A metal-oxo cluster-supported transition metal complex: Synthesis, structure and properties of [Cu(phen)2]2[{Cu(phen)}2Mo8O 26]·H2O

Ren Zhang Wang; Ji Qing Xu; Guo Yu Yang; Wei Ming Bu; Yong Heng Xing; Dong Mei Li; Shu Qing Liu; Ling Ye; Yu Guo Fan

doi:10.1016/S0277-5387(99)00200-4

A metal-oxo cluster-supported transition metal complex: Synthesis, structure and properties of [Cu(phen)₂]₂[{Cu(phen)}₂Mo₈O ₂₆]·H₂O

Ren Zhang Wang
, Ji Qing Xu^*
, Guo Yu Yang
, Wei Ming Bu
, Yong Heng Xing
, Dong Mei Li
, Shu Qing Liu
, Ling Ye
, Yu Guo Fan

^*Corresponding author for this work

Jilin University
Nanjing University

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

[Cu(phen)₂]₂[{Cu(phen)}₂Mo ₈O₂₆]·H₂O has been synthesized from MoO₃, H₂MoO₄, Cu(Ac)₂·H₂O and 1,10-phenanthroline in aqueous solution using the hydrothermal method and characterized by single-crystal X-ray structure analysis. The title compound consists of a centrometric β-octamolybdate-supported complex anion [{Cu(phen)}₂Mo₈O₂₆]^2-, two bis-phenanthroline Cu(I) cations, and one water molecule of crystallization.

Original language	English
Pages (from-to)	2971-2975
Number of pages	5
Journal	Polyhedron
Volume	18
Issue number	23
DOIs	https://doi.org/10.1016/S0277-5387(99)00200-4
Publication status	Published - 8 Oct 1999
Externally published	Yes

Keywords

Crystal structure
Hydrothermal synthesis
β-Octamolybdate-supported complex

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10.1016/S0277-5387(99)00200-4

Cite this

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title = "A metal-oxo cluster-supported transition metal complex: Synthesis, structure and properties of [Cu(phen)2]2[\{Cu(phen)\}2Mo8O 26]·H2O",

abstract = "[Cu(phen)2]2[\{Cu(phen)\}2Mo 8O26]·H2O has been synthesized from MoO3, H2MoO4, Cu(Ac)2·H2O and 1,10-phenanthroline in aqueous solution using the hydrothermal method and characterized by single-crystal X-ray structure analysis. The title compound consists of a centrometric β-octamolybdate-supported complex anion [\{Cu(phen)\}2Mo8O26]2-, two bis-phenanthroline Cu(I) cations, and one water molecule of crystallization.",

keywords = "Crystal structure, Hydrothermal synthesis, β-Octamolybdate-supported complex",

author = "Wang, \{Ren Zhang\} and Xu, \{Ji Qing\} and Yang, \{Guo Yu\} and Bu, \{Wei Ming\} and Xing, \{Yong Heng\} and Li, \{Dong Mei\} and Liu, \{Shu Qing\} and Ling Ye and Fan, \{Yu Guo\}",

year = "1999",

month = oct,

day = "8",

doi = "10.1016/S0277-5387(99)00200-4",

language = "English",

volume = "18",

pages = "2971--2975",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "23",

}

TY - JOUR

T1 - A metal-oxo cluster-supported transition metal complex

T2 - Synthesis, structure and properties of [Cu(phen)2]2[{Cu(phen)}2Mo8O 26]·H2O

AU - Wang, Ren Zhang

AU - Xu, Ji Qing

AU - Yang, Guo Yu

AU - Bu, Wei Ming

AU - Xing, Yong Heng

AU - Li, Dong Mei

AU - Liu, Shu Qing

AU - Ye, Ling

AU - Fan, Yu Guo

PY - 1999/10/8

Y1 - 1999/10/8

N2 - [Cu(phen)2]2[{Cu(phen)}2Mo 8O26]·H2O has been synthesized from MoO3, H2MoO4, Cu(Ac)2·H2O and 1,10-phenanthroline in aqueous solution using the hydrothermal method and characterized by single-crystal X-ray structure analysis. The title compound consists of a centrometric β-octamolybdate-supported complex anion [{Cu(phen)}2Mo8O26]2-, two bis-phenanthroline Cu(I) cations, and one water molecule of crystallization.

AB - [Cu(phen)2]2[{Cu(phen)}2Mo 8O26]·H2O has been synthesized from MoO3, H2MoO4, Cu(Ac)2·H2O and 1,10-phenanthroline in aqueous solution using the hydrothermal method and characterized by single-crystal X-ray structure analysis. The title compound consists of a centrometric β-octamolybdate-supported complex anion [{Cu(phen)}2Mo8O26]2-, two bis-phenanthroline Cu(I) cations, and one water molecule of crystallization.

KW - Crystal structure

KW - Hydrothermal synthesis

KW - β-Octamolybdate-supported complex

UR - https://www.scopus.com/pages/publications/0038391010

U2 - 10.1016/S0277-5387(99)00200-4

DO - 10.1016/S0277-5387(99)00200-4

M3 - Article

AN - SCOPUS:0038391010

SN - 0277-5387

VL - 18

SP - 2971

EP - 2975

JO - Polyhedron

JF - Polyhedron

IS - 23

ER -

A metal-oxo cluster-supported transition metal complex: Synthesis, structure and properties of [Cu(phen)₂]₂[{Cu(phen)}₂Mo₈O ₂₆]·H₂O

Abstract

Keywords

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