by hydrogen bonds
AU - Hu, Yong
AU - Dong, Wen Shuai
AU - Lu, Zu Jia
AU - Zhang, Han
AU - Zhang, Jian Guo
N1 - Publisher Copyright:
© 2023 The Royal Society of Chemistry.
PY - 2023/7/13
Y1 - 2023/7/13
N2 - The design of heat-resistant energetic compounds generally employs symmetry, planarity, and multi-hydrogen bonds to obtain compounds with high density, good thermal stability, and low sensitivity. In this paper, a heat-resistant hydrazine-bridged compound, 6,6′-(hydrazine-1,2-diyl)bis(5-nitropyrimidine-2,4-diamine) (PHP), was designed and synthesized with the strategy of multi-fused conjugated structure constructed by hydrogen bonds. The compound featured high symmetry, high planarity, and strong conjugation with good thermal stability (364 °C). This strategy provides a basis for the design of heat-resistant energetic compounds.
AB - The design of heat-resistant energetic compounds generally employs symmetry, planarity, and multi-hydrogen bonds to obtain compounds with high density, good thermal stability, and low sensitivity. In this paper, a heat-resistant hydrazine-bridged compound, 6,6′-(hydrazine-1,2-diyl)bis(5-nitropyrimidine-2,4-diamine) (PHP), was designed and synthesized with the strategy of multi-fused conjugated structure constructed by hydrogen bonds. The compound featured high symmetry, high planarity, and strong conjugation with good thermal stability (364 °C). This strategy provides a basis for the design of heat-resistant energetic compounds.
UR - https://www.scopus.com/pages/publications/85167354401
U2 - 10.1039/d3cc02504g
DO - 10.1039/d3cc02504g
M3 - Article
C2 - 37491895
AN - SCOPUS:85167354401
SN - 1359-7345
VL - 59
SP - 9864
EP - 9867
JO - Chemical Communications
JF - Chemical Communications
IS - 65
ER -